High-speed moisture-cure hybrid siloxane/silsesquioxane-urethane and siloxane/silsesquioxane-epoxy systems with adhesive properties
Materials containing the reaction products of a cyclic azasilane with water and a compound or polymer containing an isocyanate or epoxy functional group and methods for their synthesis are provided. Stable mixtures containing a cyclic azasilane and a compound or polymer containing an isocyanate or epoxy functional group according to invention are stored under anhydrous conditions. The invention also provides a novel class of materials, mono and bis(cycloaza)disiloxanes comprising one or two cyclic structures bridged by an Si—O—Si bond.
1. A material comprising a reaction product of a cyclic azasilane with water and a compound or polymer comprising an isocyanate functional group, wherein the cyclic azasilane is selected from azasilanes having the following structures:
2. A material comprising a reaction product of a cyclic azasilane with water and a compound or polymer comprising an epoxy functional group, wherein the cyclic azasilane is selected from azasilanes having the following structures:
3. A compound bis(n-butyl-1-methoxycycloaza-1-silacyclopentyl)ether.
4. A compound N-butyl-1-methoxy-1-(n-butylaminopropyldimethoxysiloxy)cycloazasilane.