IP Library Granted Patent US 11,267,954
Granted Patent B2
US 11,267,954 · App. 16/485,244 · Granted Mar 8, 2022

Rubber composition

Inventors: Hiroki Sugimoto (Hiratsuka, JP); Tsuyoshi Nomaguchi (Hiratsuka, JP)
Assignee: The Yokohama Rubber Co., Ltd.
C08L7/00B60C1/00B60C2001/0066
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Quick Facts
Patent No.
US 11,267,954
App. No.
16/485,244
Granted
Mar 8, 2022
Kind
B2
Abstract

A rubber composition including 100 parts by mass of a diene rubber containing natural rubber, and blended with from 40 to 80 parts by mass of carbon black, cobalt neodecanoate borate represented by the following Chemical Formula (1), a phenolic resin, a curing agent, sulfur, and a vulcanization accelerator, wherein the carbon black has DBP oil absorption of from 50×10 −5 to 80×10 −5 m 3 /kg, and iodine adsorption of from 100 to 150 g/kg, and a vulcanized rubber has characteristics of a dynamic storage modulus (E′) at a dynamic strain of 2% and at 20° C. of 8 MPa or more, a tangent loss (tan δ) at 60° C. of 0.20 or less, and the number of times of repetition until fracture is caused in a constant strain fatigue test at a strain of 60% and at 400 rpm of 45,000 or more.

Claims (4)

1. A rubber composition comprising: 100 parts by mass of a diene rubber containing natural rubber and blended with from 40 to 80 parts by mass of carbon black; cobalt neodecanoate borate represented by Chemical Formula (1) present in an amount from 0.3 to 1.5 parts by mass; a phenolic resin present in amount of 0.5 parts by mass or more and less than 3.0 parts by mass; a methylene donor curing agent present in an amount from 0.5 to 5.0 parts by mass, based on 100 parts by mass of the diene rubber; sulfur; and a vulcanization accelerator, the carbon black having DBP oil absorption of from 50×10 −5 to 80×10 −5 m 3 /kg, a nitrogen absorption specific area (N 2 SA) of 90 to 115 m 2 /g, and iodine adsorption of from 100 to 150 g/kg, wherein the rubber composition formed by mixing the diene rubber, the carbon black, the cobalt neodecanoate borate, the phenolic resin, the curing agent, the sulfur, and the vulcanization accelerator has a water content of 0.25 mass % or more, and wherein when the rubber composition is vulcanized it has characteristics of a dynamic storage modulus (E′) at a dynamic strain of 2% and at 20° C. of 8 MPa or more, a tangent loss (tan δ) at 60° C. of 0.20 or less, and the number of times of repetition until fracture is caused in a constant strain fatigue test at a strain of 60% and at 400 rpm of 45,000 or more

2. The rubber composition according to claim 1 , wherein a sulfenamide-based vulcanization accelerator is present in an amount of from 0.1 to 1.0 part by mass based on 100 parts by mass of the diene rubber.

3. A pneumatic tire comprising a belt layer formed from the rubber composition according to claim 1 .

4. A pneumatic tire comprising a belt layer formed from the rubber composition according to claim 2 .

Assignments (2)
CHANGE OF ADDRESS FOR ASSIGNEE Recorded Nov 18, 2023
From: THE YOKOHAMA RUBBER CO., LTD.
To: THE YOKOHAMA RUBBER CO., LTD.
Reel/Frame 065626/0740 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 26, 2019
From: SUGIMOTO, HIROKI; NOMAGUCHI, TSUYOSHI
To: THE YOKOHAMA RUBBER CO., LTD.
Reel/Frame 050500/0669 →