HETEROPHASIC POLYOLEFIN COMPOSITION WITH EXCELLENT OPTICAL PROPERTIES
Heterophasic polyolefin composition having an MFR of 7 to 100 g/10 min and having a Tm(1) of 150° C. or higher comprising a propylene butylene copolymer matrix phase and a rubber phase selected from ethylene/C3-C12 alpha olefin plastomers the composition being obtainable by blending A) 60.0 to 99.0 wt.-% of a propylene butylene copolymer which comprises monomer units derived from a) propylene in an amount of 88-98 wt.-% b) butylenes in an amount of 2-12 wt.-% with respect to the total weight the propylene butylene copolymer B) 1.0-40.0 wt.-% of ethylene/C3-C12 alpha olefin plastomers having a density of less than 904 kg/m 3 and optionally a nucleating agent in an amount of less than 0.25 wt.-% with respect to the total of the heterophasic composition.
1 . A heterophasic polyolefin composition having an MFR of 7 to 100 g/10 min and
having a Tm(1) of 150° C. or higher
comprising a propylene butylene copolymer matrix phase and a rubber phase selected from ethylene/C3-C12 alpha olefin plastomers the composition being obtainable by blending
A) 60.0 to 99.0 wt.-% of a propylene butylene copolymer which comprises monomer units derived from
a) propylene in an amount of 88-98 wt.-%
b) butylenes in an amount of 2-12 wt.-%
with respect to the total weight of the propylene butylene copolymer
B) 1.0-40.0 wt.-% of ethylene/C3-C12 alpha olefin plastomers having a density of less than 904 kg/m 3 and
optionally a nucleating agent in an amount of less than 0.25 wt.-% with respect to the total of the heterophasic composition.
2 . Heterophasic polyolefin composition of claim 1 ,
wherein the ethylene/C3-C12 alpha olefin plastomer is a C3C2 rubber having an ethylene content of 17 wt.-% or lower and a density of 0.88 g/cm 3 or less, further optionally an elongation at break of 2000% or more.
3 . Heterophasic polyolefin composition according to claim 2 having a tensile modulus of 900 MPa or more.
4 . Heterophasic polyolefin composition according to claim 2 having a NIS (23°) of at least 4.5 kJ/m 2 .
5 . Heterophasic polyolefin composition according to claim 2 having a haze of below 35% (1 mm plaque).
6 . Heterophasic polyolefin composition of claim 1 ,
wherein the ethylene/C3-C12 alpha olefin plastomer is a C2C8 plastomer and the C2C8 plastomer has a density of below 0.904 g/cm 3 , preferably of below 890 g/cm 3 , optionally an elongation at break of above 930% (ISO 527-2(5A), molded plaques), preferably of above 990%.
7 . Heterophasic polyolefin composition according to claim 6 having a tensile modulus of 1200 MPa or more.
8 . Heterophasic polyolefin composition according to claim 6 having a NIS (23°) of at least 4.5 kJ/m 2 .
9 . Heterophasic polyolefin composition according to claim claim 6 having a haze of below 40% (1 mm plaque).
10 . Heterophasic polyolefin composition according to any claim 1 comprising at least one nucleating agent.
11 . Heterophasic polyolefin composition according to any claim 1 , the composition further comprising a propylene homopolymer C) which is coblended in an amount of less than 2 wt.-% based on the total weight of the composition.
12 . Heterophasic polyolefin composition according to any claim 1 not containing a compatibilizer selected from the group of ethylene polymers having an ethylene content of at least 80 mol % and a density of 905 to 925 kg/m 3 , LDPE and/or Styrene Ethylene Butylene Styrene Block Copolymer(s).
13 . Process for the preparation of a heterophasic polyolefin composition according to claim 1 comprising the steps of
polymerizing a propylene butylene copolymer including monomer units derived from
a) propylene in an amount of 88-98 wt.-%
b) butylene in an amount of 2-12 wt.-%
with respect to the total weight of the propylene butylene copolymer;
in at least two reactors coupled in series using a Ziegler Natta catalyst system having citraconate as internal donor, and
an organo aluminium compound as cocatalyst and an organosilane, preferably dicyclopentyldimethoxysilane (donor D) as external donor at a Al/external donor ratio of 5.0-8.0 mol/mol and a Al/Ti ratio of 190 to 240 mol/mol,
whereby in a first reactor a pre-polymerization is carried out at 25-35° C. for 10 to 60 minutes yielding a pre-polymer, further polymerizing the pre-polymer at a temperature of 65-75° C., at a C4/C3 ratio of 115 to 145 mol/kmol yielding a first intermediate having an C4 content of 4 to 7 wt.-%,
transferring the first intermediate to a second reactor and further polymerizing at 75 to 85° C. at a C4/C3 ratio of 90 to 150 mol/kmol, to yield the second reactor product,
extruding 60.0 to 99.0 wt.-% of the second reactor product together with 1.0-40.0 wt.-% of ethylene/C3-C12 alpha olefin plastomers having a density of less than 904 kg/m 3 ,
in the presence of a nucleating agent in an amount of less than 0.25 wt.-% with respect to the total heterophasic polyolefin composition to yield the final heterophasic polyolefin composition.
14 . Article comprising the composition according to claim 1 .
15 . Use of composition according to claim 1 for injection molding and packing applications particularly thin wall packaging.