Soft magnetic powder, Fe-based nanocrystalline alloy powder, magnetic component and dust core
This soft magnetic powder is represented by composition formula Fe a Si b B c P d Cu e with the exception of unavoidable impurities. In the composition formula, a, b, c, d and e satisfy 79≤a≤84.5 at %, 0≤b<6 at %, 4≤c≤10 at %, 4<d≤11 at %, 0.2≤e<0.4 at %, and a+b+c+d+e=100 at %.
1. A soft magnetic powder represented by composition formula of Fe a Si b B c P d Cu e except for inevitable impurities, wherein 79≤a≤84.5 at %, 0≤b<6 at %, 4≤c≤10 at %, 4<d≤11 at %, 0.2≤e<0.4 at % and a+b+c+d+e=100 at %,
wherein:
the soft magnetic powder is configured to be used as a starting material of an Fe-based nanocrystalline alloy powder which can be formed by applying heat-treatment to the soft magnetic powder;
the soft magnetic powder has an amorphous phase as a main phase;
the soft magnetic powder, before the heat-treatment, contains a crystal phase of at least 0.2 volume % and not more than 10 volume %;
the crystal phase consists of αFe crystals;
the soft magnetic powder includes Al, Ti, S, O and N as the inevitable impurities, the content of Al is not more than 0.1 mass % and not less than 0.001 mass %, the content of Ti is not more than 0.1 mass % and not less than 0.001 mass %, the content of S is not more than 0.1 mass % and not less than 0.002 mass %, the content of 0 is not more than 1.0 mass % and not less than 0.08 mass %, and the content of N is not more than 0.01 mass % and not less than 0.0005 mass %;
e/d is at most 0.07; and
due to the crystal phase contained in the soft magnetic powder, the soft magnetic powder represented by the composition formula is not suitable for forming a continuous strip.
2. The soft magnetic powder as recited in claim 1 , wherein 2≤b<6 at %.
3. The soft magnetic powder as recited in claim 2 , wherein 0.3≤e<0.4 at %.
4. The soft magnetic powder as recited in claim 2 , wherein 5<d≤11 at %.
5. The soft magnetic powder as recited in claim 2 , wherein not more than 3 at % of Fe is replaced with at least one element selected from Cr, V, Mn, Co, Ni, Zn, Nb, Zr, Hf, Mo, Ta, W, Ag, Au, Pd, K, Ca, Mg, Sn, C, Y and rare-earth elements.
6. The soft magnetic powder as recited in claim 1 , wherein 0.3≤e<0.4 at %.
7. The soft magnetic powder as recited in claim 6 , wherein 0.35≤e<0.4 at %.
8. The soft magnetic powder as recited in claim 7 , wherein 5<d≤11 at %.
9. The soft magnetic powder as recited in claim 7 , wherein not more than 3 at % of Fe is replaced with at least one element selected from Cr, V, Mn, Co, Ni, Zn, Nb, Zr, Hf, Mo, Ta, W, Ag, Au, Pd, K, Ca, Mg, Sn, C, Y and rare-earth elements.
10. The soft magnetic powder as recited in claim 6 , wherein 5<d≤11 at %.
11. The soft magnetic powder as recited in claim 6 , wherein not more than 3 at % of Fe is replaced with at least one element selected from Cr, V, Mn, Co, Ni, Zn, Nb, Zr, Hf, Mo, Ta, W, Ag, Au, Pd, K, Ca, Mg, Sn, C, Y and rare-earth elements.
12. The soft magnetic powder as recited in claim 1 , wherein 5<d≤11 at %.
13. The soft magnetic powder as recited in claim 1 , wherein not more than 3 at % of Fe is replaced with at least one element selected from Cr, V, Mn, Co, Ni, Zn, Nb, Zr, Hf, Mo, Ta, W, Ag, Au, Pd, K, Ca, Mg, Sn, C, Y and rare-earth elements.
14. The soft magnetic powder as recited in claim 1 , wherein the content of Al is not more than 0.01 mass % and not less than 0.001 mass %, the content of Ti is not more than 0.01 mass % and not less than 0.001 mass %, the content of S is not more than 0.05 mass % and not less than 0.002 mass %, the content of O is not more than 0.3 mass % and not less than 0.08 mass %, and the content of N is not more than 0.002 mass % and not less than 0.0005 mass %.
15. The soft magnetic powder as recited in claim 1 , wherein the soft magnetic powder contains the crystal phase of at least 0.2 volume % and not more than 3 volume %.
16. An Fe-based nanocrystalline alloy powder made by using the soft magnetic powder as recited in claim 1 as a starting material.
17. A magnetic component comprising the Fe-based nanocrystalline alloy powder as recited in claim 16 .
18. A dust core comprising the Fe-based nanocrystalline alloy powder as recited in claim 16 .