Methods for treating a flue gas stream using a wet scrubber unit
Sorbent compositions, comprising a solid sorbent, a dispersive agent, and optionally a capture agent for enhanced wet-Flue Gas Desulfurization (wFGD) or wet scrubber unit function in a flue gas pollutant control stream is disclosed. The sorbent composition may include a sorbent with a dispersive agent, designed to enhance the dispersion of the sorbent in an aqueous sorption liquid of a wet scrubber unit, and therefore may be especially useful in EGU or industrial boiler flue gas streams that include one or more wet scrubber units. The sorbent composition may also include a capture agent useful in sequestering mercury and bromine, as well as other contaminants that may include arsenic, selenium and nitrates.
1. A wet scrubber unit disposed in a flue gas train, the wet scrubber unit containing an aqueous sorption liquid, wherein the aqueous sorption liquid comprises:
water;
an alkaline compound dispersed in the water;
a solid sorbent; and
a dispersive agent,
wherein the solid sorbent is dispersed throughout the aqueous sorption liquid.
2. The wet scrubber unit recited in claim 1 , wherein the alkaline compound comprises limestone.
3. The wet scrubber unit recited in claim 1 , wherein the solid sorbent comprises a carbonaceous sorbent.
4. The wet scrubber unit recited in claim 3 , wherein the carbonaceous sorbent comprises activated carbon.
5. The wet scrubber unit recited in claim 1 , wherein the dispersive agent is selected from the group consisting of dispersants, deflocculants, surfactants, wetting agents, coupling agents and mixtures thereof.
6. The wet scrubber unit recited in claim 5 , wherein the dispersive agent comprises at least one of the deflocculants.
7. The wet scrubber unit recited in claim 6 , wherein the dispersive agent comprises a phosphate salt.
8. The wet scrubber unit recited in claim 7 , wherein the phosphate salt comprises tri-sodium phosphate.
9. The wet scrubber unit recited in claim 1 , wherein the dispersive agent is disposed on the solid sorbent.
10. The wet scrubber unit recited in claim 9 , wherein the dispersive agent is coated on the solid sorbent.
11. The wet scrubber unit recited in claim 1 , wherein the aqueous sorption liquid comprises a capture agent.
12. The wet scrubber unit recited in claim 11 , wherein the capture agent is selected from the group consisting of peroxides, persulfates, silver compounds and mixtures thereof.
13. The wet scrubber unit recited in claim 12 , wherein the capture agent comprises ammonium persulfate.
14. The wet scrubber unit recited in claim 12 , wherein the capture agent comprises a silver compound, the silver compound comprising a silver salt.
15. The wet scrubber unit recited in claim 14 , wherein the silver salt comprises silver nitrate.