Ammonia process using advanced shift process
A process for producing an ammonia synthesis gas, said process comprising the steps of: —Reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH 4 , CO, CO 2 , H 2 and H 2 O, —Shifting the synthesis gas in one in or more shift steps in series, —Optionally wash the synthesis gas leaving the shift section with water, —Sending the process condensate originating from cooling and washing the synthesis gas leaving the shift section to a process condensate stripper wherein the dissolved shift byproducts and dissolved gases are stripped out of the process condensate using steam resulting in a steam stream containing more than 99% of the dissolved methanol in process condensate. —Adding all or part of said steam stream from the process condensate stripper to the synthesis gas downstream the reforming step, prior to the last shift step, wherein —The steam/carbon ratio in the reforming step and the shift step is less than 2.6.
1. A process for producing an ammonia synthesis gas, said process comprising the steps of:
reforming a hydrocarbon feed in a reforming section thereby obtaining a synthesis gas comprising CH 4 , CO, CO 2 , H 2 and H 2 O;
shifting the synthesis gas in a shift section comprising one or more shift steps in series;
optionally washing the synthesis gas leaving the shift section with water;
sending a process condensate originating from cooling and washing the synthesis gas leaving the shift section to a process condensate stripper, wherein dissolved shift byproducts and dissolved gases are stripped out of the process condensate using steam resulting in a steam stream; and
adding at least part of said steam stream from the process condensate stripper to the synthesis gas downstream the reforming section, upstream the last shift step,
wherein the steam/carbon ratio in the reforming step and the shift steps is less than 2.6.
2. The process according to claim 1 wherein the one and more shift steps are one or more high temperature (HT) shift steps, using a promoted zinc-aluminum oxide based catalyst, with possibility for cooling and/or steam addition in between.
3. The process according to claim 2 wherein the temperature in the high temperature shift step(s) is 300-600° C.
4. The process according to claim 1 , wherein the promoted zinc-aluminum oxide based HT shift catalyst comprises a Zn/Al molar ratio in the range 0.5 to 1.0 and a content of alkali metal in the range 0.4 to 8.0 wt % and a copper content in the range 0-10% based on the weight of oxidized catalyst.
5. The process according to claim 1 , wherein the steam/carbon ratio in the reforming step is 2.6-0.1.
6. The process according to claim 1 , wherein the reforming takes place in an autothermal reformer (ATR).
7. The process according to claim 1 , wherein the space velocity in the ATR is less than 20,000 Nm 3 C/m 3 /h.
8. The process according to claim 1 , further comprising a prereforming step.
9. The process according to claim 1 , comprising one or more additional shift steps comprising one or more high temperature shift steps, one and more medium temperature shift steps and/or one or more low temperature shift steps.
10. The process according to claim 1 , wherein steam is optionally added to the synthesis gas before the one or more additional shift steps downstream the high temperature shift step.
11. The process according to claim 1 , further comprising a CO 2 removal step removing CO 2 from the synthesis gas down to a level less than 400 vppm CO 2 .
12. The process according to claim 1 , further comprising a N 2 wash step.
13. The process according to claim 1 , wherein the steam stream contains more than 90% of the methanol dissolved in process condensate.
14. The process for producing ammonia according to claim 1 , wherein the ammonia process loop is an inert free loop.