Conveyor belt rubber composition, method for producing conveyor belt rubber composition, conveyor belt, and belt conveyor
An object of the present invention is to provide a conveyor belt rubber composition having excellent cut resistance and wear resistance, a method for producing the conveyor belt rubber composition, a conveyor belt formed using the conveyor belt rubber composition, and a belt conveyor equipped with the conveyor belt. The present invention relates to a conveyor belt rubber composition containing a diene rubber containing 50 mass % or more of an aromatic vinyl-conjugated diene copolymer, wherein the aromatic vinyl-conjugated diene copolymer has a content of repeating units derived from an aromatic vinyl of more than 20 mass %, and a proportion of a vinyl structure in repeating units derived from a conjugated diene of 8 mol % or less.
1. A conveyor belt rubber composition comprising a diene rubber containing 50 mass % or more of an aromatic vinyl-conjugated diene copolymer, wherein the aromatic vinyl-conjugated diene copolymer has a content of repeating units derived from an aromatic vinyl of more than 20 mass %, a proportion of a vinyl structure in the repeating units derived from a conjugated diene of 8 mol % or less, a proportion of a 1,4-cis structure in the repeating units derived from the conjugated diene of from 10 to 62 mol %, and a proportion of a 1,4-trans structure in the repeating units derived from the conjugated diene of 40 mol % or less
2. The conveyor belt rubber composition according to claim 1 , wherein the aromatic vinyl-conjugated diene copolymer has a glass transition temperature of −50° C. or lower.
3. The conveyor belt rubber composition according to claim 2 , wherein the aromatic vinyl-conjugated diene copolymer has a proportion of a 1,4-cis structure in the repeating units derived from the conjugated diene of 17 to 62 mol %.
4. The conveyor belt rubber composition according to claim 3 , wherein the proportion of the vinyl structure is 5 mol % or less.
5. The conveyor belt rubber composition according to claim 3 , wherein the proportion of the 1,4-cis structure is 60 to 62 mol %.
6. The conveyor belt rubber composition according to claim 5 , wherein the proportion of the vinyl structure is 5 mol % or less.
7. The conveyor belt rubber composition according to claim 2 , wherein the proportion of the vinyl structure is 5 mol % or less.
8. The conveyor belt rubber composition according to claim 2 , wherein the aromatic vinyl-conjugated diene copolymer is terminally modified with at least one modifier selected from the group consisting of a titanium halide, a tin halide, a cyclic silazane, an alkoxysilane, an epoxide, an amine, a ketone, and a compound represented by the formula (N),
where, R 1 represents a hydrogen atom or an alkyl group, and R 2 represents an alkylene group.
9. The conveyor belt rubber composition according to claim 1 , wherein the aromatic vinyl-conjugated diene copolymer has a proportion of a 1,4-cis structure in the repeating units derived from the conjugated diene of 17 to 62 mol %.
10. The conveyor belt rubber composition according to claim 9 , wherein the proportion of the vinyl structure is 5 mol % or less.
11. The conveyor belt rubber composition according to claim 9 , wherein the aromatic vinyl-conjugated diene copolymer is terminally modified with at least one modifier selected from the group consisting of a titanium halide, a tin halide, a cyclic silazane, an alkoxysilane, an epoxide, an amine, a ketone, and a compound represented by the formula (N),
where, R 1 represents a hydrogen atom or an alkyl group, and R 2 represents an alkylene group.
12. The conveyor belt rubber composition according to claim 9 , wherein the proportion of the 1,4-cis structure is 60 to 62 mol %.
13. The conveyor belt rubber composition according to claim 12 , wherein the proportion of the vinyl structure is 5 mol % or less.
14. The conveyor belt rubber composition according to claim 12 , wherein the aromatic vinyl-conjugated diene copolymer is terminally modified with at least one modifier selected from the group consisting of a titanium halide, a tin halide, a cyclic silazane, an alkoxysilane, an epoxide, an amine, a ketone, and a compound represented by the formula (N),
where, R 1 represents a hydrogen atom or an alkyl group, and R 2 represents an alkylene group.
15. The conveyor belt rubber composition according to claim 1 , wherein the proportion of the vinyl structure is 5 mol % or less.
16. The conveyor belt rubber composition according to claim 1 , wherein the aromatic vinyl-conjugated diene copolymer is terminally modified with at least one modifier selected from the group consisting of a titanium halide, a tin halide, a cyclic silazane, an alkoxysilane, an epoxide, an amine, a ketone, and a compound represented by the formula (N),
where, R 1 represents a hydrogen atom or an alkyl group, and R 2 represents an alkylene group.
17. A conveyor belt comprising an upper surface cover rubber layer; a reinforcing layer; and a lower surface cover rubber layer, wherein
at least the upper surface cover rubber layer is formed using the conveyor belt rubber composition described in claim 1 .
18. A belt conveyor equipped with the conveyor belt described in claim 17 .
19. A method for producing a conveyor belt rubber composition, the conveyor belt rubber composition containing a diene rubber containing 50 mass % or more of an aromatic vinyl-conjugated diene copolymer, the aromatic vinyl-conjugated diene copolymer having a content of repeating units derived from an aromatic vinyl of more than 20 mass %, a proportion of a vinyl structure in repeating units derived from a conjugated diene of 8 mol % or less, a proportion of a 1,4-cis structure in the repeating units derived from the conjugated diene of from 10 to 62 mol %, and a proportion of a 1,4-trans structure in the repeating units derived from the conjugated diene of 40 mol % or less, the method comprising: copolymerizing monomers comprising the aromatic vinyl and the diene using an initiator prepared using an organolithium compound, an alkyl aluminum, and a metal alcoholate to produce the aromatic vinyl-conjugated diene copolymer.
20. A method for producing a conveyor belt rubber composition, the conveyor belt rubber composition containing a diene rubber containing 50 mass % or more of an aromatic vinyl-conjugated diene copolymer, the aromatic vinyl-conjugated diene copolymer having a content of repeating units derived from an aromatic vinyl of more than 20 mass % and a proportion of vinyl structure in repeating units derived from a conjugated diene of 8 mol % or less, a proportion of a 1,4-cis structure in the repeating units derived from the conjugated diene of from 10 to 62 mol %, and a proportion of a 1,4-trans structure in the repeating units derived from the conjugated diene of 40 mol % or less, and being terminally modified with at least one modifier selected from the group consisting of a titanium halide, a tin halide, a cyclic silazane, an alkoxysilane, an epoxide, an amine, a ketone, and a compound represented by formula (N), the method comprising:
copolymerizing monomers comprising the aromatic vinyl and the diene using an initiator prepared using an organolithium compound, an alkylaluminum and a metal alcoholate, and then
terminating the polymerization using an electrophile selected from a titanium halide, a tin halide, a cyclic silazane, an alkoxysilane, an epoxide, an amine, a ketone, and a compound represented by formula (N) to produce the aromatic vinyl-conjugated diene copolymer,
where, R 1 represents a hydrogen atom or an alkyl group, and R 2 represents an alkylene group.