IP Library Granted Patent US 10,981,374
Granted Patent B2
US 10,981,374 · App. 16/524,830 · Granted Apr 20, 2021

Ejector device

Inventors: David K. Biegelsen (Portola Valley, CA); Timothy D. Stowe (Alameda, CA); Mandana Veiseh (Piedmont, CA)
Assignee: Palo Alto Research Center Incorporated
B33Y30/00B29C64/112
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Quick Facts
Patent No.
US 10,981,374
App. No.
16/524,830
Granted
Apr 20, 2021
Kind
B2
Abstract

An ejector device that includes one or more ejectors comprises an ejector layer that spans at least one hollow area. The ejector layer has a first surface and an opposing second surface arranged to receive a viscous material with viscosity between 20 and 50,000 centipoise. The ejector layer includes a radiation absorber material configured to thermally expand without phase transition in response to heating by activation radiation transmitted to the first surface. Thermal expansion of the ejector layer causes displacement of the ejector layer and ejection of the material from the second surface of the ejector layer.

Claims (29)

1. A method, comprising:

depositing a base layer on a substrate;

patterning the base layer to form at least one sacrificial region;

conformally coating the sacrificial region with an ejector layer; and

etching the sacrificial region to form an ejector mesa comprising the ejector layer spanning a hollow area, wherein the ejector layer is configured to thermally expand without phase transition in response to heating by activation radiation, the thermal expansion of the ejector layer sufficient to cause ejection of a droplet of viscous material from the ejector layer; and wherein the ejector layer comprises multiple layers including a first layer having a first coefficient of thermal expansion, CTE1, and a second layer having a second coefficient of thermal expansion, CTE2, wherein CTE2>CTE1.

2. The method of claim 1 , wherein patterning the base layer comprises depositing a photoresist material on the base layer.

3. The method of claim 2 , further comprising:

irradiating the photoresist through a patterned mask; and

etching non-irradiated portions of the photoresist material.

4. The method of claim 3 , further comprising before conformally coating the sacrificial region with the ejector layer, forming a pinhole in a portion of the irradiated photoresist material and etching a portion of the sacrificial region through the pinhole, the etched portion of the sacrificial region having a convex surface.

5. The method of claim 4 , wherein etching the sacrificial region to form an ejector mesa comprises etching the sacrificial region to form a convex ejector mesa.

6. The method of claim 1 , wherein depositing the base layer on the substrate comprises depositing a first base layer on the substrate and depositing a second base layer on the first base layer.

7. The method of claim 1 , wherein patterning the base layer comprises patterning the first base layer into a first pattern and patterning the second base layer into a second pattern.

8. The method of claim 7 , wherein the first pattern is different than the second pattern.

9. The method of claim 7 , wherein patterning the first base layer and the second base layer comprises selectively etching the first base layer and the second base layer.

10. The method of claim 9 , further comprising selectively etching the second base layer to form the second pattern before selectively etching the first base layer to form the first pattern.

11. The method of claim 1 , further comprising forming one or more vias through the substrate, wherein etching the sacrificial mesa comprises etching the sacrificial mesa through the one or more vias.

12. The method of claim 1 , wherein patterning the base layer comprises using one or more of flexography and lithography.

13. A method, comprising:

depositing a base layer on a substrate;

depositing a photoresist material on the base layer;

irradiating the photoresist through a patterned mask; etching non-irradiated portions of the photoresist material and the base layer at least one sacrificial region; conformally coating the sacrificial region with an ejector layer; and etching the sacrificial region to form an ejector mesa comprising the ejector layer spanning a hollow area, wherein the ejector layer is configured to thermally expand without phase transition in response to heating by activation radiation, the thermal expansion of the ejector layer sufficient to cause ejection of a droplet of viscous material from the ejector layer; and wherein the ejector layer comprises multiple layers including a first layer having a first coefficient of thermal expansion, CTE1, and a second layer having a second coefficient of thermal expansion, CTE2, wherein CTE2>CTE1.

14. The method of claim 13 , further comprising before conformally coating the sacrificial region with the ejector layer, forming a pinhole in a portion of the irradiated photoresist material and etching a portion of the sacrificial region through the pinhole, the etched portion of the sacrificial region having a convex surface.

15. The method of claim 14 , wherein etching the sacrificial region to form an ejector mesa comprises etching the sacrificial region to form a convex ejector mesa.

16. The method of claim 13 , wherein depositing the base layer on the substrate comprises depositing a first base layer on the substrate and depositing a second base layer on the first base layer.

17. The method of claim 13 , wherein patterning the base layer comprises patterning the first base layer into a first pattern and patterning the second base layer into a second pattern.

18. The method of claim 17 , wherein the first pattern is different than the second pattern.

19. The method of claim 17 , wherein patterning the first base layer and the second base layer comprises selectively etching the first base layer and the second base layer.

20. The method of claim 13 , further comprising forming one or more vias through the substrate, wherein etching the sacrificial mesa comprises etching the sacrificial mesa through the one or more vias.

Assignments (9)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 14, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073562/0677 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →
Continuity (2)
Division 14576159 · Dec 18, 2014
Related Publication 20190351668A1 · Nov 21, 2019