High energy density fast charge Li ion battery and the method of preparing the same
A fast charge lithium ion battery capable of being charged or discharged with 80% capacity retention at C rate of at least 2C is provided in the present invention, which includes a fast charge graphite-based anode; a cathode; and a separator, wherein the anode includes an anode current collector and a fast charge graphite layer deposited on at least one surface of the anode current collector, the fast charge graphite having a lattice constant equals to or larger than 0.3374 nm, a D-band to G-band integrated area ratio (I D /I G ) of 0.03 to 0.3, and a surface morphology of a plate-like crystal structure under a scanned electron microscope; the cathode includes a cathode current collector and one or more active materials deposited on at least one surface of the cathode current collector.
1. A fast charge lithium ion battery capable of being charged or discharged with 80% capacity retention at C rate of at least 2C, comprising
a fast charge graphite-based anode;
a cathode; and
a separator,
wherein the anode includes an anode current collector and a fast charge graphite layer deposited on at least one surface of the anode current collector, the fast charge graphite having a lattice constant equal to or larger than 0.3374 nm; the fast charge graphite also having a D-band to G-band integrated area ratio (I D /I G ) in a range of 0.03-0.3, with a peak intensity of the G-band integrated area in a range of 1300˜1400 cm −1 and a peak intensity of the D-band integrated area in a range of 1530˜1650 cm −1 as measured by Raman spectroscopy at a laser wavelength of 633 nm; the fast charge graphite also having a surface morphology of a plate-like crystal structure under a scanning electron microscope;
the cathode includes a cathode current collector and one or more active materials deposited on at least one surface of the cathode current collector.
2. The battery of claim 1 , wherein the fast charge graphite has an X-ray diffraction peak at 26.35° two theta.
3. The battery of claim 1 , wherein the fast charge graphite has particle sizes of 5˜30 μm with more than 60% thereof are less than 20 μm.
4. The battery of claim 1 , wherein the one or more active materials deposited on the cathode current collector comprise LiFePO 4 , LiMnO 2 , LiCoO 2 , LiNi x Mn y O 2 and LiNi 0.1x Co 0.1y Mn 0.1z O 2 , where x=1˜10; y=1˜10; z=1˜10.
5. The battery of claim 1 , wherein the separator comprises PP and PE layers with or without ceramic materials on at least one surface thereof.
6. The battery of claim 5 , wherein the separator has a thickness of 5˜40 μm.
7. The battery of claim 1 , wherein the fast charge graphite layer is formed by a graphite slurry formulation comprising the fast charge graphite, super P, carboxymethyl cellulose (CMC) and styrene-butadiene rubber (SBR).
8. The battery of claim 7 , wherein the fast charge graphite, super P, CMC and SBR have weight ratios of 70%˜93%, 3%˜10%, 3%˜10% and 1%˜10%, respectively.
9. The battery of claim 7 , wherein the fast charge graphite layer is formed by coating the graphite slurry formulation on at least one surface of the anode current collector via compression at a compression ratio of 0.6˜0.8.
10. The battery of claim 9 , wherein said compression is calendering and is carried out at room temperature.
11. The battery of claim 9 , wherein the anode has an areal capacity of 0˜3.5 mAh/cm 2 .
12. The battery of claim 9 , wherein the anode has a mass loading of 5˜10 mg/cm 2 .
13. The battery of claim 1 , wherein the battery is capable of being charged or discharged with 80% capacity retention at C rate of 2C, 3C, 4C and 6C for 834, 230, 212, and 64 cycles, respectively.