Internal electrical connections for concentric tubular electrochemical cells
Self-cleaning electrochemical cells, systems including self-cleaning electrochemical cells, and methods of operating self-cleaning electrochemical cells are disclosed. The self-cleaning electrochemical cell can include a plurality of concentric electrodes disposed in a housing, a fluid channel defined between the concentric electrodes, and an electrical connector positioned at a distal end of a concentric electrode and electrically connected to the electrode. The electrical connectors may be configured to provide a substantially even current distribution to the concentric electrode and minimize a zone of reduced velocity occurring downstream from the electrical connector. The electrical connector may be configured to cause a temperature of an electrolyte solution to increase by less than about 0.5° C. while transmitting at least 100 W of power.
1. A self-cleaning electrochemical cell comprising:
a plurality of electrodes disposed concentrically in a housing about a central axis of the housing;
a fluid channel defined between adjacent electrodes of the plurality of electrodes and extending substantially parallel to the central axis; and
an electrical connector positioned at a distal end of at least one of the plurality of electrodes and electrically connected to the at least one of the plurality of electrodes,
the electrical connector being dimensioned to allow fluid flow through the fluid channel and provide a substantially even current distribution to the at least one of the plurality of electrodes while maintaining a zone of reduced velocity having less than a predetermined length within the fluid channel downstream of the electrical connector, the zone of reduced velocity defined by a region in the fluid channel in which fluid flow velocity deviates from a mean fluid flow velocity in the channel by within 20%.
2. The self-cleaning electrochemical cell of claim 1 , wherein the electrical connector has an average resistivity of less than about 7.8×10 −7 ohm-meter.
3. The self-cleaning electrochemical cell of claim 2 , wherein the electrical connector is dimensioned to generate less than about 25 W of heat when transmitting at least 100 W of power to the at least one of the plurality of electrodes.
4. The self-cleaning electrochemical cell of claim 3 , wherein the electrical connector is dimensioned to generate less than about 25 W of heat when transmitting at least 1 kW of power to the at least one of the plurality of electrodes.
5. The self-cleaning electrochemical cell of claim 1 , wherein the electrical connector comprises a wheel and a plurality of spokes extending from the wheel.
6. The self-cleaning electrochemical cell of claim 5 , further comprising a separator disposed between the adjacent electrodes, the separator comprising a feature configured to mate with the electrical connector.
7. The self-cleaning electrochemical cell of claim 6 , wherein the feature of the separator includes a slot configured to mate with a spoke of the electrical connector.
8. The self-cleaning electrochemical cell of claim 6 , wherein each spoke of the plurality of spokes is dimensioned to minimize electrical resistance across the electrical connector and maintain a heat generation of the electrical connector to be less than about 0.1° C. when transmitting at least 100 W of power to the at least one of the plurality of electrodes.
9. The self-cleaning electrochemical cell of claim 6 , wherein the plurality of spokes are substantially evenly distributed on the wheel.
10. The self-cleaning electrochemical cell of claim 6 , wherein the spokes have an aqualined configuration in a direction parallel to the central axis of the housing.
11. The self-cleaning electrochemical cell of claim 1 , comprising a plurality of fluid channels disposed concentrically between respective pairs of adjacent electrodes, wherein the electrical connector comprises a plurality of wheels and a plurality of spokes extending between adjacent wheels of the plurality of wheels.
12. The self-cleaning electrochemical cell of claim 11 , wherein spokes extending from adjacent wheels are angularly offset from each other.
13. The self-cleaning electrochemical cell of claim 12 , wherein the spokes extending from adjacent wheels are substantially equally angularly offset from each other.
14. A self-cleaning electrochemical cell comprising:
a plurality of electrodes disposed concentrically in a housing about a central axis of the housing;
a fluid channel defined between adjacent electrodes and extending substantially parallel to the central axis; and
an electrical connector positioned at a distal end of an electrode of the plurality of electrodes and electrically connected to the electrode, the electrical connector being dimensioned to allow fluid flow through the channel while maintaining a zone of reduced velocity having less than a predetermined length within the fluid channel downstream of the electrical connector, an electrolyte solution velocity deviation from mean at the predetermined length being less than ±5% of an average flow velocity of the electrolyte solution through the fluid channel, and control a temperature of electrolyte flowing through the fluid channel at about 2 m/s and having a temperature of about 20° C. to increase by less than about 0.5° C. while transmitting at least 100 W of power to the at least one of the plurality of electrodes.
15. The self-cleaning electrochemical cell of claim 14 , wherein the electrical connector includes an electrical connection for connecting to an external source of power and electrical resistance of the electrical connector between the electrical connection and the electrode is less than about 5×10 −5 ohms.
16. The self-cleaning electrochemical cell of claim 14 , wherein the electrical connector is dimensioned to provide a substantially even current distribution to the plurality of electrodes.
17. The self-cleaning electrochemical cell of claim 14 , wherein the velocity deviation from mean at the predetermined length is less than ±2% of the average flow velocity of the electrolyte solution through the fluid channel.
18. The self-cleaning electrochemical cell of claim 1 , wherein an electrolyte solution velocity deviation from mean at the predetermined length is less than ±5% of the average flow velocity of the electrolyte solution through the fluid channel.
19. The self-cleaning electrochemical cell of claim 18 , wherein the velocity deviation from mean at the predetermined length is less than ±2% of the average flow velocity of the electrolyte solution through the fluid channel.