Packaging method for fruits and vegetables

1. A sealable, thermoplastic film for the packaging of fruits or vegetables comprising:

a) a first outer layer comprising between 40 and 60 wt % of a linear low density polyethylene, between 15 and 35 wt % of a medium density polyethylene, and between 15 wt % and 35 wt % of an ethylene-vinyl acetate copolymer, all wt % being based on the weight of the first outer layer;

b) a second outer layer comprising between 40 and 60 wt % of a linear low density polyethylene, between 15 and 35 wt % of a medium density polyethylene, and between 15 wt % and 35 wt % of an ethylene-vinyl acetate copolymer, all wt % being based on the weight of the second outer layer; and

c) an inner layer comprising between 80 and 97 wt % of a linear low density polyethylene and between 1 and 20 wt % of a low density polyethylene, wherein the total amount of polyethylene in the inner layer is at least 90 wt %, all wt % being based on the weight of the inner layer;

the thermoplastic film having:

an oxygen transmission rate between 8000 and 14000 cc/sqm·day·atm, measured according to ASTM D-3985 at 23° C. and 0% in-0% out relative humidity,

a CO2 transmission rate between 25000 to 41000 cc/sqm·day·atm, measured according to ASTM F-2476, at 23° C. and 0% in-0% out relative humidity,

a water vapour transmission rate between 8 and 35 g/sqm·day·atm, measured according to ASTM D1249 at 38° C. and 98% in-0% out relative humidity, and

a transmittance of less than 70% of light at wavelengths from the entirety of 200 to 400 nm, measured with the method as follows:

3 cm×1.7 cm pieces of film cut from portions of the film along a transverse direction are put into sample holders of a spectrophotometer equipped with a light source deuterium lamp (190-350 nm) and a halogen lamp (330-900 nm)

the spectrophotometer set to have a light wavelength range being 200-850 nm, under the following conditions:

resolution of 0.5 nm

response: medium

scanning speed: 100 nm/min

baseline flatness ±0.004 Abs

band width: 2 nm

photometric mode: absorbance

the instrument measured absorbance is converted by an integrated software into % transmittance.

2. The thermoplastic film according to claim 1 , wherein the film has a ratio between the CO 2 transmission rate (measured according to ASTM F-2476, at 23° C. and 0% in-0% out relative humidity) and the oxygen transmission rate (measured according to ASTM D-3985 at 23° C. and 0% in-0% out relative humidity) between 2 and 3.8.

3. The thermoplastic film according to claim 1 , wherein the film is heat sealable.

4. The thermoplastic film according to claim 1 , where the film is cross linked, oriented or heat shrinkable.

5. The thermoplastic film according to claim 1 wherein the film is a multilayer film, comprising a number of layers between 3 and 4.

6. The thermoplastic film according to claim 1 , wherein the total thickness of the film is between 5 and 20 microns.

7. The thermoplastic film according to claim 1 , wherein the film comprises between 60 and 90 wt % of a polyethylene, selected from linear low density polyethylene (LLDPE), low density polyethylene (LDPE), medium density polyethylene (MDPE) and mixtures thereof.

8. The thermoplastic film according to claim 1 , wherein the film is blue coloured, red coloured or green coloured and comprises a blue, red, or green pigment or a blue, red, or green dye inside one or more layers of the film or applied on one or both the surfaces of an outer layers of the film.

9. The thermoplastic film according to claim 1 , wherein the film is microperforated, wherein the diameter of the microperforations is comprised between 25 microns and 250 microns.

10. The thermoplastic film according to claim 1 formed into a flexible container by self-sealing the thermoplastic film or by sealing two separate pieces of the thermoplastic film to form a package for packaging fruits and/or vegetables.

11. The thermoplastic film according to claim 10 , wherein the flexible container is in the form of a pouch or bag.

12. Method for packaging fruits and/or vegetables comprising the following steps:

a) providing a sealable thermoplastic film comprising:

i. a first outer layer comprising between 40 and 60 wt % of a linear low density polyethylene, between 15 and 35 wt % of a medium density polyethylene, and between 15 wt % and 35 wt % of an ethylene-vinyl acetate copolymer, all wt % being based on the weight of the first outer layer;

ii. a second outer layer comprising between 40 and 60 wt % of a linear low density polyethylene, between 15 and 35 wt % of a medium density polyethylene, and between 15 wt % and 35 wt % of an ethylene-vinyl acetate copolymer, all wt % being based on the weight of the second outer layer; and

iii. an inner layer comprising between 80 and 97 wt % of a linear low density polyethylene and between 1 and 20 wt % of a low density polyethylene, wherein the total amount of polyethylene in the inner layer is at least 90 wt %, all wt % being based on the weight of the inner layer;

the thermoplastic film having:

an oxygen transmission rate between 8000 and 14000 cc/sqm·day·atm, measured according to ASTM D-3985 at 23° C. and 0% in-0% out relative humidity,

a CO2 transmission rate between 25000 to 41000 cc/sqm·day·atm, measured according to ASTM F-2476, at 23° C. and 0% in-0% out relative humidity,

a water vapour transmission rate between 8 and 35 g/sqm·day·atm, measured according to ASTM D1249 at 38° C. and 98% in-0% out relative humidity, and

a transmittance of less than 70% of light at wavelengths from the entirety of 200 to 400 nm, measured with the method as follows:

