Quantum dot color filter ink compositions and devices utilizing the same
Liquid ink compositions containing quantum dots for optoelectronic display applications are provided. Also provided are solid films formed by drying the ink compositions, optical elements incorporating the solid films, display devices incorporating the optical elements, and methods of forming the solid films, optical elements, and the devices. Liquid ink compositions and solid films made by drying the liquid ink compositions include one or more blue light-absorbing materials in combination with red light-emitting QDs or green light-emitting QDs.
1. An optoelectronic display device comprising:
a blue light-emitting backlight unit;
an array of pixels in the optical path of the backlight unit, the array of pixels comprising at least one red sub-pixel, at least one green sub-pixel, and at least one blue sub-pixel; and
a first solid film comprising red-emitting quantum dots and a blue light-absorbing material in a red sub-pixel, a second solid film comprising green-emitting quantum dots and a blue light-absorbing material in a green sub-pixel, or both, wherein the blue light-absorbing material is characterized in that it preferentially absorbs blue light relative to red light or green light, wherein the first solid film, the second solid film, or both, has an optical density, at a wavelength of 450 nm, of at least 1.3.
2. The device of claim 1 , wherein each of the first solid film and the second solid film further comprises scattering particles.
3. The device of claim 1 , wherein the blue light-absorbing material comprises organic molecules.
4. The device of claim 3 , wherein the organic molecules comprise coumarin molecules.
5. The device of claim 1 , wherein the blue light-absorbing material comprises an inorganic material.
6. The device of claim 1 , wherein the blue light-absorbing material comprises a luminophor.
7. The device of claim 6 , wherein the blue light-absorbing material is selected from phosphorescent dopant molecules, fluorescent dopant molecules, phosphorescent polymer molecules, fluorescent polymer molecules, semiconductor quantum dots, lanthanide-containing compounds, polycyclic aromatic hydrocarbons, and combinations of two or more thereof.
8. The device of claim 1 , wherein the blue light-absorbing material transfers energy to the red-emitting quantum dots or the green-emitting quantum dots when the device is in operation.
9. The device of claim 1 , wherein the blue light-absorbing material is present in each of the red sub-pixel, the green sub-pixel, or both, in a concentration gradient with a higher concentration of the blue light-absorbing material at the light output side of the sub-pixel than at the light input side of the sub-pixel.
10. An optoelectronic display device comprising:
a blue light-emitting backlight unit;
an array of pixels in the optical path of the backlight unit, the array of pixels comprising at least one red sub-pixel, at least one green sub-pixel, and at least one blue sub-pixel; and
a first solid film comprising red-emitting quantum dots and a blue light-absorbing material in a red sub-pixel, a second solid film comprising green-emitting quantum dots and a blue light-absorbing material in a green sub-pixel, or both, wherein the blue light-absorbing material is characterized in that it preferentially absorbs blue light relative to red light or green light, and the blue light-absorbing material is a (meth)acrylate polymer containing one or more blue light-absorbing components, wherein the material of the red sub-pixel and the green sub-pixel has an optical density, at a wavelength of 450 nm, of at least 0.3.
11. The device of claim 10 , wherein the one or more blue light-absorbing components are selected from the group consisting of phosphorescent dopant molecules, fluorescent dopant molecules, fluorescent polymer molecules, phosphorescent polymer molecules, semiconductor quantum dots, lanthanide-containing compounds, polycyclic aromatic hydrocarbons, and combinations of two or more thereof.
12. The device of claim 11 , wherein the material of the red sub-pixel and the green sub-pixel has an optical density, at a wavelength of 450 nm, of at least 1.0.
13. The device of claim 10 , wherein the one or more blue light-absorbing components comprises organic molecules.
14. The device of claim 10 , wherein the (meth)acrylate polymer is a polymerization product of di(meth)acrylate molecules.
15. The device of claim 10 , wherein the one or more blue light-absorbing components comprises coumarin.
16. The device of claim 10 , wherein the pixels or each of the first solid film and the second solid film further comprise light-scattering particles.
17. The device of claim 10 , wherein the blue light-absorbing material is present in each of the red sub-pixel, the green sub-pixel, or both, in a concentration gradient with a higher concentration of the blue light-absorbing material at the light output side of the sub-pixel than at the light input side of the sub-pixel.
18. An optoelectronic display device comprising:
a blue light-emitting backlight unit;
an array of pixels in the optical path of the backlight unit, the array of pixels comprising at least one red sub-pixel, at least one green sub-pixel, and at least one blue sub-pixel; and
a first solid film comprising red-emitting quantum dots and a blue light-absorbing material in a red sub-pixel, a second solid film comprising green-emitting quantum dots and a blue light-absorbing material in a green sub-pixel, or both, wherein the blue light-absorbing material is characterized in that it preferentially absorbs blue light relative to red light or green light, and the blue light-absorbing material is a (meth)acrylate polymer containing one or more organic blue light-absorbing molecules, wherein each of the first solid film and the second solid film, or the pixels, comprise light-scattering particles, wherein the material of the red sub-pixel and the green sub-pixel has an optical density, at a wavelength of 450 nm, of at least 1.0.
19. The device of claim 18 , wherein the one or more blue light-absorbing components are selected from the group consisting of phosphorescent dopant molecules, fluorescent dopant molecules, fluorescent polymer molecules, phosphorescent polymer molecules, polycyclic aromatic hydrocarbons, and combinations of two or more thereof.
20. The device of claim 18 , wherein the blue light-absorbing material is present in each of the red sub-pixel, the green sub-pixel, or both, in a concentration gradient with a higher concentration of the blue light-absorbing material at the light output side of the sub-pixel than at the light input side of the sub-pixel.