IP Library Granted Patent US 12,509,576
Granted Patent B2
US 12,509,576 · App. 16/608,733 · Granted Dec 30, 2025

Stabilized polymer compositions

Inventors: Linnea Petersson (Västerås, SE); Henrik Hillborg (Västerås, SE); Joakim Jämbeck (Stockholm, SE); Gang Zhang (State College, PA); T.C. Mike Chung (State College, PA)
Assignee: HITACHI ENERGY LTD
C08L23/12C08L23/14H01B3/30H01G4/18C08L2201/08C08L2203/20C08L2205/025
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Quick Facts
Patent No.
US 12,509,576
App. No.
16/608,733
Granted
Dec 30, 2025
Kind
B2
Abstract

A polymer composition including: a) a polymer matrix; b) a polymeric antioxidant compatible with the polymer matrix, and having pendant phenol antioxidant moieties; and c) a mono- or oligo-functional phenol antioxidant. The invention further discloses film capacitors and power system components having such polymer compositions.

Claims (18)

1 . A polymer composition comprising:

a) a polymer matrix, the polymer composition including from 5 weight % to 99.8 weight % of the polymer matrix, calculated with respect to the total weight of the polymer composition, the polymer matrix comprising a polyolefin selected from polyethylene (PE), polypropylene (PP), polymethylpentene (PMP), polybutene-1 (PB-1) polyisobutylene (PIB), ethylene propylene rubber (EPR) and ethylene propylene diene rubber (EPDM) including low density polyethylene (LDPE), linear low density polyethylene (LLDPE), very low density polyethylene (VLDPE), high density polyethylene (HDPE), cross linked polyethylene (XLPE), medium density polyethylene (MDPE), ultra high molecular weight polyethylene (UHMWPE) and biaxially-oriented polypropylene (BOPP);

b) a polymeric antioxidant compatible with the polymer matrix, and including from 0.2 to 10 mol % pendant phenol antioxidant moieties, the polymer composition including from 0.1 weight % to 50 weight % of polymeric antioxidant, calculated with respect to the total weight of the polymer composition, a weight % of the polymeric antioxidant being 0.5% of a weight of the polymer matrix; and

c) a mono-or oligo-functional phenol antioxidant, the polymer composition including from 0.1 weight % to 5 weight % of mono-or oligo-functional phenol antioxidant, calculated with respect to the total weight of the polymer composition, and the polymeric antioxidant is a compatibilizer between the polymer matrix and the mono-or oligo-functional phenol antioxidant.

2 . The polymer composition according to claim 1 , wherein the polymer matrix includes one or more of a natural rubber, an acrylic, polystyrene, a styrenic copolymer, a polyacetal, a polyamide, a polycarbonate, a polyester, a polyurethane, PVC, and polyvinyl butyral.

3 . The polymer composition according to claim 1 , wherein the polymeric antioxidant includes the same monomer units as the polymer matrix.

4 . The polymer composition according to claim 1 , wherein the polymer matrix and the polymeric antioxidant can crystalize.

5 . The polymer composition according to claim 1 , wherein the polymer matrix is a polyolefin and the polymeric antioxidant is a polyolefin copolymer.

6 . The polymer composition according to claim 1 , wherein the pendant phenol antioxidant moieties include phenol groups including one or two ortho-substituents selected from C1-C4 alkyl, C1-C4-alkoxy, amino, N-alkylamino and N,N′-dialkylamino.

7 . The polymer composition according to claim 1 , wherein the mono-or oligo-functional phenol antioxidant is selected from 2,6-di-tert-butyl-phenol, 2,6-Di-tert-butyl-4-methylphenol, 2-tert-butyl-4-methoxyphenol and octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)-propionate, 2-tertbutyl-6-(2-hydroxy-3-tert-butyl-5-methyl-benzyl)-4-methyl-phenol and 2-tert-butyl-6-[(3-tert-butyl-5-ethyl-2-hydroxyphenyl)methyl]-4-ethylphenol, the trifunctional 1,3,5-trimethyl-2,4,6-tris (3,5-Di-tert-butyl-4-hydroxybenzyl)benzene, 1,1,3-tris (2-methyl-4-hydrox-5-tert-butyl phenyl) butane, pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate), and combinations thereof.

8 . The polymer composition according to claim 1 , wherein the pendant phenol antioxidant moiety and the mono-or oligo-functional phenol antioxidant have matching hindered phenol structural element.

9 . The polymer composition according to claim 1 wherein the polymer composition is a film capacitor comprising a dielectric.

10 . The polymer composition according to claim 1 wherein the polymer composition is an electric power system component comprising an insulator.

11 . The polymer composition according to claim 1 , wherein the polymeric antioxidant is a polypropylene-hindered phenol copolymer.

12 . The polymer composition according to claim 1 , wherein the polymer matrix comprises polypropylene,

wherein the polymeric antioxidant comprises a PolyPropylene-Hindered Phenol copolymer.

13 . The polymer composition of claim 1 , further comprising from 2 weight % to 50 weight % of the polymeric antioxidant.

14 . The polymer composition of claim 1 , the polypropylene-hindered phenol copolymer having a structure represented by the following formula (I):

Assignments (5)
MERGER Recorded Nov 13, 2023
From: HITACHI ENERGY SWITZERLAND AG
To: HITACHI ENERGY LTD
Reel/Frame 065548/0869 →
CHANGE OF NAME Recorded Dec 31, 2021
From: ABB POWER GRIDS SWITZERLAND AG
To: HITACHI ENERGY SWITZERLAND AG
Reel/Frame 058601/0692 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 15, 2021
From: ABB SCHWEIZ AG
To: ABB POWER GRIDS SWITZERLAND AG
Reel/Frame 055585/0670 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 31, 2020
From: ABB SCHWEIZ AG
To: ABB POWER GRIDS SWITZERLAND AG
Reel/Frame 054787/0529 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 31, 2019
From: PETERSSON, LINNEA; HILLBORG, HENRIK; JÄMBECK, JOAKIM; ZHANG, GANG; CHUNG, T.C. MIKE
To: ABB SCHWEIZ AG
Reel/Frame 051392/0667 →