Method for quantitatively assessing stability additive performance at field dosages
The impact of a stabilizing additive for treating oil-based fluids having destabilized solids, such as asphaltenes and polynuclear aromatics, may be quantitatively assessed, by determining the settling rate of flocculated destabilized solids in samples of untreated oil-based fluids and oil-based fluids treated with the stabilizing additive through the use of a turbidity meter or nephelometer while the field and quantifying the difference between the two settling rates to determine if a change in the amount of stabilizing additive applied to the oil-based fluid is necessary.
1. A method for determining the impact of a stabilizing additive on the settling rate of destabilized solids in an oil-based fluid comprising:
preparing a sample of an oil-based fluid containing flocculated destabilized solids and a field dosage amount of a stabilizing additive and preparing a sample of an oil-based fluid containing flocculated destabilized solids with no stabilizing additive; and
measuring the change in turbidity over time of each sample to determine a settling rate of the flocculated destabilized solids in each sample; and
quantifying the difference between settling rate of the flocculated destabilized solids in the sample of the oil-based fluid having a field dosage amount of stabilizing additive and the settling rate of the flocculated destabilized solids in the sample of the oil-based fluid having no stabilizing additive to assess performance of the stabilizing additive.
2. The method of claim 1 , wherein the step of preparing samples of an oil-based fluid containing flocculated destabilized solids and a field dosage amount of a stabilizing additive and an oil-based fluid containing flocculated destabilized solids with no stabilizing additive comprises:
titrating an oil-based fluid containing destabilized solids and a field dosage amount of a stabilizing additive and an oil-based fluid containing destabilized solids with no stabilizing additive by dosing the oil-based fluids with a paraffinic solvent until there is flocculation of the destabilized solids; and
extracting a sample from each oil-based fluid after the titration and once the destabilized solids in each oil-based fluid have flocculated; and
mixing each extracted sample with a cycloparaffin.
3. The method of claim 2 , wherein the step of mixing each extracted sample with a cycloparaffin results in the dispersion of the destabilized solid flocs present in each extracted sample.
4. The method of claim 2 , wherein the paraffinic solvent is selected from the group consisting of cetane, heptane, xylene, toluene, hexane, pentane, methylnaphthalene, a paraffinic solvent having a solubility range of about 6.8 to 7.2 (cal/cm 3 ) 1/2 , and combinations thereof.
5. The method of claim 2 , wherein the cycloparaffin is cyclohexane.
6. The method of claim 1 , wherein the oil-based fluid is selected from the group consisting of crude oil, fuel oil, atmospheric residua, vacuum, residua, distillation residua, quench oil, visbreaker tar, H-Oil process stream, LC Fining process stream, fluidized catalytic cracker slurry, and combinations thereof.
7. The method of claim 1 , wherein the destabilized solids are selected from a group consisting of asphaltenes, polynuclear aromatics, coke, coke precursors, and combinations thereof.
8. The method of claim 1 , wherein the field dosage amount ranges from about 1 ppm to about 500 ppm based on the oil-based fluid.
9. The method of claim 1 , wherein the step of measuring the change in turbidity over time of each sample to determine a settling rate of the flocculated destabilized solids in each sample is carried out by a turbidity meter.
10. The method of claim 9 , wherein the turbidity meter is portable.
11. The method of claim 9 , wherein the turbidity meter is in the field.
12. The method of claim 1 , further comprising implementing a change to the amount of stabilizing additive applied to the oil-based fluid based upon quantifying the difference between settling rate of the flocculated destabilized solids in the sample of the oil-based fluid having a field dosage amount of stabilizing additive and the settling rate of the flocculated destabilized solids in the sample of the oil-based fluid having no stabilizing additive.
13. The method of claim 1 , wherein the step of measuring the change in turbidity over time of each sample to determine a settling rate of the flocculated destabilized solids in each sample is carried out by a nephelometer.
14. The method of claim 13 , wherein the nephelometer is portable.
15. The method of claim 1 , wherein the field dosage amount ranges from about 10 ppm to about 50 ppm based on the oil-based fluid.
16. The method of claim 1 , further comprising implementing a change to a production, transportation, or refining process based upon quantifying the difference between settling rate of the flocculated destabilized solids in the sample of the oil-based fluid having a field dosage amount of stabilizing additive and the settling rate of the flocculated destabilized solids in the sample of the oil-based fluid having no stabilizing additive, the change being selected from a group consisting of: adding an additional feed stream to the oil-based fluid to stabilize the oil-based fluid, adding an additive to the oil-based fluid, adding a different demulsifier to the oil-based fluid than any demulsifier already present in the oil-based fluid, changing a temperature of the oil-based fluid, changing a water feed rate of a unit within the refinery process, and combinations thereof.