Graphite film and manufacturing method thereof
A graphite film has a higher degree of thermal diffusion property in one in-plane direction and a method produces the graphite film. The graphite film includes a first axial direction, which is a direction having the highest thermal diffusivity in a film surface, and a second axial direction orthogonal to the first axial direction in the film surface. A value obtained by dividing the thermal diffusivity in the first axial direction by a thermal diffusivity in the second axial direction is not less than 1.020 and not more than 1.300.
1. A graphite film, including a first axial direction and a second axial direction, the first axial direction being a direction having a highest thermal diffusivity in a film surface, the second axial direction being orthogonal to the first axial direction in the film surface,
wherein a value obtained by dividing the thermal diffusivity in the first axial direction by a thermal diffusivity in the second axial direction is not less than 1.020 and not more than 1.300.
2. The graphite film according to claim 1 , wherein a percent elongation in the first axial direction obtained through measurement in a tensile test is lower than a percent elongation in the second axial direction obtained through measurement in the tensile test,
wherein in the tensile test, the measurement is carried out according to ASTM-D-882 such that a sample shaped in a size-1 dumbbell defined in JIS K 6251 is cut from the graphite film, the sample is elongated at a chuck-to-chuck distance of 100 mm, at a tension speed of 50 mm/min, and at room temperature until the sample breaks, and the percent elongation is calculated.
3. The graphite film according to claim 1 , wherein a percent elongation in the first axial direction obtained through measurement in a tensile test is not less than 0.20% and not more than 1.80%, and
a percent elongation in the second axial direction obtained through measurement in a tensile test is not less than 1.50% and not more than 4.00%,
wherein in the tensile test, the measurement is carried out according to ASTM-D-882 such that a sample shaped in a size-1 dumbbell defined in JIS K 6251 is cut from the graphite film, the sample is elongated at a chuck-to-chuck distance of 100 mm, at a tension speed of 50 mm/min, and at room temperature until the sample breaks, and the percent elongation is calculated.
4. The graphite film according to claim 1 , wherein when a peeled surface exposed by peeling a surface of the graphite film is subjected to Raman spectroscopic measurement, a peak of a D-band appears in a vicinity of 1300 cm −1 to 1400 cm −1 .
5. A method of producing a graphite film, comprising the steps of:
preparing a raw graphite film by subjecting a polymeric film to heat treatment until the raw graphite film has a thickness which is not less than 0.900 times and not more than 1.500 times a thickness of the polymeric film; and
until the graphite film has a thickness which is 0.600 times or less a thickness of the raw graphite film, compressing the raw graphite film in a state in which a tension of not less than 1.00 N/cm and not more than 20.00 N/cm is applied to the raw graphite film in one direction of the raw graphite film.
6. The method according to claim 5 , wherein the compression is carried out by rolling, and
the tension is applied in a rolling direction.
7. The method according to claim 5 , wherein the step of preparing the raw graphite film includes a step of subjecting a polymeric film to heat treatment in a state in which a tension is applied to the polymeric film in one direction of the polymeric film.
8. The method according to claim 5 , wherein a linear pressure of 1 ton or more per 200 mm of the raw graphite film is applied to the raw graphite film during the compression.