Method of preparing acrylic adhesive and adhesive film prepared therefrom
A method of preparing an acrylic adhesive, in which the durability of an adhesive film may be improved through additional photocuring and the residual components according to solution photopolymerization are efficiently removed, and an adhesive film prepared therefrom.
1. A method of preparing an acrylic adhesive, the method comprising:
preparing a mixture including a (meth)acrylate-based monomer, a photoreactive functional group-containing (meth)acrylate-based monomer, a chain transfer agent, and a solvent;
solution photopolymerizing the mixture to form a solution including an acrylic resin, wherein the acrylic resin has a weight average molecular weight of 5,000 g/mol to 40,000 g/mol;
mixing the solution including the acrylic resin with a monomer for dilution; and then
reducing pressure to remove the solvent and any residual amount of the chain transfer agent from the solution including the acrylic resin with the monomer for dilution,
wherein the photoreactive functional group-containing (meth)acrylate-based monomer is included in an amount of 0.1 part by weight or more to 10 parts by weight or less based on 100 parts by weight of the (meth)acrylate-based monomer.
2. The method of claim 1 , wherein the photoreactive functional group-containing (meth)acrylate-based monomer comprises at least one photoreactive functional group of an acetophenone group, a benzoin group, an acylphosphine oxide group, a titanocene group, a benzophenone group, an anthracene group, or a thioxanthone group.
3. The method of claim 1 , wherein the (meth)acrylate-based monomer comprises at least one of an alkyl group-containing (meth)acrylate-based monomer, a cycloalkyl group-containing (meth)acrylate-based monomer, or a polar functional group-containing (meth)acrylate-based monomer.
4. The method of claim 3 , wherein the (meth)acrylate-based monomer comprises the alkyl group-containing (meth)acrylate-based monomer, the cycloalkyl group-containing (meth)acrylate-based monomer, and the polar functional group-containing (meth)acrylate-based monomer.
5. The method of claim 4 , wherein the (meth)acrylate-based monomer comprises:
the alkyl group-containing (meth)acrylate-based monomer in an amount of 40 parts by weight to 60 parts by weight based on 100 parts by weight of a total sum of the (meth)acrylate-based monomer,
the cycloalkyl group-containing (meth)acrylate-based monomer in an amount of 20 parts by weight to 40 parts by weight based on 100 parts by weight of the total sum of the (meth)acrylate-based monomer, and
the polar functional group-containing (meth)acrylate-based monomer in an amount of 10 parts by weight to 30 parts by weight based on 100 parts by weight of the total sum of the (meth)acrylate-based monomer.
6. The method of claim 1 , wherein the chain transfer agent is a compound including a thiol group.
7. The method of claim 1 , wherein the chain transfer agent is included in an amount of 0.5 part by weight or more to 10 parts by weight or less based on 100 parts by weight of the (meth)acrylate-based monomer.
8. The method of claim 1 , wherein the solvent is included in an amount of 15 parts by weight or more to 25 parts by weight or less based on 100 parts by weight of the (meth)acrylate-based monomer.
9. The method of claim 1 , wherein a conversion rate of the acrylic resin is 90% to 100%.
10. The method of claim 1 , wherein the pressure of the solution is reduced from atmospheric pressure to 0.1 mTorr to 0.5 mr-Torr to remove the solvent and the chain transfer agent.