IP Library Granted Patent US 11,702,804
Granted Patent B2
US 11,702,804 · App. 16/580,619 · Granted Jul 18, 2023

Thermoplastic pavement marking composition

Inventors: Govindasamy Paramasivam Rajendran (Garnet Valley, PA); Mark Terry (Madison, MS); Jeffrey Lee Stricker (Narberth, PA)
Assignee: Ennis-Flint, Inc.
E01F9/506B29B9/12B29B13/022C08J7/12C08K3/013C08K3/346C08K3/40C08K5/0016C08K5/01C08K5/10C08L23/06B29B2009/125
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Quick Facts
Patent No.
US 11,702,804
App. No.
16/580,619
Granted
Jul 18, 2023
Kind
B2
Abstract

A pelletized road marking composition includes a binder mixture, a filler mixture and bentonite clay. The binder mixture includes at least one alkyd ester, at least one wax, at least one ethylene copolymer, and at least one plasticizer. The filler mixture includes at least one coloring additive, reflective elements, and at least one inert inorganic filler. The components of the road marking composition are mixed and melted and processed into pellets. The bentonite clay added to the composition prevents the pellets from clumping when stored at elevated temperatures.

Claims (25)

1. A road marking composition comprising:

a binder mixture comprising an alkyd ester, a wax, an ethylene copolymer, and a plasticizer;

a filler mixture comprising a coloring additive, reflective elements, and an inorganic filler; and

bentonite clay therein,

said road marking composition formed into pellets.

2. The composition of claim 1 , wherein said bentonite clay is an organic modified bentonite.

3. The composition of claim 1 , wherein the amount of said bentonite clay in said composition ranges from 0.01 to 5.0 percent by weight.

4. The composition of claim 3 , wherein the amount of said bentonite clay in said composition ranges from 0.1 to 2.0 percent by weight.

5. The composition of claim 1 further comprising a glass fill viscosity modifier.

6. The composition of claim 5 , wherein the amount of said glass fill is in the range of 25 to 40 percent by weight.

7. A method for manufacturing the road marking composition of claim 1 comprising the steps of:

heating a mixture of the binder mixture, the bentonite clay, and the filler mixture to form a molten composition;

processing said molten composition into a plurality of pellets; and

cooling and drying the plurality of pellets.

8. The method of claim 7 , wherein said bentonite clay is an organic modified bentonite.

9. The method of claim 7 , wherein the amount of said bentonite clay in said composition ranges from 0.01 to 5.0 percent by weight.

10. The method of claim 9 , wherein the amount of said bentonite clay in said composition ranges from 0.1 to 2.0 percent by weight.

11. The method of claim 7 further comprising the step of adding a glass fill viscosity modifier before heating said thermoplastic composition.

12. The method of claim 11 , wherein the amount of said glass fill is in the range of 25 to 40 percent by weight.

13. The composition of claim 1 , wherein the ethylene copolymer comprises ethylene vinyl acetate.

14. The composition of claim 1 , wherein the ethylene copolymer comprises of one or more of ethylene vinyl acetate copolymers, ethylene acrylate copolymers, ethylene methacrylate copolymers, ethylene acrylate glycidyl-acrylate copolymers.

15. The composition of claim 1 , wherein the ethylene unit of the ethylene copolymer ranges from 50 to 95 percent by weight of the total ethylene copolymer.

16. The composition of claim 1 , wherein the road marking composition formed into pellets does not include a calcium carbonate coating.

17. The composition of claim 1 , wherein the composition comprises a clump strength of at least 82 psi.

18. The composition of claim 3 , wherein the amount of said bentonite clay in said composition ranges from 0.5 to 1.0 percent by weight.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 19, 2021
From: POTTERS INDUSTRIES, LLC
To: ENNIS-FLINT, INC.
Reel/Frame 055647/0656 →
SECURITY AGREEMENT Recorded Dec 14, 2020
From: POTTERS INDUSTRIES, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
Reel/Frame 054751/0291 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 26, 2019
From: RAJENDRAN, GOVINDASAMY PARAMASIVAM; TERRY, MARK; STRICKLER, JEFFERY LEE
To: POTTERS INDUSTRIES, LLC
Reel/Frame 050500/0106 →
Continuity (2)
Provisional Application 62736117 · Sep 25, 2018
Related Publication 20200095739A1 · Mar 26, 2020