IP Library Granted Patent US 11,124,745
Granted Patent B2
US 11,124,745 · App. 16/552,022 · Granted Sep 21, 2021

Composition for use in cleaning metal components

Inventor: Jacob Bonta (Lexington, KY)
Assignee: VALVOLINE LICENSING AND INTELLECTUAL PROPERTY LLC
C11D11/0029C11D7/5018C11D7/5022
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Quick Facts
Patent No.
US 11,124,745
App. No.
16/552,022
Granted
Sep 21, 2021
Kind
B2
Abstract

A composition for use in cleaning metal components having Hansen Solubility Parameters for the composition of δ D ≥15, δ P <6, and δ H from about 5.5 to about 6.9. The composition includes a blend of organic solvents, none of which are classified as a volatile organic compound, a hazardous air pollutant, or a potential carcinogen, or exhibit a vapor pressure of less than 0.1 mmHg at 20° C. Further, the blend of organic solvents includes a halogenated aromatic solvent having one or more halide groups and from 6 to 8 carbon atoms, an organic solvent having one or more ester functional group and from 3 to 9 carbon atoms, and one or more of a linear or branched hydrocarbon solvent with 6-12 carbon atoms with a single polar moiety head group or a solvent containing one or more ketone functional groups and from 2 to 5 carbon atoms.

Claims (31)

1. A composition for use in cleaning metal components, wherein the Hansen Solubility Parameters for the composition are δ D from about 12.0 to about 16.0, δ P from about 3.0 to about 10.0, and δ H from about 4.0 to about 6.9, and wherein the composition comprises a blend of organic solvents, wherein none of the solvents are classified as a volatile organic compound, wherein the blend of organic solvents comprises:

a halogenated aromatic solvent having one or more halide groups and from 6 to 8 carbon atoms, wherein the Hansen Solubility Parameters for the halogenated aromatic solvent are in the range of about δ D : 17-19, δ P : 5-7, and δ H : 3-5;

an organic solvent having one or more ester functional group and from 3 to 9 carbon atoms, wherein the Hansen Solubility Parameters for the organic solvent are in the range of about δ D : 14-16, δ P : 3.5-7.5, and δ H : 5-10; and one or more of the following:

a linear or branched hydrocarbon solvent with 6-12 carbon atoms with a single polar moiety head group, wherein the Hansen Solubility Parameters for the hydrocarbon solvent are in the range of about δ D : 6-9, δ P : 1-3, and δ H : 5-7; and

a solvent containing one or more ketone functional groups and from 2 to 5 carbon atoms, wherein the Hansen Solubility Parameters for the solvent containing one or more ketone functional groups are in the range of about δ D : 14-16, δ P : 8.5-11, and δ H : 5-8.

2. The composition of claim 1 , wherein the halogenated aromatic solvent is parachlorobenzotrifluoride, and wherein the parachlorobenzotrifluoride is present in an amount from about 0.25% to about 20% of the composition.

3. The composition of claim 1 , wherein the organic solvent with one or more ester functional groups is selected from the group consisting of tert-butyl acetate, methyl acetate, dimethyl carbonate, diethylene glycol monoethyl acetate, and diethylene glycol monobutyl ether acetate.

4. The composition of claim 3 , wherein the organic solvent with one or more ester functional groups is tert-butyl acetate, and wherein the tert-butyl acetate is present in an amount from about 15% to about 95% of the composition.

5. The composition of claim 1 , wherein the hydrocarbon solvent having a single polar moiety head group is 1-butoxyhexanol or 2-ethyl-hexanol, and wherein the hydrocarbon solvent is present in an amount from about 0.1% to about 2.5% of the composition.

6. The composition of claim 1 , wherein the solvent containing one or more ketone functional groups is acetone, and where in the acetone is present in an amount from about 5% to about 75% of the composition.

7. The composition of claim 6 , wherein the organic solvent with one or more ester functional groups is selected from the group consisting of tert-butyl acetate, methyl acetate, dimethyl carbonate, diethylene glycol monoethyl acetate, and diethylene glycol monobutyl ether acetate.

8. The composition of claim 7 , wherein the organic solvent with one or more ester functional groups is tert-butyl acetate.

9. The composition of claim 6 , wherein the composition further comprises a hydrocarbon solvent having a single polar moiety head group, and wherein the hydrocarbon solvent is 1-butoxyhexanol or 2-ethyl-hexanol.

