Sorbents for the oxidation and removal of mercury
A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.
1. A method of separating mercury from a mercury-containing gas, the method comprising:
combusting coal in a combustion chamber, to provide the mercury-containing gas, wherein
the coal comprises added HI, an iodide salt, or a combination thereof, added to the coal before the coal enters the combustion chamber, or
the combustion chamber comprises added HI, an iodide salt, or a combination thereof, or
a combination thereof;
injecting a sorbent comprising activated carbon into the mercury-containing gas downstream of the combustion chamber, wherein a weight ratio of the HI, iodide salt, or the combination thereof added to the coal, added to the combustion chamber, or a combination thereof, to an amount of the sorbent injected into the mercury-containing gas is from about 1:100 to about 30:100;
contacting mercury in the mercury-containing gas with the sorbent; and
separating the sorbent contacted with the mercury from the mercury-containing gas.
2. The method of claim 1 , wherein the coal comprises the added HI, the iodide salt, or a combination thereof, added to the coal before the coal enters the combustion chamber.
3. The method of claim 1 , wherein the combustion chamber comprises the added HI, the iodide salt, or a combination thereof.
4. The method of claim 1 , wherein the coal is combusted in the combustion chamber at a coal-combustion facility, wherein the HI, iodide salt, or combination thereof, is added to the coal before the coal enters the combustion chamber, wherein the addition of the HI, iodide salt, or combination thereof, to the coal is performed at the coal-combustion facility.
5. The method of claim 1 , wherein the coal is combusted in the combustion chamber at a coal-combustion facility, wherein the HI, iodide salt, or combination thereof, is added to the coal, wherein the addition of the HI, iodide salt, or combination thereof, to the coal is performed at a site other than the coal-combustion facility.
6. The method of claim 1 , wherein the combustion chamber is a coal combustion chamber that is used to produce electricity.
7. The method of claim 1 , wherein the combustion chamber is a coal combustion furnace.
8. The method of claim 1 , wherein the coal comprises a subbituminous coal.
9. The method of claim 1 , wherein the coal comprises a lignite coal.
10. The method of claim 1 , further comprising
measuring the mercury content of the mercury-containing gas; and
modifying, in response to the measured mercury content of the mercury-containing gas,
an injection rate of injecting the sorbent into the mercury-containing gas,
an amount of the HI, the iodide salt, or a combination thereof, added to the coal or the combustion chamber, or
a combination thereof.
11. The method of claim 10 , wherein the measuring of the mercury content of the mercury-containing gas comprises continuous measurement.
12. The method of claim 1 , further comprising
modifying, in response to a measured mercury content,
an injection rate of injecting the sorbent into the mercury-containing gas,
an amount of the HI, the iodide salt, or a combination thereof, added to the coal or the combustion chamber, or
a combination thereof.
13. The method of claim 1 , wherein the sorbent contacted with the mercury comprises the element iodine and mercury.
14. The method of claim 1 , comprising removing greater than 70 wt % of the mercury in the mercury-containing gas.
15. The method of claim 1 , comprising removing greater than 70 wt % of the mercury in the mercury-containing gas with the sorbent.
16. The method of claim 1 , wherein the combination of the contacting of the mercury in the mercury-containing gas with the sorbent and the separating of the sorbent contacted with the mercury from the mercury-containing gas decreases the amount of elemental mercury in the mercury-containing gas.
17. The method of claim 1 , wherein the sorbent injected into the mercury-containing gas is a sorbent obtained by contacting a sorbent with a halogen or halide promoter prior to injection of the sorbent into the mercury-containing gas.
18. The method of claim 1 , wherein the sorbent injected into the mercury-containing gas is free of contact with a halogen or halide promoter prior to injection of the sorbent into the mercury-containing gas.
19. The method of claim 1 , further comprising injecting an additive comprising a compound comprising Ca, Na, or a combination thereof, into the mercury-containing gas downstream of the combustion chamber.
20. The method of claim 1 , wherein the mercury-containing gas is a flue gas.
21. The method of claim 1 , wherein the injection of the sorbent into the mercury-containing gas occurs upstream of a particulate separator or a scrubber.
22. The method of claim 21 , wherein the particulate separator is an electrostatic precipitator, a baghouse, a fabric filter, or a combination thereof.
23. The method of claim 1 , wherein the coal comprises added halide sorbent enhancement additive that comprises the HI, iodide salt, or combination thereof.
24. The method of claim 1 , wherein the coal and/or the combustion chamber comprises the iodide salt.
25. A method for reducing mercury in a mercury containing gas, the method comprising:
combusting coal in a combustion chamber, the coal comprising an additive comprising added HI, an iodide salt, or a combination thereof, to form the mercury-containing gas;
collecting mercury in the mercury-containing gas with an injected sorbent comprising activated carbon, wherein a weight ratio of the HI, iodide salt, or the combination thereof added to the coal, added to the combustion chamber, or a combination thereof, to an amount of the sorbent injected into the mercury-containing gas is from about 1:100 to about 30:100.
26. A method of separating mercury from a mercury-containing gas, the method comprising:
combusting coal in a combustion chamber, to provide the mercury-containing gas, wherein
the coal comprises added HI, an iodide salt, or a combination thereof, added to the coal before the coal enters the combustion chamber, or
the combustion chamber comprises added HI, an iodide salt, or a combination thereof, or
a combination thereof;
injecting a sorbent comprising activated carbon into the mercury-containing gas downstream of the combustion chamber such that the activated carbon reacts with the halogen or halide promoter in the mercury-containing gas to form a promoted sorbent, wherein a weight ratio of the HI, iodide salt, or the combination thereof added to the coal, added to the combustion chamber, or a combination thereof, to an amount of the sorbent injected into the mercury-containing gas is from about 1:100 to about 30:100;
contacting mercury in the mercury-containing gas with the promoted sorbent;
separating the promoted sorbent contacted with the mercury from the mercury-containing gas;
measuring the mercury content of the mercury-containing gas; and
modifying, in response to the measured mercury content of the mercury-containing gas,
an injection rate of injecting the sorbent into the mercury-containing gas,
an amount of the HI, the iodide salt, or a combination thereof, added to the coal or the combustion chamber, or
a combination thereof.