Poly(amide-imide) copolymer composition and colorless and transparent poly(amide-imide) film comprising the same
A poly(amide-imide) copolymer composition comprising an imide of a polyamic acid and an ultraviolet stabilizer, and a colorless and transparent poly(amide-imide) film including the composition. The poly(amide-imide) copolymer composition according to the present disclosure makes it possible to provide a poly(amide-imide) film exhibiting excellent scratch resistance, UV shielding property, and UV weather resistance while being colorless and transparent. This film can be suitably used as a cover film of various flexible or foldable devices.
1. A poly(amide-imide) film consisting essentially of:
a poly(amide-imide) copolymer resulting from copolymerizing an aromatic diamine monomer, an aromatic dianhydride monomer, and an aromatic dicarbonyl monomer; and
an ultraviolet stabilizer,
wherein the aromatic dicarbonyl monomer is contained in an amount of at least 50 mol % based on the total moles of the aromatic dianhydride monomer and the aromatic dicarbonyl monomer, and
the aromatic dicarbonyl monomer consists of 0 to 35 mol % of 4,4′-biphenyldicarbonyl chloride, 5 to 40 mol % of isophthaloyl chloride, and 60 to 95 mol % of terephthaloyl chloride, based on the total moles of the aromatic dicarbonyl monomer, and
wherein the film at a thickness of 50±2 μm has a pencil hardness measured according to ASTM D3363 of a 2H grade or more and a modulus of 6.5 GPa or more measured according to ASTM D882.
2. The poly(amide-imide) film of claim 1 , wherein a rate of change (dT/dλ) of light transmittance (T) with respect to a wavelength (λ) in a light transmittance range of 10% to 80% and in a wavelength range of 350 nm to 450 nm is 2.8 to 4.0 at a film thickness of 50±2 μm.
3. The poly(amide-imide) film of claim 1 , wherein a rate of change (dT/dλ) of light transmittance (T) with respect to a wavelength (λ) in a light transmittance range of 10% to 80% and in a wavelength range of 350 nm to 450 nm is 2.9 to 3.9 at a film thickness of 50±2 μm.
4. The poly(amide-imide) film of claim 1 , wherein the ultraviolet stabilizer is at least one compound selected from the group consisting of a benzophenone-based ultraviolet absorber, a benzotriazole-based ultraviolet absorber, a salicylate-based ultraviolet absorber, a cyanoacrylate-based ultraviolet absorber, a nickel complex salt ultraviolet absorber, and a hindered amine-based light stabilizer (HALS).
5. The poly(amide-imide) film of claim 1 , wherein the ultraviolet stabilizer is contained in an amount of 0.1 to 15 parts by weight based on 100 parts by weight of the poly(amide-imide)copolymer.
6. The poly(amide-imide) film of claim 1 , wherein the aromatic dianhydride monomer is contained in an amount of 25 mol % or less based on the aromatic diamine monomer.
7. The poly(amide-imide) film of claim 1 , wherein the aromatic diamine monomer is at least one compound selected from the group of 2,2′-bis(trifluoromethyl)-4,4′-biphenyldiamine and 2,2′-dimethyl-4,4′-diaminobiphenyl.
8. The poly(amide-imide) film of claim 1 , wherein the aromatic dianhydride monomer is at least one compound selected from the group of 3,3′,4,4′-biphenyltetracarboxylic acid dianhydride and cyclobutane-1,2,3,4-tetracarboxylic dianhydride.
9. The poly(amide-imide) film of claim 1 , wherein a rate of change (dT/dλ) of light transmittance (T) with respect to a wavelength (λ) in a light transmittance range of 10% to 80% and in a wavelength range of 350 nm to 450 nm is 3.0 to 3.8 at a film thickness of 50±2 μm.
10. The poly(amide-imide) film of claim 1 , wherein a rate of change (dT/dλ) of light transmittance (T) with respect to a wavelength (λ) in a light transmittance range of 10% to 80% and in a wavelength range of 350 nm to 450 nm is 3.3 to 3.5 at a film thickness of 50±2 μm.
11. The poly(amide-imide) film of claim 1 , wherein the film has an initial yellow index (YI 0 ) measured according to ASTM D1925 of 3.5 or less at a film thickness of 50±2 μm.
12. The poly(amide-imide) film of claim 11 , wherein the film at a film thickness of 50±2 μm has a coefficient of thermal expansion of 15 ppm/° C. or less.
13. The poly(amide-imide) film of claim 1 , wherein the film at a thickness of 50±2 μm has transmittance of 88.0% or more with respect to visible light having a wavelength of 550 nm, and transmittance of 15.0% or less with respect to ultraviolet light having a wavelength of 388 nm.