Separator for power storage device and method for producing same, and power storage device and method for producing same
This separator for a power storage device has a porous layer containing a polyolefin resin and surface-treated ionic compound. The ionic compound content of the porous layer is 5 to 99 mass %, and the degree of surface hydrophilicity of the ionic compound is 0.10 to 0.80.
1. A separator for electricity storage devices, which has a porous layer comprising a polyolefin resin and a surface-treated ionic compound, wherein:
the ionic compound has a content of 86% by weight or more and 99% by weight or less in the porous layer;
the degree of surface hydrophilicity of the ionic compound is 0.10 or more and 0.80 or less;
the ionic compound has one or more anions selected from the group consisting of a sulfate ion, a nitrate ion, a phosphate ion, and a halide ion; and
the ionic compound has one or more cations selected from the group consisting of an alkali metal ion and an alkaline earth metal ion.
2. The separator according to claim 1 , wherein a ratio of a weight loss of the surface-treated ionic compound at 350° C. to that at 550° C. is 0.03 or more and 0.70 or less.
3. The separator for electricity storage devices according to claim 1 , wherein the ionic compound is surface-treated with one or more selected from the group consisting of saturated fatty acid, unsaturated fatty acid, a saturated fatty acid salt, and an unsaturated fatty acid salt.
4. The separator for electricity storage devices according to claim 1 , wherein a surface treatment amount of the ionic compound is 0.1% by weight or more and 10% by weight or less based on 100% by weight of the surface-treated ionic compound.
5. The separator for electricity storage devices according to claim 1 , wherein the ionic compound is barium sulfate.
6. The separator for electricity storage devices according to claim 1 , wherein an average particle size of the ionic compound is 5 nm or more and 600 nm or less.
7. The separator for electricity storage devices according to claim 1 , wherein the polyolefin resin contains polyethylene having a viscosity-average molecular weight of 600,000 or more.
8. The separator for electricity storage devices according to claim 1 , wherein an average pore size is 10 nm or more and 150 nm or less.
9. The separator for electricity storage devices according to claim 1 , wherein an air permeability is 10 seconds/100 ml or longer and 500 seconds/100 ml or shorter.
10. The separator for electricity storage devices according to claim 1 , wherein a puncture strength is 100 gf or more and 600 gf or less.
11. An electricity storage device comprising a positive electrode, a negative electrode, and the separator for electricity storage devices according to claim 1 .
12. A method for manufacturing an electricity storage device, which comprises the following steps:
(1) a step of combining a positive electrode and a negative electrode via the separator for electricity storage devices according to claim 1 , and inserting into an outer package; and
(2) a step of injecting a nonaqueous electrolytic solution into the outer package and sealing the outer package.
13. A method for manufacturing a separator for electricity storage devices according to claim 1 , comprising extracting a plasticizer from a kneaded product containing a plasticizer having an infrared (IR) absorbance ratio A 1700 to 1800 /A 2700 of 0.01 or more and 0.25 or less, a polyolefin resin, and an ionic compound, wherein:
the ionic compound has one or more anions selected from the group consisting of a sulfate ion, a nitrate ion, a phosphate ion, and a halide ion; and
the ionic compound has one or more cations selected from the group consisting of an alkali metal ion and an alkaline earth metal ion.
14. The method for manufacturing a separator for electricity storage devices according to claim 13 , wherein a sheet molding of the kneaded product is stretched 4 times or more and 15 times or less in a machine direction (MD) and 4 times or more and 15 times or less in a transverse direction (TD).
15. The method for manufacturing a separator for electricity storage devices according to claim 13 , which comprises a step of simultaneously stretching the sheet molding of the kneaded product to MD and TD.
16. An electricity storage device comprising a positive electrode, a negative electrode, and the separator for electricity storage devices manufactured according to claim 15 .
17. A method for manufacturing an electricity storage device, which comprises the following steps:
(1) a step of combining a positive electrode and a negative electrode via the separator for electricity storage devices manufactured according to claim 15 , and inserting to an outer package; and
(2) a step of injecting a nonaqueous electrolytic solution into the outer package and sealing the outer package.