3 cm×1.7 cm pieces of film cut from portions of the film along a transverse direction are put into sample holders of a spectrophotometer equipped with a light source deuterium lamp (190-350 nm) and a halogen lamp (330-900 nm)

the spectrophotometer set to have a light wavelength range being 200-850 nm, under the following conditions:

resolution of 0.5 nm

response: medium

scanning speed: 100 nm/min

baseline flatness ±0.004 Abs

band width: 2 nm

photometric mode: absorbance

the instrument measured absorbance is converted by an integrated software into % transmittance,

b) running the film through a former thus forming a tube,

c) inserting one or more fruits and/or vegetables into the tube,

d) sealing the tube longitudinally forming a package,

e) sealing and cutting the tube transversally at the beginning and at the end of the package.

13. The method for packaging fruits and/or vegetables according to claim 12 , further comprising the following step of flushing an inert gas or a mixture of gases into the packaging between steps c) and e).

14. The method according to claim 12 for packaging fruits selected from the group consisting of bananas and mangoes.

15. A package comprising a sealable thermoplastic film comprising:

a) a first outer layer comprising between 40 and 60 wt % of a linear low density polyethylene, between 15 and 35 wt % of a medium density polyethylene, and between 15 wt % and 35 wt % of an ethylene-vinyl acetate copolymer, all wt % being based on the weight of the first outer layer;

b) a second outer layer comprising between 40 and 60 wt % of a linear low density polyethylene, between 15 and 35 wt % of a medium density polyethylene, and between 15 wt % and 35 wt % of an ethylene-vinyl acetate copolymer, all wt % being based on the weight of the second outer layer; and

c) an inner layer comprising between 80 and 97 wt % of a linear low density polyethylene and between 1 and 20 wt % of a low density polyethylene, wherein the total amount of polyethylene in the inner layer is at least 90 wt %, all wt % being based on the weight of the inner layer;

the thermoplastic film having:

an oxygen transmission rate between 8000 and 14000 cc/sqm·day·atm, measured according to ASTM D-3985 at 23° C. and 0% in-0% out relative humidity,

a CO2 transmission rate between 25000 to 41000 cc/sqm·day·atm, measured according to ASTM F-2476, at 23° C. and 0% in-0% out relative humidity,

a water vapour transmission rate between 8 and 35 g/sqm·day·atm, measured according to ASTM D1249 at 38° C. and 98% in-0% out relative humidity, and

a transmittance of less than 70% of light at wavelengths from the entirety of 200 to 400 nm, measured with the method as follows:

3 cm×1.7 cm pieces of film cut from portions of the film along a transverse direction are put into sample holders of a spectrophotometer equipped with a light source deuterium lamp (190-350 nm) and a halogen lamp (330-900 nm)

the spectrophotometer set to have a light wavelength range being 200-850 nm, under the following conditions:

resolution of 0.5 nm

response: medium

scanning speed: 100 nm/min

baseline flatness ±0.004 Abs

band width: 2 nm

photometric mode: absorbance

the instrument measured absorbance is converted by an integrated software into % transmittance,

and one or more fruits and/or vegetables packaged in said package.

16. The package according to claim 15 , comprising one or more fruits selected from the group consisting of bananas and mangoes.

17. The package according to claim 15 , wherein the thermoplastic film is oriented.

18. The package according to claim 15 , wherein the thermoplastic film has

an oxygen transmission rate between 10000 and 13000 cc/sqm·day·atm, measured according to ASTM D-3985 at 23° C. and 0% in-0% out relative humidity,

a CO2 transmission rate between 27000 to 39000 cc/sqm·day·atm, measured according to ASTM F-2476, at 23° C. and 0% in-0% out relative humidity,

a water vapour transmission rate between 20 and 30 g/sqm·day·atm, measured according to ASTM D1249 at 38° C. and 98% in-0% out relative humidity, and

a transmittance of less than 60% of light at wavelengths from the entirety of 200 to 400 nm, measured with the method as follows:

3 cm×1.7 cm pieces of film cut from portions of the film along a transverse direction are put into sample holders of a spectrophotometer equipped with a light source deuterium lamp (190-350 nm) and a halogen lamp (330-900 nm)

the spectrophotometer set to have a light wavelength range being 200-850 nm, under the following conditions:

resolution of 0.5 nm

response: medium

scanning speed: 100 nm/min

baseline flatness ±0.004 Abs

band width: 2 nm

photometric mode: absorbance

the instrument measured absorbance is converted by an integrated software into % transmittance.