Methods and systems for decolorizing textile materials
Provided herein is a method for decolorizing textile materials under hydrothermal conditions using dye adsorbent materials. The process is non-toxic and environmentally friendly, and the adsorbent materials can be repeatedly used. The textile materials are textile materials dyeable with disperse dyes. Further provided is a system for decolorizing textile materials. The decolorization system is designed to allow the adsorbent materials to react with the textile materials in a contact manner and a non-contact manner.
1. A decolorization system for decolorizing textile materials, comprising:
a decolorization reactor ( 1 ) for treating the textile materials under hydrothermal conditions so as to at least partially decolorize the textile materials, wherein the decolorization reactor is provided with a feed inlet ( 11 ) and an outlet ( 12 ) and is configured to accommodate water, the textile materials and optional dye adsorbent materials;
a heating device ( 2 ) for providing a heat source to the decolorization reactor;
a filtration device ( 3 ) for filtering and collecting the at least partially decolorized textile materials, wherein the filtration device ( 3 ) is connected to the outlet ( 12 ) of the decolorization reactor ( 1 ) via a first valve ( 4 ), wherein:
(i) in the case where the decolorization reactor ( 1 ) is configured to accommodate water, the textile materials and the dye adsorbent materials, the decolorization further comprises:
a separation device ( 7 ) for separating and collecting the dye adsorbent materials; or
(ii) in the case where the decolorization reactor ( 1 ) is configured to accommodate water and the textile material, the decolorization system further comprises:
an adsorption device ( 31 ) configured to accommodate the dye adsorbent materials, wherein the adsorption device ( 31 ) is in fluid communication with the decolorization reactor ( 1 ) so as to receive a liquid containing dye molecules desorbed from the textile materials collected from the decolorization reactor ( 1 ), and to allow the dye adsorbent materials to contact with the liquid.
2. The decolorization system according to claim 1 further comprising:
a stirring device ( 8 ) for promoting the dye molecules within the textile materials being separated from the textile materials and dispersed into water, wherein the stirring device ( 8 ) comprises a stirrer ( 5 ) and optionally an ultrasonic probe ( 6 ).
3. The decolorization system according to claim 1 , wherein the separation device ( 7 ) is disposed outside the decolorization reactor ( 1 ) and comprises at least one magnetic field generator, and the dye adsorbent materials are magnetized dye adsorbent materials.
4. The decolorization system according to claim 1 , wherein:
the adsorption device ( 31 ) is disposed in a circulation loop that is in fluid communication with the decolorization reactor ( 1 ), and the circulation loop further comprises a liquid collector ( 21 ) and at least one circulation pump ( 22 , 32 ), wherein the liquid collector ( 21 ), the at least one circulation pump ( 22 , 32 ) and the adsorption device ( 31 ) are in fluid communication.
5. The decolorization system according to claim 4 , wherein:
the circulation loop comprises a first circulation loop ( 20 ) and a second circulation loop ( 30 ), wherein,
the first circulation loop ( 20 ) comprises the liquid collector ( 21 ) and a first circulation pump ( 22 ), and the first circulation loop ( 20 ) is in fluid communication with the decolorization reactor ( 1 ); and
the second circulation loop ( 30 ) comprises the adsorption device ( 31 ), a second circulation pump ( 32 ) and optionally an observation hole ( 33 ), and the second circulation loop ( 30 ) is in fluid communication with the liquid collector ( 21 ).
6. The decolorization system according to claim 1 , wherein the adsorption device ( 31 ) comprises at least one adsorption column ( 34 ), and a second valve ( 35 ) and a third valve ( 36 ) connected to both ends of the adsorption column ( 34 ), wherein the adsorption column ( 34 ) is configured to accommodate the dye adsorbent materials.
7. The decolorization system according to claim 1 , wherein the heating device ( 2 ) is one of a steam heating device, an electric heating device, a microwave heating device or any combination thereof.