Formulations and method for low temperature cleaning of dairy equipment
A formulation having at least one of a product stabilization solvent, a sequestrant or chelating agent, and an alkalinity agent capable of use in a cleaning operation at a reduced temperature. Optionally, the formulation may additionally comprise any one or more of a degreaser emulsifier solvent, a surfactant, a hydrotrope, a stabilizer, a biocide, and a buffer. An additive formulation of the invention, as defined herein, comprises these stated types of compounds and is combined with an alkalinity agent at the time of the formulations use in a reduced temperature dairy equipment cleaning operation. A full formulation of the invention, as defined herein, additionally comprises an alkalinity agent in addition to the other named compounds. In many cases, the full formulations are used in a reduced temperature dairy equipment cleaning operation without being combined with an additional alkalinity agent. The reduced temperature of the dairy equipment cleaning operation using the formulation of the invention may be less than about 50° C. or, alternatively, less than about 40° C.
1. A method of cleaning a dairy processing equipment, the method comprising:
preparing a cleaning solution from a formulation;
raising a temperature of the cleaning solution to less than about 50° C.; and
contacting the cleaning solution with the dairy processing equipment to clean the dairy processing equipment,
wherein the cleaning solution comprises:
an alkalinity agent chosen from sodium hydroxide sodium carbonate, potassium hydroxide, or any mixture thereof in an amount of from about 0.05% to about 0.35% by weight of the cleaning solution; and
a sequestrant chosen from ethylenediamine tetraacetic acid (EDTA), methylglycine diacetic acid (MGDA), glutamate diacetate (GLDA), diethylene triamine pentaacetic acid (DTPA), hydroxyethylene diamine triacetic acid (HEDTA), nitrilotriacetic acid (NTA), poly(acrylic acid), or any mixture thereof,
wherein the formulation is a chlorine-free formulation.
2. The method of claim 1 , wherein a concentration of the alkalinity agent in the cleaning solution is from about 0.1 wt % to about 0.3 wt % by weight of the cleaning solution.
3. The method of claim 1 , wherein the formulation further comprises a product stabilization solvent, a degreaser emulsifier solvent, a surfactant, a stabilizer, a biocide, a buffer, a hydrotrope, or any combination thereof.
4. The method of claim 1 , further comprising:
holding the cleaning solution in the dairy processing equipment for a time needed to achieve a desired extent of soil removal, and
discharging the cleaning solution from the dairy processing equipment.
5. The method of claim 1 , wherein the temperature of the cleaning solution is raised to less than about 40° C.
6. The method of claim 3 , wherein:
the product stabilization solvent comprises water;
the degreaser/emulsifier solvent comprises an alcohol, a glycol, or a mixture thereof;
the hydrotrope comprises a salt of cumene sulfonic acid, a salt of xylene sulphonic acid, a glycolic acid, a salt of a fatty acid, an amphoteric surfactant, a nonionic surfactant, or any combination thereof;
the surfactant comprises an alcohol alkoxylate that includes an ethylene oxide/propylene oxide (EO/PO), an alcohol alkoxylate that includes an ethylene oxide/butylene oxide (EO/BO), or both.
7. The method of claim 1 , wherein the step of preparing a cleaning solution comprises:
providing the formulation comprising the sequestrant and the alkalinity agent;
combining the formulation with water to form the cleaning solution.
8. The method of claim 7 , wherein the formulation comprises up to about 93.7 wt % of a product stabilization solvent, from about 1 wt % to about 20 wt % of a degreaser emulsifier solvent, from about 1 wt % to about 20 wt % of a hydrotrope, from about 0.1 wt % to about 30 wt % of the sequestrant, from about 0.2 wt % to about 20 wt % of a surfactant and from about 4 wt % to about 40 wt % of the alkalinity agent all by weight of the formulation.
9. The method of claim 7 , wherein the formulation comprises from about 28.5 wt % to about 89.5 wt % of a product stabilization solvent, from about 2 wt % to about 10 wt % of a degreaser emulsifier solvent, from about 2.5 wt % to about 15 wt % of a hydrotrope, from about 0.5 wt % to about 27.5 wt % of the sequestrant, from about 0.5 wt % to about 5 wt % of a surfactant and from about 5 wt % to about 15 wt % of the alkalinity agent all by weight of the formulation.
10. The method of claim 7 , wherein the formulation comprises from about 41.5 wt % to about 81 wt % of a product stabilization solvent, from about 4 wt % to about 6 wt % of a degreaser emulsifier solvent, from about 4.5 wt % to about 12 wt % of a hydrotrope, from about 2.25 wt % to about 27 wt % of the sequestrant, from about 0.75 wt % to about 2.5 wt % of a surfactant and from about 7.5 wt % to about 11 wt % of the alkalinity agent all by weight of the formulation.
11. The method of claim 1 , wherein the step of preparing a cleaning solution comprises:
providing the formulation comprising the sequestrant;
combining the formulation and the alkalinity agent in water to form the cleaning solution.
12. The method of claim 11 , wherein the cleaning solution comprises from about 0.10 wt % to about 0.50 wt % of the formulation based on total weight of the cleaning solution.
13. The method of claim 7 , wherein the cleaning solution comprises from about 0.50 wt % to about 5.00 wt % of the formulation based on total weight of the cleaning solution.
14. The method of claim 1 , wherein the temperature of the cleaning solution is raised to a temperature above the cloud point temperature of any surfactant in the cleaning solution, in order to prevent foaming of the cleaning solution.
15. The method of claim 6 , wherein the amphoteric surfactant comprises an alkyl amino propionate, a salt of alkyl amino propionate, an alkyl amino dipropionate, a salt of alkyl amino dipropionate, or any combination thereof.
16. The method of claim 6 , wherein the nonionic surfactant comprises an alkyl polyglucoside.
17. The method of claim 11 , wherein the formulation comprises up to about 97.7 wt % of the product stabilization solvent, from about 1 wt % to about 20 wt % of the degreaser emulsifier solvent, from about 0.1 wt % to about 20 wt % of the hydrotrope, from about 0.1 wt % to about 20 wt % of the sequestrant, and from about 0.2 wt % to about 20 wt % of the surfactant all by weight of the formulation.
18. The method of claim 11 , wherein the formulation comprises from about 45 wt % to about 92.5 wt % of the product stabilization solvent, from about 3 wt % to about 12 wt % of the degreaser emulsifier solvent, from about 0.2 wt % to about 15 wt % of the hydrotrope, from about 1 wt % to about 15 wt % of the sequestrant, and from about 0.5 wt % to about 18 wt % of the surfactant all by weight of the formulation.
19. The method of claim 11 , wherein the formulation comprises from about 40 wt % to about 82.5 wt % of the product stabilization solvent, from about 8 wt % to about 10 wt % of the degreaser emulsifier solvent, from about 0.5 wt % to about 5 wt % of the hydrotrope, from about 3 wt % to about 12 wt % of the sequestrant, and from about 1 wt % to about 18 wt % of the surfactant all by weight of the formulation.
20. The method of claim 11 , wherein the formulation comprises up to about 97.7 wt % of the product stabilization solvent, from about 1 wt % to about 20 wt % of the degreaser emulsifier solvent, from about 1 wt % to about 20 wt % of the hydrotrope, from about 0.1 wt % to about 20 wt % of the sequestrant, from about 0.2 wt % to about 20 wt % of the surfactant, all by weight of the formulation.