10. A composition for use in cleaning metal components, wherein the Hansen Solubility Parameters for the composition are δ D ≥15, δ P <6, and δ H from about 5.5 to about 6.9, and wherein the composition comprises a blend of organic solvents, and wherein either none of the solvents are classified as a volatile organic compound, a hazardous air pollutant, or Potential Carcinogen, or wherein the organic solvent exhibits a vapor pressure of less than 0.1 mmHg at 20° C., the blend of organic solvents comprising:

from about 1% to about 9% parachlorobenzotrifluoride; and from about 25% to about 70% tert-butyl acetate; and one or more of the following:

from about 0.1 to about 1% 2-ethylhexanol, and

from about 5% to about 75% acetone.

11. The composition of claim 10 , wherein the composition comprises both 2-ethylhexanol and acetone.

12. The composition of claim 11 , wherein the composition comprises about 25% to about 29% acetone, about 65% to about 67.5% t-butyl acetate, about 1% to about 2.5% parachlorobenzotrifluoride, and about 1% 2-ethylhexanol.

13. A composition for use in cleaning metal components, wherein the Hansen Solubility Parameters for the composition are δ D from about 12.0 to about 16.0, δ P from about 3.0 to about 10.0, and δ H from about 4.0 to about 6.9, and wherein the composition comprises a blend of organic solvents, wherein either none of the solvents are classified as a volatile organic compound, a hazardous air pollutant, or a potential carcinogen, or wherein the solvent exhibits a vapor pressure of less than 0.1 mmHg at 20° C., wherein the blend of organic solvents comprises:

a halogenated aromatic solvent is parachlorobenzotrifluoride present in an amount from about 0.25% to about 20% of the composition, and wherein the Hansen Solubility Parameters for the halogenated aromatic solvent are in the range of about δ D : 17-19, δ P : 5-7, and δ H : 3-5;

an organic solvent having one or more ester functional group and from 3 to 9 carbon atoms, wherein the Hansen Solubility Parameters for the organic solvent are in the range of about δ D : 14-16, δ P : 3.5-7.5, and δ H : 5-10; and one or more of the following:

a linear or branched hydrocarbon solvent with 6-12 carbon atoms with a single polar moiety head group, wherein the Hansen Solubility Parameters for the hydrocarbon solvent are in the range of about δ D : 6-9, δ P : 1-3, and δ H : 5-7; and

a solvent containing one or more ketone functional groups and from 2 to 5 carbon atoms, wherein the Hansen Solubility Parameters for the solvent containing one or more ketone functional groups are in the range of about δ D : 14-16, δ P : 8.5-11, and δ H : 5-8.

14. The composition of claim 13 , wherein the organic solvent with one or more ester functional groups is selected from the group consisting of tert-butyl acetate, methyl acetate, dimethyl carbonate, diethylene glycol monoethyl acetate, and diethylene glycol monobutyl ether acetate.

15. The composition of claim 14 , wherein the organic solvent with one or more ester functional groups is tert-butyl acetate, and wherein the tert-butyl acetate is present in an amount from about 15% to about 95% of the composition.

16. The composition of claim 13 , wherein the hydrocarbon solvent having a single polar moiety head group is 1-butoxyhexanol or 2-ethyl-hexanol, and wherein the hydrocarbon solvent is present in an amount from about 0.1% to about 2.5% of the composition.

17. The composition of claim 13 , wherein the solvent containing one or more ketone functional groups is acetone, and where in the acetone is present in an amount from about 5% to about 75% of the composition.

18. The composition of claim 17 , wherein the organic solvent with one or more ester functional groups is selected from the group consisting of tert-butyl acetate, methyl acetate, dimethyl carbonate, diethylene glycol monoethyl acetate, and diethylene glycol monobutyl ether acetate.

19. The composition of claim 18 , wherein the organic solvent with one or more ester functional groups is tert-butyl acetate.

20. The composition of claim 17 , wherein the composition further comprises a hydrocarbon solvent having a single polar moiety head group, and wherein the hydrocarbon solvent is 1-butoxyhexanol or 2-ethyl-hexanol.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2023
From: VALVOLINE LICENSING AND INTELLECTUAL PROPERTY LLC
To: VGP IPCO LLC
Reel/Frame 063411/0655 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 28, 2023
From: VALVOLINE LICENSING AND INTELLECTUAL PROPERTY LLC
To: VGP IPCO LLC
Reel/Frame 063174/0450 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 27, 2019
From: BONTA, JACOB
To: VALVOLINE LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 050179/0125 →
Continuity (1)
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