Modified butadiene polymer and rubber composition
The present invention provides a compounding agent which, when used in a rubber composition containing a reinforcing filler, exhibits excellent dispersibility, workability, toughness, low heat build-up, and wear resistance; and a rubber composition containing the compounding agent. A modified butadiene polymer of the present invention has a functional group containing a nitrogen atom and silicon atom at a terminal, a weight average molecular weight of the modified butadiene polymer being from 1000 to 15000, and a molecular weight distribution of the modified butadiene polymer being 2.0 or less.
1. A modified butadiene polymer comprising a functional group containing a nitrogen atom and a silicon atom at a terminal, the nitrogen atom being included as an amino group, the modified butadiene polymer having a weight average molecular weight of from 1000 to 9500, and a molecular weight distribution of 2.0 or less, wherein a proportion of vinyl structure contained in the modified butadiene polymer is from 24 to 50 mol %.
2. The modified butadiene polymer according to claim 1 , wherein a viscosity is from 150 to 240% relative to a viscosity of a butadiene polymer prior to modification, wherein the viscosity is measured with a cone-plate viscometer.
3. A rubber composition comprising a rubber component having a weight average molecular weight greater than 15000, a reinforcing filler, and the modified butadiene polymer described in claim 1 , wherein a content of the reinforcing filler is from 50 to 200 parts by mass per 100 parts by mass of the rubber component, and a content of the modified butadiene polymer is from 1 to 25 mass % with respect to the content of the reinforcing filler.
4. A rubber composition comprising a rubber component having a weight average molecular weight greater than 15000, a reinforcing filler containing at least one selected from the group consisting of carbon black and silica, and the modified butadiene polymer described in claim 1 .
5. The rubber composition according to claim 3 , wherein the reinforcing filler contains at least one selected from the group consisting of carbon black and silica, and the silica has a nitrogen adsorption specific surface area of 194 m 2 /g or greater, a CTAB adsorption specific surface area of 185 m 2 /g or greater, and a ratio of the nitrogen adsorption specific surface area to the CTAB adsorption specific surface area is from 0.9 to 1.4.
6. The rubber composition according to claim 4 , comprising silica as the reinforcing filler and further comprising a silane coupling agent, wherein a content of the silane coupling agent is from 1 to 20 mass % with respect to the content of the silica.
7. The rubber composition according to claim 3 , wherein a glass transition temperature of the rubber component is −60° C. or higher.
8. A rubber composition comprising a rubber component having a weight average molecular weight greater than 15000, a reinforcing filler, and the modified butadiene polymer described in claim 2 , wherein a content of the reinforcing filler is from 50 to 200 parts by mass per 100 parts by mass of the rubber component, and a content of the modified butadiene polymer is from 1 to 25 mass % with respect to the content of the reinforcing filler.
9. A rubber composition comprising a rubber component having a weight average molecular weight greater than 15000, a reinforcing filler containing at least one selected from the group consisting of carbon black and silica, and the modified butadiene polymer described in claim 2 .
10. The rubber composition according to claim 4 , wherein the reinforcing filler contains silica, and the silica has a nitrogen adsorption specific surface area of 194 m 2 /g or greater, a CTAB adsorption specific surface area of 185 m 2 /g or greater, and a ratio of the nitrogen adsorption specific surface area to the CTAB adsorption specific surface area is from 0.9 to 1.4.
11. The rubber composition according to claim 8 , wherein the reinforcing filler contains at least one selected from the group consisting of carbon black and silica, and the silica has a nitrogen adsorption specific surface area of 194 m 2 /g or greater, a CTAB adsorption specific surface area of 185 m 2 /g or greater, and a ratio of the nitrogen adsorption specific surface area to the CTAB adsorption specific surface area is from 0.9 to 1.4.
12. The rubber composition according to claim 9 , wherein the reinforcing filler contains silica, and the silica has a nitrogen adsorption specific surface area of 194 m 2 /g or greater, a CTAB adsorption specific surface area of 185 m 2 /g or greater, and a ratio of the nitrogen adsorption specific surface area to the CTAB adsorption specific surface area is from 0.9 to 1.4.