Method and system for controlling mercury emissions from coal-fired thermal processes
View Patent ↗The present disclosure is directed to the use of elemental or speciated iodine and bromine to control total mercury emissions.
1. A method, comprising:
selecting a mercury-containing feed material natively including mercury and halogen, the halogen comprising one or more of bromine and iodine;
contacting the mercury-containing feed material with a halogen-containing additive to form a treated feed material, the halogen-containing additive comprising one or more of bromine and iodine, wherein the one or more of bromine and iodine concentration of the treated feed material relative to a weight of the feed material is about 30 ppmw or less;
generating, from the treated feed material, a mercury-containing gas stream comprising vapor-phase mercury and vapor-phase halogen derived from the one or more of bromine and iodine; and
removing 50% or more of the mercury from the gas stream.
2. The method of claim 1 , wherein the one or more of bromine and iodine comprises bromine and wherein the mercury-containing feed material has from about 0.003 to about 100 ppmw mercury.
3. The method of claim 1 , wherein the one or more of bromine and iodine comprises iodine, wherein the halogen-containing additive facilitates the vapor-phase mercury to be removed from the mercury-containing gas stream, and wherein the mercury-containing feed material natively comprises no more than about 5 ppmw halogen.
4. The method of claim 1 , wherein the mercury-containing feed material natively has one of:
(i) no more than about 5 ppmw iodine;
(ii) no more than about 4 ppmw iodine;
(iii) no more than about 3 ppmw iodine;
(iv) no more than about 2 ppmw iodine; or
(v) no more than about 1 ppmw iodine.
5. The method of claim 1 , wherein the mercury-containing feed material comprises a high alkali, a high iron, and/or a high sulfur coal.
6. The method of claim 1 , wherein the halogen-containing additive comprises iodine.
7. The method of claim 1 , wherein the halogen-containing additive comprises at least one of an iodine containing coal, a bromine containing coal, an alkali halide, an alkaline earth halide, and a diatomic halide.
8. The method of claim 1 , wherein at least one of the following is true:
(i) the mercury-containing gas stream comprises about 3.5 ppmw or less of the vapor-phase halogen derived from the treated feed material;
(ii) in the mercury-containing gas stream, a molar ratio of the vapor-phase halogen derived from the treated feed material to the vapor-phase mercury derived from the treated feed material is no more than about 600; and
(iii) at an air preheater outlet, a concentration of the vapor-phase halogen derived from the treated feed material ranges from about 0.1 to about 10 ppmw.
9. The method of claim 1 , wherein the mercury-containing feed material is combusted in a thermal unit to produce the mercury-containing gas stream.
10. The method of claim 1 , further comprising passing the mercury-containing gas stream through a particulate removal device to form a treated gas stream free of particulates and mercury.
11. A method, comprising:
contacting a mercury-containing feed material comprising a native iodine with a halogen-containing additive to form a treated feed material having a total iodine content of about 30 ppmw or less relative to a weight of the treated feed material, wherein the halogen-containing additive comprises one or more of bromine and iodine and wherein no more than about 2 ppmw of the treated feed material iodine comprises the native iodine;
generating, from the treated feed material, a mercury-containing gas stream comprising vapor-phase mercury and vapor-phase iodine derived from the treated feed material; and
removing 50% or more of the vapor-phase mercury from the gas stream.
12. The method of claim 11 , wherein the one or more of bromine and iodine comprises iodine and wherein the mercury-containing feed material has from about 0.003 to about 100 ppmw mercury.
13. The method of claim 11 , wherein the one or more of bromine and iodine comprises bromine, wherein the mercury containing feed material natively comprises bromine, and wherein the bromine concentration is:
(i) no more than about 10 ppmw of bromine; or
(ii) no more than about 5 ppmw of bromine.
14. The method of claim 11 , wherein the halogen-containing additive comprises at least one of an iodine containing coal, an alkali iodide, an alkaline earth iodide, and diatomic iodine.
