Adhesive compositions

1. An adhesive composition comprising:

(a) Part A comprising:

(i) a (meth)acrylic component;

(ii) a cure accelerator represented by structure A

wherein X is H C 1-20 alkyl, C 2-20 alkenyl, or C 7-20 alkaryl, functionalized by one or more groups selected from —OH, —NH 2 or

—SH, or X and Y taken together form a carbocyclic ring having from 5-7 ring atoms; Z is O, S, or NX′, where X′ is H, C 1-20 alkyl, C 2-20 alkenyl, or C 7-20 alkaryl, any of the latter three of which may be interrupted by one or more hetero atoms or functionalized by one or more groups selected from —OH, —NH 2 or

—SH; R is optional but when present may occur up to 3 times on the aromatic ring and when present is C 1-20 alkyl, C 2-20 alkenyl, or C 7-20 alkaryl, any of the latter three of which may be interrupted by one or more hetero atoms or functionalized by one or more groups selected from —OH, —NH 2 or —SH; and n is 0 or 1; and z is 1-3;

(iii) a thermoplastic elastomer; and

(iv) a reactive acid/ester component; and

(b) Part B comprising:

(i) an epoxy resin component;

(ii) an oxidant;

(iii) a plasticizer; and

(iv) optionally, a block copolymer.

2. The composition of claim 1 , wherein the (meth)acrylic component of Part A is selected from the group consisting of methyl (meth)acrylate, (meth)acrylic acid, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate, n-pentyl (meth)acrylate, n-hexyl (meth)acrylate, cyclohexyl (meth)acrylate, n-heptyl (meth)acrylate, n-octyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, nonyl (meth)acrylate, decyl (meth)acrylate, dodecyl (meth)acrylate, phenyl (meth)acrylate, tolyl (meth)acrylate, benzyl (meth)acrylate, 2-methoxyethyl (meth)acrylate, 3-methoxybutyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, stearyl (meth)acrylate, glycidyl (meth)acrylate, 2-aminoethyl (meth)acrylate, γ-(meth)acryloyloxypropyl trimethoxysilane, (meth)acrylic acid-ethylene oxide adduct, trifluoromethylmethyl (meth)acrylate, 2-trifluoromethylethyl (meth)acrylate, 2-perfluoroethylethyl (meth)acrylate, 2-perfluoroethyl-2-perfluorobutylethyl (meth)acrylate, 2-perfluoroethyl (meth)acrylate, perfluoromethyl (meth)acrylate, diperfluoromethylmethyl (meth)acrylate, 2-perfluoromethyl-2-perfluoroethylmethyl (meth)acrylate, 2-perfluorohexylethyl (meth)acrylate, 2-perfluorodecylethyl (meth)acrylate, 2-perfluorohexadecylethyl (meth)acrylate, ethoxylated trimethylolpropane triacrylate, trimethylol propane trimethacrylate, dipentaerythritol monohydroxypentacrylate, pentaerythritol triacrylate, ethoxylated trimethylolpropane triacrylate, 1,6-hexanedioldiacrylate, neopentyl glycoldiacrylate, pentaerythritol tetraacrylate, 1,2-butylene glycoldiacrylate, trimethylopropane ethoxylate tri(meth)acrylate, glyceryl propoxylate tri(meth)acrylate, trimethylolpropane tri(meth)acrylate, dipentaerythritol monohydroxy penta(meth)acrylate, tri(propylene glycol) di(meth)acrylate, neopentylglycol propoxylate di(meth)acrylate, 1,4-butanediol di(meth)acrylate, polyethyleneglycol di(meth)acrylate, triethyleneglycol di(meth)acrylate, butylene glycol di(meth)acrylate, ethoxylated bisphenol A di(meth)acrylate, and combinations thereof.

3. The composition of claim 1 , wherein the cure accelerator is selected from

4. The composition of claim 1 , wherein the reactive acid/ester component is selected from the group consisting of (meth)acrylic acid or (meth)acrylic acid derivatives, sulphonic acid, sulphonic acid derivatives, phosphoric acid, phosphoric acid derivatives, and phosphate esters.

5. The composition of claim 1 , wherein the reactive acid/ester component is a phosphate ester comprising a compound of the formula:

wherein R 1 is H or CH 3 , and R 2 is H or:

6. The composition of claim 1 , wherein the reactive acid/ester component is hydroxyl ethyl methacrylate phosphate ester.

7. The composition of claim 1 , further comprising a free radical inhibitor selected from the group consisting of quinones, hydroquinones, hydroxylamines, nitroxyls, phenols, amines, amines, quinolines, phenothiazines, and combinations thereof.

8. The composition of claim 1 , further comprising a free radical inhibitor selected from the group consisting of hydroquinone, tertiary butylhydroquinone, phenothiazine, methyl hydroquinone, hydroxyethylhydroquinone, N-alkyl substituted p-phenylenediamines, and combinations thereof.

9. The composition of claim 1 , wherein the epoxy resin component of Part B is selected from the group consisting of cycloaliphatic epoxy resins, epoxy novolac resins, bisphenol-A epoxy resins, bisphenol-F epoxy resins, bisphenol-A epichlorohydrin based epoxy resin, alkyl epoxides, limonene dioxide, polyfunctional epoxy resins, and combinations thereof.

10. The composition of claim 1 , wherein the epoxy resin component of Part B is a bisphenol A epichlorohydrin epoxy resin.

11. The composition of claim 1 , wherein the oxidant of Part B is benzoyl peroxide.

12. A method of bonding a first surface to a second surface, comprising:

applying a two part composition according to claim 1 to at least one of a first surface and a second surface to be bonded;

mating the first surface and the second surface, under conditions favorable to cure the two part composition and form an adhesive bond between the mated surfaces.

13. The composition of claim 1 , wherein when Part A and Part B are mixed and applied to at least one substrate, the composition has up to 5 minutes of open time.

14. The composition of claim 1 , wherein when the substrates are mated the composition demonstrates a fixture time of less than 90 seconds at a temperature of less than 60° C.