Multilayer anode and lithium secondary battery including the same
A multilayer anode includes an anode collector, and a plurality of anode mixture layers sequentially stacked on at least one surface of the anode collector, and including natural graphite as an anode active material. A weight ratio of the natural graphite in innermost and outermost anode mixture layers is greater than a weight ratio of the natural graphite in an anode mixture layer located between the innermost and outermost anode mixture layers, in a stacking direction of the plurality of anode mixture layers. Performance of a cell may be improved and calendering-calender contamination occurring in a calendering process and an electrode stripping phenomenon may be prevented.
1. A multilayer anode comprising:
an anode collector; and
a plurality of anode mixture layers sequentially stacked on at least one surface of the anode collector,
wherein an innermost anode mixture layer and an outermost anode mixture layer of the anode mixture layers comprise natural graphite as an anode active material,
wherein an anode mixture layer located between the innermost anode mixture layer and the outermost anode mixture layer comprises a carbon material as anode active material,
wherein among the plurality of anode mixture layers, a weight ratio of the natural graphite in the innermost anode mixture layer over the total active material of the innermost anode mixture layer and a weight ratio of the natural graphite in the outermost anode mixture layer over the total anode active material of the outermost anode mixture layer are each greater than a weight ratio of natural graphite in the anode mixture layer located between the innermost and outermost anode mixture layers over the total anode active material of the anode mixture layer located between the innermost and outermost anode mixture layers, in a stacking direction.
2. The multilayer anode of claim 1 , wherein the plurality of anode mixture layers is comprised of three or more layers.
3. The multilayer anode of claim 1 ,
wherein a total height of the plurality of anode mixture layers in the stacking direction is divided in an innermost region occupied by the innermost anode mixture layer, an outermost region occupied by the outermost anode mixture layer and a middle region occupied by the anode mixture layer located between the innermost anode mixture layer and the outermost anode mixture layer, and
wherein the innermost region extends from the anode collector to a first height which is 20% of the total height of the plurality of anode mixture layers in the stacking direction, the middle region extends from the first height to a second height of the plurality of anode mixture layers which is 80% of the total height and the outermost region extends from the second height to a third height which is 100% of the total height of the plurality of anode mixture layers.
4. The multilayer anode of claim 1 , wherein the natural graphite of the innermost anode mixture layer is contained in an amount of 50 to 100 wt % over the total anode active material of the innermost anode mixture layer.
5. The multilayer anode of claim 1 , wherein the natural graphite of the outermost anode mixture layer is contained in an amount of 50 to 100 wt % over the total anode active material of the outermost anode mixture layer.
6. The multilayer anode of claim 1 , wherein the anode mixture layer located between the innermost anode mixture layer and the outermost anode mixture layer comprises one or more anode active materials selected from artificial graphite, natural graphite, soft carbon, hard carbon, acetylene carbon black, Ketjen black, carbon nanotubes, carbon nanofiber and silicon oxide.
7. The multilayer anode of claim 1 , wherein the plurality of anode mixture layers further comprise a binder and a conductive material.
8. A lithium secondary battery comprising the multilayer anode according to claim 1 .
9. The multilayer anode of claim 1 , wherein the carbon material comprises graphite.
10. The multilayer anode of claim 1 , wherein the carbon material further comprises artificial graphite.
11. The multilayer anode of claim 10 , wherein the carbon material further comprises natural graphite.