Methods of recycling silicon swarf into electronic grade polysilicon or metallurgical-grade silicon
View Patent ↗Methods of recycling silicon swarf into electronic grade polysilicon or metallurgical-grade silicon are described herein are described. In an example, a method includes cutting a silicon ingot and recovering silicon swarf having a first purity from the cutting process. The recovered silicon is purified in an upgraded metallurgical silicon process to produce electronic grade polysilicon particles having a second purity higher than the first purity. The upgraded metallurgical silicon process can include dissolving the recovered silicon particles in a molten aluminum metal smelt.
1. A method, comprising:
cutting a silicon ingot to divide the silicon ingot into a wafer portion and a silicon swarf, wherein the silicon swarf includes recovered silicon particles having a first purity and metal debris contaminants and coolant contaminants, the coolant contaminants accounting for 0.5-4% volume of the silicon swarf, and wherein the silicon ingot includes an n-type dopant or a p-type dopant; and
purifying the recovered silicon particles into electronic grade polysilicon particles having a second purity higher than the first purity, wherein purifying the recovered silicon particles includes dissolving the recovered silicon particles in a molten aluminum metal smelt.
2. The method of claim 1 , wherein cutting the silicon ingot includes sawing the silicon ingot using a diamond-wire cutting process.
3. The method of claim 1 further comprising filtering the silicon swarf to separate the recovered silicon particles from the metal debris contaminants and coolant contaminants.
4. The method of claim 1 , wherein the silicon ingot includes a p-type dopant, and wherein the electronic grade polysilicon particles includes the p-type dopant.
5. The method of claim 1 , wherein the silicon ingot includes an n-type dopant, and wherein the electronic grade polysilicon particles includes the n-type dopant.
6. The method of claim 1 , wherein the electronic grade polysilicon particles have a same resistivity as the silicon ingot.
7. The method of claim 1 , wherein the first purity is less than 4 N, and wherein the second purity is higher than 10 N.
8. A solar cell fabricated according to the method of claim 1 .
9. A method, comprising:
cutting a silicon ingot to divide the silicon ingot into a wafer portion and a silicon swarf, wherein the silicon ingot is pre-doped, and wherein the silicon swarf has metal debris contaminants and coolant contaminants, the coolant contaminants accounting for 0.5-4% volume of the silicon swarf;
compacting the silicon swarf into a silicon aggregate; and
dehydrating the silicon aggregate to form a plurality of metallurgical grade silicon particles.
10. The method claim 9 , wherein cutting the silicon ingot includes sawing the silicon ingot using a diamond-wire cutting process.
11. The method claim 9 , wherein compacting the silicon swarf includes centrifuging the silicon swarf.
12. The method claim 11 , wherein the silicon swarf is a mixture of a plurality of silicon particles and a liquid waste, and wherein centrifuging the silicon swarf separates the liquid waste from the plurality of silicon particles and compacts the plurality of silicon particles into the silicon aggregate.
13. The method claim 9 , wherein a moisture content of the silicon aggregate is at least twice a moisture content of the plurality of metallurgical grade silicon particles.
14. The method claim 13 , wherein a majority of the plurality of metallurgical grade silicon particles have a particle size at least an order of magnitude greater than a particle size of the plurality of silicon particles.
15. The method claim 14 , wherein the particle size is greater than 500 microns.
16. The method claim 14 , further comprising grinding the metallurgical grade silicon particles to reduce the particle size of the metallurgical grade silicon particles to less than 10 micron.
17. The method claim 14 , further comprising separating a first subset of the metallurgical grade silicon particles having the particle size from a second subset of the metallurgical grade silicon particles.
18. The method claim 9 , further comprising purifying the metallurgical grade silicon particles into electronic grade polysilicon particles, wherein the metallurgical grade silicon particles have a first purity and the electronic grade polysilicon particles have a second purity higher than the first purity.
19. A solar cell fabricated according to the method of claim 9 .