15. The method of claim 11 , wherein the halogen-containing additive comprises iodine and:
(i) no more than about 25% of halogens other than iodine;
(ii) no more than about 10% of halogens other than iodine; or
(iii) no more than about 5% of halogens other than iodine.
16. The method of claim 11 , wherein the halogen-containing additive comprises iodine and bromine.
17. The method of claim 11 , wherein at least one of the following is true:
(i) the mercury-containing gas stream comprises about 3.5 ppmw or less of the vapor-phase halogen derived from the treated feed material;
(ii) in the mercury-containing gas stream, a molar ratio of the vapor-phase halogen derived from the treated feed material to the vapor-phase mercury derived from the treated feed material is no more than about 600; and
(iii) at an air preheater outlet, a concentration of the vapor-phase halogen derived from the treated feed material ranges from about 0.1 to about 10 ppmw.
18. A method, comprising:
selecting a first mercury-containing feed material that natively includes mercury and less than about 2 ppmw iodine;
selecting a second mercury-containing feed material that natively includes mercury and greater than about 2 ppmw iodine;
mixing, in no particular order, the first mercury containing feed material, the second mercury containing feed material, and a halogen-containing additive to form a treated feed material, wherein the halogen-containing additive comprises one or more of iodine and bromine, and wherein the treated feed material has a halogen concentration relative to a weight of the treated feed material of about 30 ppmw or less;
generating, from the treated feed material, a mercury-containing gas stream comprising vapor-phase mercury and vapor-phase halogen derived from the treated feed material; and
removing 50% or more of the mercury from the gas stream.
19. The method of claim 18 , wherein the second mercury-containing feed material natively has one of:
(i) greater than about 3 ppmw iodine;
(ii) greater than about 4 ppmw iodine; or
(iii) greater than about 5 ppmw iodine.
20. The method of claim 18 , wherein the halogen-containing additive comprises iodine and the treated feed material has a total iodine concentration relative to a weight of the treated feed material of about 30 ppmw or less, and wherein the first and second mercury-containing feed materials each have from about 0.003 to about 100 ppmw mercury.
21. The method of claim 18 , wherein the halogen-containing additive comprises bromine, wherein the mercury containing feed material natively comprises bromine, and wherein the bromine concentration is:
no more than about 10 ppmw of bromine; or
no more than about 5 ppmw of bromine.
22. The method of claim 18 , wherein the treated mercury-containing feed material is combusted in a thermal unit to produce the mercury-containing gas stream and wherein the halogen-containing additive comprises iodine and:
no more than about 25% of halogens other than iodine;
no more than about 10% of halogens other than iodine; or
no more than about 5% of halogens other than iodine.
23. The method of claim 18 , wherein the halogen-containing additive comprises at least one of an alkali or alkaline earth metal iodide and diatomic iodine.
24. The method of claim 18 , further comprising passing the mercury-containing gas stream through a particulate removal device to form a treated gas stream free of particulates and mercury.
25. The method of claim 18 , wherein at least one of the following is true:
(i) the mercury-containing gas stream comprises about 3.5 ppmw or less of the vapor-phase halogen derived from the treated feed material;
(ii) in the mercury-containing gas stream, a molar ratio of the vapor-phase halogen derived from the treated feed material to the vapor-phase mercury derived from the treated feed material is no more than about 600; and
(iii) at an air preheater outlet, a concentration of the vapor-phase halogen derived from the treated feed material ranges from about 0.1 to about 10 ppmw.
26. The method claim 11 , wherein the mercury-containing feed material comprises a high alkali, a high iron, and/or a high sulfur coal.
27. The method of claim 11 , wherein the mercury-containing gas stream comprises about 3.5 ppmw or less vapor-phase iodine.
28. The method of claim 11 , wherein the mercury-containing feed material is combusted in a thermal unit to produce the mercury-containing gas stream.
29. The method of claim 11 , further comprising passing the mercury-containing gas stream through a particulate removal device to form a treated gas stream free of particulates and mercury.
30. The method of claim 11 , wherein the halogen containing additive comprises a bromine-containing salt.