Method for purifying 1,1,1,2,2-pentafluoropropane
View Patent ↗The present invention relates to a process for purifying a stream including 1,1,1,2,2-pentafluoropropane, comprising the steps of i) providing a stream A comprising 1,1,1,2,2-pentafluoropropane and at least one of the compounds selected from the group consisting of 2-chloro-1,1,1,3,3-pentafluoropropane, 1,2-dichloro-3,3,3-trifluoropropene, 2-chloro-1,3,3,3-tetrafluoropropene; ii) purification, preferably by distillation, of the stream A provided in i) in order to form a first stream A 1 comprising 1,1,1,2,2-pentafluoropropane, preferably recovered at the top of the distillation column, and a second stream A 2 comprising said at least one of the compounds selected from the group consisting of 2-chloro-1,1,1,3,3-pentafluoropropane, 1,2-dichloro-3,3,3-trifluoropropene, 2-chloro-1,3,3,3-tetrafluoropropene, preferably recovered at the bottom of the distillation column.
1. A process for purifying a stream including 1,1,1,2,2-pentafluoropropane, comprising the steps of:
i) providing a stream A comprising at least 50% 1,1,1,2,2-pentafluoropropane and at least one of the compounds selected from the group consisting of 2-chloro-1,1,1,3,3-pentafluoropropane, 1,2-dichloro-3,3,3-trifluoropropene, and 2-chloro-1,3,3,3-tetrafluoropropene; and
ii) purifying stream A provided in i) under conditions effective for forming a first stream A 1 comprising 1,1,1,2,2-pentafluoropropane and a second stream A 2 comprising said at least one of the compounds selected from the group consisting of 2-chloro-1,1,1,3,3-pentafluoropropane, 1,2-dichloro-3,3,3-trifluoropropene, and 2-chloro-1,3,3,3-tetrafluoropropene.
2. The process as claimed in claim 1 , wherein stream A provided in step i) and second stream A 2 of step ii) comprise at least two of the compounds selected from the group consisting of 2-chloro-1,1,1,3,3-pentafluoropropane, 1,2-dichloro-3,3,3-trifluoropropene, and 2-chloro-1,3,3,3-tetrafluoropropene.
3. The process as claimed in claim 1 , wherein stream A further comprises hydrofluoric acid.
4. The process as claimed in claim 1 , wherein in first stream A 1 obtained in step ii), the 1,1,1,2,2-pentafluoropropane is obtained in the form of an azeotropic or quasi-azeotropic mixture.
5. The process as claimed in claim 1 , further comprising adding a flow comprising at least 90% of 1,1,1,2,2-pentafluoropropane to the stream A of step i) before carrying out step ii).
6. The process as claimed in claim 1 , wherein stream A provided in step i) further comprises (E/Z)-1,3,3,3-tetrafluoropropene, 2-chloro-3,3,3-trifluoropropene, E-1-chloro-3,3,3-trifluoropropene, Z-1-chloro-3,3,3-trifluoropropene or 1,1,1,3,3-pentafluoropropane.
7. The process as claimed in claim 6 , wherein the (E/Z)-1,3,3,3-tetrafluoropropene, 2-chloro-3,3,3-trifluoropropene, E-1-chloro-3,3,3-trifluoropropene or 1,1,1,3,3-pentafluoropropane is (are) recovered in said first stream A 1 of step (ii).
8. The process of claim 1 , wherein stream A is purified by distillation.
9. The process of claim 2 , wherein stream A provided in step i) and second stream A 2 of step ii) comprise 1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,1,3,3-pentafluoropropane, 1,2-dichloro-3,3,3-trifluoropropene, and 2-chloro-1,3,3,3-tetrafluoropropene.
10. The process of claim 4 , wherein the azeotropic or quasi-azeotropic mixture comprises 1,1,1,2,2-pentafluoropropane and HF.