Sensor for lead detection

1. A sensor for the detection of lead comprising:

a substrate;

a working electrode formed on a surface of the substrate;

a counter electrode formed on the surface of the substrate;

a dielectric layer covering a portion of the working electrode and counter electrode and defining an aperture exposing other portions of the working electrode and counter electrode; wherein the working electrode includes a metalized film with working surface and an atomic monolayer or bilayer of bismuth deposited on the working surface by underpotential deposition.

2. The sensor of claim 1 , wherein working surface of the metalized film is substantially free of surface adsorbed impurities between the metalized film and the atomic monolayer or bilayer.

3. The sensor of claim 1 , wherein the working electrode and counter electrode independently comprise gold, platinum, palladium, silver, carbon, alloys thereof, and composites thereof.

4. The sensor of claim 1 , the metalized films are provided on the surface of the substrate by sputtering or coating the films on the surface and wherein the working electrode and the counter electrode are formed using laser ablation.

5. The sensor of claim 1 , further comprising a reference electrode on the surface of the substrate, the dielectric covering a portion of the reference electrode.

6. The sensor of claim 1 , further comprising a measuring device for applying voltage potentials to the working electrode and counter electrode and measuring the current flow between the working electrode and counter electrode.

7. A method of detecting the quantity of lead in an aqueous sample, the method comprising:

providing a sensor that includes a substrate, a working electrode formed on a surface of the substrate; a counter electrode formed on the surface of the substrate; a dielectric layer covering a portion of the working electrode and counter electrode and defining an aperture exposing other portions of the working electrode and counter electrode, wherein the working electrode includes a metalized film with working surface and an atomic monolayer or bilayer of bismuth deposited on the working surface by underpotential deposition,

applying a volume of an aqueous sample on the working electrode for a duration of time effective to allow lead ions in the sample to complex with the deposited bismuth;

anodic stripping the complexed lead ions;

measuring an anodic stripping current during anodic stripping; and

comparing the measured anodic stripping current to a control value to detect the quantity of lead ions in the aqueous sample.

8. The method of claim 7 , wherein the complexed lead ions are anodically stripped by differential pulse voltammetry.

9. The method of claim 7 , wherein the control value is a calibration curve.

10. The method of claim 7 , wherein working surface of the metalized film is substantially free of surface adsorbed impurities between the metalized film and the atomic monolayer or bilayer.

11. The method of claim 7 , wherein the working electrode and counter electrode independently comprise gold, platinum, palladium, silver, carbon, alloys thereof, and composites thereof.

12. The method of claim 7 , the metalized films are provided on the surface of the substrate by sputtering or coating the films on the surface and wherein the working electrode and the counter electrode are formed using laser ablation.

13. The method of claim 7 , further comprising a reference electrode on the surface of the substrate, the dielectric covering a portion of the reference electrode.

14. The method of claim 7 , further comprising providing a measuring device for applying voltage potentials to the working electrode and counter electrode, and for measuring the current flow between the working electrode and counter electrode.