Electrolytic on-site generator
Method and apparatus for a low maintenance, high reliability on-site electrolytic generator incorporating automatic cell monitoring for contaminant film buildup, as well as automatically removing or cleaning the contaminant film. This method and apparatus preferably does not require human intervention to clean. For high current density cells, cleaning is preferably performed by reversing the polarity of the electrodes and applying a lower current density to the electrodes, preferably by adjusting the salinity or brine concentration of the electrolyte while keeping the voltage constant. Electrolyte flow preferably comprises water and brine flows which are preferably separately monitored and automatically adjusted. For bipolar cells, flow between modules arranged in parallel is preferably approximately equally distributed between modules and between intermediate electrodes within each module.
1. A bipolar electrolytic cell for producing an oxidant, comprising:
a plurality of modules arranged in parallel, each module comprising primary electrodes and one or more intermediate electrodes and each module defining an inlet end having an inlet;
a manifold for distributing electrolyte substantially evenly between each module;
a flow barrier in each module, the flow barrier positioned to deflect fluid entering the module from the inlet of the module toward a distribution area defined within the module; and wherein
(i) an intermediate electrode has an extension beneath which extension electrolyte can flow, or
(ii) an intermediate electrode has an opening formed therein, through which opening electrolyte can flow;
wherein a general flow direction of electrolyte in each module is parallel to the electrodes.
2. The bipolar electrolytic cell of claim 1 , wherein the flow barrier blocks electrolyte entering each module from flowing directly between the electrodes.
3. The bipolar electrolytic cell of claim 1 , wherein an intermediate electrode has an extension beneath which extension electrolyte can flow beneath the intermediate electrode.
4. The bipolar electrolytic cell of claim 1 , wherein an intermediate electrode has an opening formed therein, through which opening electrolyte can flow.
5. The bipolar electrolytic cell of claim 1 , wherein a module of the plurality of modules comprises a gasket that comprises one or more grooves for receiving and holding the intermediate electrodes.
6. The bipolar electrolytic cell of claim 5 wherein the gasket comprises chlorinated polyvinyl chloride (CPVC).
7. The bipolar electrolytic cell of claim 5 , wherein the gasket is replaceable by a different size gasket, thereby enabling a single module housing to accommodate different sizes of intermediate electrodes.
8. The bipolar electrolytic cell of claim 1 , wherein the openings of an intermediate electrode of a module of the plurality of modules are staggered or offset from openings in an adjacent intermediate electrode of the module.
9. A method of operating a bipolar electrolytic cell, the method comprising:
with a manifold, substantially evenly distributing a flow of electrolyte entering the electrolytic cell between a plurality of modules arranged in parallel,
each module comprising primary electrodes and one or more intermediate electrodes,
each module comprising an inlet and a flow barrier located inside the module, the flow barrier deflecting fluid entering the module from the inlet of the module toward a distribution area defined within the module, and
each module being configured for electrolyte flow generally parallel to the electrodes of the module;
distributing a flow of electrolyte entering each module with a distribution area defined within each module such that the electrolyte flow is substantially even between one or more intermediate electrodes present in each module;
mixing the electrolyte flows (i) between the intermediate electrodes in a space between intermediate electrodes of a module or (ii) through one or more openings present in one or more of the intermediate electrodes; and
flowing the electrolyte in a direction generally parallel to the intermediate electrodes.
10. The method of claim 9 , wherein the distributing comprises blocking electrolyte entering each module from flowing directly between the intermediate electrodes.
11. The method of claim 9 , further comprising:
selecting a low threshold amount of oxidant in an oxidant tank, which amount signals initiation of electrolysis; and
initiating electrolysis of the electrolyte when an oxidant amount in the oxidant tank is higher than the low threshold amount.