Multi-angle coating composition color strength measurement
View Patent ↗The color strength of a colored batch containing effect pigments can be measured and corrected using one or more non-uniformly weighted factors to determine, at a plurality of combinations of illumination angles and measurement angles, and at one or more wavelengths, the color and intensity of light reflected or absorbed by a coating film made from the batch in comparison to a reference color strength. Based on such comparison, let-downs or batches may be passed, rejected, mixed or otherwise dispersed. The composition of such let-downs or batches may also or instead be adjusted by adding non-effect pigments, effect pigments, binder, carrier, binder, or non-effect or effect pigments dispersed in either or both of a carrier and binder, in order to correct the let-down or batch color strength to within a desired tolerance of the reference color strength.
1. A method for measuring the color strength of a colored batch, the method comprising:
a) coating onto a substrate a portion of a first colored batch comprising one or more pigments dispersed in either or both of a carrier and binder, the first colored batch optionally including one or more effect pigments, to form a coated test film;
b) optionally hardening the test film;
c) illuminating the test film and measuring the intensity of light reflected or absorbed by the test film at a plurality of combinations of illumination angle and measurement angle, and at one or more wavelengths;
d) calculating a plurality of color strengths for the test film at such plurality of combinations of illumination angle and measurement angle, and at such one or more wavelengths;
e) determining a composite color strength for the test film by applying non-uniform weighting factors to such plurality of color strengths.
2. The method according to claim 1 , wherein the first colored batch comprises a liquid coating composition.
3. The method according to claim 1 , wherein the first colored batch comprises a powder coating composition.
4. The method according to claim 1 , wherein the color and intensity of light reflected or absorbed by the test film are determined using a plurality of measurement angles.
5. The method according to claim 1 , wherein the color and intensity of light reflected or absorbed by the test film are determined using a plurality of illumination angles.
6. The method according to claim 1 , wherein the color and intensity of light reflected or absorbed by the test film are determined using a plurality of illumination angles and a plurality of measurement angles.
7. The method according to claim 1 , wherein the color and intensity of light reflected or absorbed by the test film are determined at a plurality of wavelengths.
8. The method according to claim 1 , wherein the non-uniform weighting factors are all positive or zero values.
9. The method according to claim 1 , wherein the non-uniform weighting factors are a mixture of positive values, negative values and optionally zero values.
10. The method according to claim 1 , wherein the color and intensity of light reflected or absorbed by the test film are based on or partly based on measuring graininess or coarseness under diffuse illumination.
11. The method according to claim 1 , wherein the color and intensity of light reflected or absorbed by the test film are based on or partly based on measuring glint or sparkle under directional illumination.
12. The method according to claim 1 , wherein the color strength for the test film is calculated based on a maximum absorption peak for a plurality of combinations of illumination angle, measurement angle and wavelength.
13. The method according to claim 1 , wherein the color strength for the test film is calculated based on a maximum absorption peak for at least one combination of illumination angle and measurement angle, and averaged over a plurality of wavelengths.
14. The method according to claim 1 , wherein the first colored batch contains a plurality of pigments and the color strength calculations and weighting factors are determined separately for each pigment in the first colored batch.
15. The method according to claim 1 , wherein the first colored batch contains effect pigment flakes having an aspect ratio of at least 20:1.
16. The method according to claim 1 , wherein the first colored batch contains pigment particles having average particle diameters of about 5 μm and to about 100 μm.
17. The method according to claim 1 , further comprising:
comparing the composite color strength to one or more historic or contemporary composite color strengths obtained from one or more similarly coated and measured reference films made from one or more previously-prepared or contemporaneously-prepared reference colored batches; and
at least one of:
performing one or more of accepting, rejecting, mixing, milling or adjusting the composition of a remaining portion of the first colored batch, or
adding to such remaining portion non-effect pigments, effect pigments, carrier, binder, or non-effect or effect pigments dispersed in either or both of a carrier and binder, to provide a third colored batch whose similarly-measured composite color strength is within a desired tolerance of the reference colored batch composite color strength.
18. The method according to claim 17 , comprising adding to such remaining portion non-effect pigments, effect pigments, carrier, binder, or non-effect or effect pigments dispersed in either or both of a carrier and binder, to provide a third colored batch whose similarly-measured composite color strength is within a desired tolerance of the reference colored batch composite color strength.
19. The method according to claim 17 , comprising accepting, milling, or adjusting the composition of such remaining portion.
20. The method according to claim 1 , further comprising adjusting a color strength of the first colored batch by subjecting the first colored batch to milling, adding additional effect pigments to the first colored batch, or adding additional binder to the first colored batch.