IP Library Granted Patent US 10,898,855
Granted Patent B2
US 10,898,855 · App. 16/608,679 · Granted Jan 26, 2021

Method and system for the removal of noxious compounds from flue-gas using fabric filter bags with an SCR catalyst

Inventor: Pär L. T. Gabrielsson (Helsingborg, SE)
Assignee: Haldor Topsoe A/S
B01D53/869B01D46/0027B01D46/02B01D53/8631B01D53/8634B01D2251/2062B01D2251/2067B01D2255/1021B01D2255/1023B01D2255/915
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Quick Facts
Patent No.
US 10,898,855
App. No.
16/608,679
Granted
Jan 26, 2021
Kind
B2
Abstract

Method and system for the removal of nitrogen oxides, from flue gas at low temperatures.

Claims (18)

1. A method for the removal of nitrogen oxides from flue gas from combustion facilities, comprising the steps of

passing the flue gas through one or more fabric filter bags catalysed with a catalyst for selective reduction of nitrogen oxides in presence of ammonia added to the flue gas either as such or in form of a precursor thereof;

injecting an effluent gas containing nitrogen dioxide into the flue gas upstream the one or more fabric filter bags;

providing the effluent gas containing nitrogen dioxide by steps of catalytically oxidizing ammonia or a precursor thereof with an oxygen containing atmosphere to an effluent gas containing nitrogen monoxide and oxygen in presence of an oxidation catalyst;

cooling the effluent gas to ambient temperature and oxidizing the nitrogen monoxide in the cooled effluent gas to the nitrogen dioxide containing effluent gas.

2. The method of claim 1 , wherein the oxygen containing atmosphere comprises flue gas.

3. The method of claim 1 , wherein the oxygen atmosphere is ambient air.

4. The method according to claim 1 , wherein the nitrogen dioxide containing effluent gas is injected into the flue gas in an amount resulting in 45 to 55% by volume of the nitrogen oxides is nitrogen dioxide at inlet to the catalyst for selective reduction of nitrogen oxides.

5. The method according to claim 1 , wherein the oxidation of the nitrogen monoxide in the cooled effluent gas to the nitrogen dioxide containing effluent gas is performed in presence of an oxidation catalyst.

6. System for use in the method according to claim 1 , comprising within a flue gas duct a filter bag house with one or more fabric filter bags catalysed with a catalyst for selective reduction of nitrogen oxides;

upstream the one or more fabric filter bags or the filter bag house injection means for injection of ammonia or a urea solution into the flue gas duct;

upstream the one or more fabric filter bags or the filter bag house, injection means for injection of nitrogen dioxide containing effluent gas; and

outside the flue gas duct,

an ammonia oxidation catalyst unit; and

means for cooling and oxidizing nitrogen monoxide containing effluent gas withdrawn from the ammonia oxidation catalyst to the nitrogen dioxide containing effluent gas connected at its outlet end to the injection means for injection of the nitrogen dioxide containing effluent gas.

7. The system of claim 6 , wherein the means for cooling and oxidizing the nitrogen monoxide containing effluent gas is in form of a heat exchanger.

8. The system of claim 6 , wherein the means for cooling and oxidizing the nitrogen monoxide containing effluent gas is in form of a spirally wound tube.

9. The system of claim 6 , wherein the means for the cooling and oxidizing nitrogen monoxide containing effluent gas is provided with an oxidation catalyst.

Assignments (2)
CHANGE OF NAME Recorded Oct 3, 2023
From: HALDOR TOPSØE A/S
To: TOPSOE A/S
Reel/Frame 065108/0028 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2019
From: GABRIELSSON, PAR L. T.
To: HALDOR TOPSOE A/S
Reel/Frame 050832/0587 →
Priority Claims (2)
DK 2017 00265 · Apr 26, 2017 · national
DK 2017 00278 · May 2, 2017 · national
Continuity (1)
Related Publication 20200188849A1 · Jun 18, 2020