IP Library Granted Patent US 11,370,883
Granted Patent B2
US 11,370,883 · App. 16/615,685 · Granted Jun 28, 2022

Polycarbonate resin composition, molded article, polycarbonate resin, and end-capping agent for polycarbonate resin

Inventors: Yuji Shibasaki (Iwate, JP); Hiroyoshi Maruyama (Kanagawa, JP); Kimitaka Nakao (Kanagawa, JP); Yuusuke Nii (Ibaraki, JP)
Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
C08G64/40C07C39/225C08K5/005C07C2602/10
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Quick Facts
Patent No.
US 11,370,883
App. No.
16/615,685
Granted
Jun 28, 2022
Kind
B2
Abstract

A polycarbonate resin composition, a molded article, a polycarbonate resin, and an end-capping agent for polycarbonate resins are provided. The polycarbonate resin composition contains: a polycarbonate resin having a terminal structure represented by Formula (A) and having a viscosity average molecular weight from 1×10 4 to 5×10 4 , and a stabilizer. In Formula (A), R 1 is selected from the group consisting of a hydrogen atom, halogen atoms, linear alkyl groups having from 1 to 9 carbons, branched alkyl groups having from 3 to 9 carbons, linear alkenyl groups having from 2 to 9 carbons, branched alkenyl groups having from 3 to 9 carbons, and aryl groups having from 6 to 12 carbons; and R 2 to R 7 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons.

Claims (18)

1. A polycarbonate resin composition comprising:

a polycarbonate resin having a terminal structure represented by Formula (A) and having a viscosity average molecular weight from 1×10 4 to 5×10 4 , and

a stabilizer;

wherein, R 1 is selected from the group consisting of a hydrogen atom, halogen atoms, linear alkyl groups having from 1 to 9 carbons, branched alkyl groups having from 3 to 9 carbons, linear alkenyl groups having from 2 to 9 carbons, branched alkenyl groups having from 3 to 9 carbons, and aryl groups having from 6 to 12 carbons; and R 2 to R 7 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons.

2. The polycarbonate resin composition according to claim 1 , wherein Formula (A) is represented by Formula (B):

wherein, R 2 to R 7 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons; and R 8 to R 12 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons.

3. The polycarbonate resin composition according to claim 1 , wherein Formula (A) is represented by Formula (C):

wherein, R 2 to R 7 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons; and R 8 to R 12 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons.

4. The polycarbonate resin composition according to claim 1 , wherein the stabilizer is at least one type selected from the group consisting of thermal stabilizers and antioxidants.

5. The polycarbonate resin composition of claim 1 , wherein the polycarbonate resin has a Tg of 151° C. or higher.

6. A polycarbonate resin having a terminal structure represented by Formula (A) and having a viscosity average molecular weight from 1×10 4 to 5×10 4 ;

wherein, R 1 is selected from the group consisting of a hydrogen atom, halogen atoms, linear alkyl groups having from 1 to 9 carbons, branched alkyl groups having from 3 to 9 carbons, linear alkenyl groups having from 2 to 9 carbons, branched alkenyl groups having from 3 to 9 carbons, and aryl groups having from 6 to 12 carbons; and R 2 to R 7 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons.

7. A molded article formed from the polycarbonate resin composition described in claim 1 .

8. The polycarbonate resin of claim 6 having a Tg of 151° C. or higher.

9. The polycarbonate resin according to claim 6 , wherein Formula (A) is represented by Formula (B):

wherein, R 2 to R 7 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons; and R 8 to R 12 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons.

10. The polycarbonate resin according to claim 6 , wherein Formula (A) is represented by Formula (C):

wherein, R 2 to R 7 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons; and R 8 to R 12 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 21, 2019
From: SHIBASAKI, YUJI; MARUYAMA, HIROYOSHI; NAKAO, KIMITAKA; NII, YUUSUKE
To: MITSUBISHI GAS CHEMICAL COMPANY, INC.
Reel/Frame 051080/0142 →
Priority Claims (1)
JP JP2017-103600 · May 25, 2017 · national
Continuity (1)
Related Publication 20200115496A1 · Apr 16, 2020