Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto
This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).
1. A molecule having the structure of Formula One:
wherein:
(A) Ar 1 is (1a)
wherein, R 1 , R 2 , R 3 , R 4 , and R 5 are each independently selected from the group consisting of H, (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, and (C 1 -C 6 )haloalkoxy;
(B) Het is (1b)
wherein, R 6 is H;
(C) L 1 is
wherein R 8 and R 10 are each independently selected from the group consisting of H, (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy and (C 1 -C 6 )haloalkoxy;
(D) Ar 2 is (1e)
wherein:
(1) X 1 is selected from the group consisting of N and CR 13 ,
(2) X 2 is selected from the group consisting of N and CR 14 , and
(3) R 11 , R 12 , R 13 , and R 14 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , NR x R y , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, phenyl, (C 1 -C 6 )alkoxy, and (C 1 -C 6 )haloalkoxy;
(E) R 15 is H or (C 1 -C 6 )alkyl;
(F) Q 1 is selected from the group consisting of O and S;
(G) Q 2 is selected from the group consisting of O and S;
(H) L 2 is (1f)
wherein, R 20 , R 21 , R 22 , R 23 , and R 24 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , NR x R y , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 1 -C 6 )alkyl-O-(C 1 -C 6 )alkyl, (C 1 -C 6 )alkyl-S(O) n -(C 1 -C 6 )alkyl, (C 1 -C 6 )alkyl-S-(C 1 -C 6 )alkyl, and optionally R 20 and R 21 together form a (C 3 -C 8 )cycloalkyl;
(I) R 16 and R 17 along with C x (Q 2 )(N x ) is (1g)
wherein, R 18 and R 19 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , and NR x R y ;
(J) R x and R y are independently selected from H and (C 1 -C 6 )alkyl; and
(K) n is 1 or 2.
2. The molecule according to claim 1 wherein said molecule is
No.
Structure
F1
F2
F3
F4
F5
F6
F7
F8
F9
F10
F11
F12
F13
F14
F15
F16
F17
F18
F19
F20
F21
F22
F23
F24
F25
F26
F27
F28
F29
F30
F31
F32
3. The molecule according to claim 1 wherein at least one H is 2 H or at least one C is 14 C.
4. A pesticidal composition comprising a molecule according to claim 1 , further comprising an active ingredient having insecticidal, herbicidal, acaricidal, nematicidal, or fungicidal activity.
5. The molecule according to claim 1 wherein:
(A) Ar 1 is (1a)
wherein, R 1 , R 2 , R 3 , R 4 , and R 5 are each independently selected from the group consisting of H, CH 3 , CF 3 , OCH 3 , OCF 3 , OC 2 H 5 , and OC 2 F 5 ;
(B) Het is (1b)
wherein, R 6 is H;
(C) L 1 is
wherein R 8 and R 10 are each independently selected from the group consisting of H, CH 3 , CF 3 , OCH 3 , OCF 3 , OC 2 H 5 , and OC 2 F 5 ;
(D) Ar 2 is (1e)
wherein:
(1) X 1 is selected from the group consisting of N and CR 13 ,
(2) X 2 is CR 14 , and
(3) R 11 , R 12 , R 13 , and R 14 are each independently selected from the group consisting of H, F, Cl, CH 3 , CF 3 , OCH 3 , OCF 3 , OC 2 H 5 , and OC 2 F 5 ;
(E) R 15 is H or CH 3 ;
(F) Q 1 is O;
(G) Q 2 is S;
(H) L 2 is (1f)
wherein, R 20 , R 21 , R 22 , R 23 , and R 24 are each independently selected from the group consisting of H, F, Cl, Br, CH 3 , OCH 3 , CH 2 CH 3 , OCH 2 CH 3 , CH 2 CH 2 CH 3 , OCH 2 CH 2 CH 3 , CH 2 CH 2 CH 2 CH 3 , CH(CH 3 ) 2 , OCH(CH 3 ) 2 , CH 2 OCH 3 , CH(CH 3 )OCH 3 , CH(CH 3 )SCH 3 , CF 3 , OCF 3 , CH 2 CF 3 , OCH 2 CF 3 , CF 2 CH 3 , OCF 2 CH 3 , CF 2 CF 3 , OCF 2 CF 3 , CH 2 CH 2 CF 3 , OCH 2 CH 2 CF 3 , CF 2 CF 2 CH 3 , OCF 2 CF 2 CH 3 , CF 2 CF 2 CF 3 , OCF 2 CF 2 CF 3 , CF(CF 3 ) 2 , OCF(CF 3 ) 2 , CF 2 OCF 3 , CF(CF 3 )OCF 3 , and optionally R 20 and R 21 together form a (C 3 -C 8 )cycloalkyl; and
(I) R 16 and R 17 along with C x (Q 2 )(N x ), is (1g)
wherein, R 18 and R 19 are each independently selected from the group consisting of H, F, Cl, Br, CH 3 , OCH 3 , CF 3 , OCF 3 , NH 2 , and NO 2 .