IP Library Granted Patent US 11,543,120
Granted Patent B2
US 11,543,120 · App. 16/620,128 · Granted Jan 3, 2023

Method for inter-bed cooling in wet gas sulfuric acid plants

Inventors: Mads Lykke (Brønshøj, DK); Martin Møllerhøj (Birkerød, DK)
Assignee: HALDOR TOPSØE A/S
F22B1/18B01D53/8612B01J8/0492B01J8/0496C01B17/765C01B17/775C01B17/803C01B17/806B01D2257/304B01D2257/306B01J2208/00194
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Quick Facts
Patent No.
US 11,543,120
App. No.
16/620,128
Granted
Jan 3, 2023
Kind
B2
Abstract

In a method for cooling of process gas between catalytic layers or beds in a sulfuric acid plant, in which sulfuric acid is produced from feed gases containing sulfurous components like SO 2 , H 2 S, CS 2 and COS or liquid feeds like molten sulfur or spent sulfuric acid, one or more boilers, especially water tube boilers, are used instead of conventional steam superheaters to cool the process gas between the catalytic beds in the SO 2 converter of the plant. Thereby a less complicated and more cost efficient heat exchanger layout is obtained.

Claims (12)

1. A method for cooling of process gas between catalytic beds in a wet gas sulfuric acid plant, in which sulfuric acid is produced by condensation of H 2 SO 4 from a feed stream, wherein the feed stream comprises at least one of a feed gas containing sulfurous components and a liquid feed containing sulfurous components,

wherein at least one boiler is used to cool the process gas between the catalytic beds in a SO 2 converter of the plant.

2. The method according to claim 1 , wherein the at least one boiler is a water tube boiler.

3. The method according to claim 2 , wherein the orientation of the water tube boiler is approximately horizontal.

4. The method according to claim 3 , wherein the water tube boiler comprises tubes in a tube bank, wherein the tubes are bare, fitted with fins or have a combination of finned and bare tubes in the tube bank.

5. The method according to claim 2 , wherein the water tube boiler is provided with a process gas side bypass in order to be able to control the inlet temperature to a downstream catalyst bed.

6. The method according to claim 5 , wherein the bypass is internal.

7. The method according to claim 5 , wherein the bypass is external.

8. The method according to claim 2 , wherein the water tube boiler is placed within a shell of the SO 2 converter.

9. The method according to claim 1 , wherein the process gas originates from combustion of at least one feed stream of spent sulfuric acid.

10. The method according to claim 1 , wherein the feed stream is a CS 2 and H 2 S containing gas from a viscose fiber production plant.

11. The method according to claim 1 , wherein the inlet temperature to a downstream catalyst bed is controlled by using a mixer to equalize a temperature difference.

Assignments (2)
CHANGE OF NAME Recorded Oct 30, 2023
From: HALDOR TOPSØE A/S
To: TOPSOE A/S
Reel/Frame 065565/0685 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2020
From: LYKKE, MADS; MØLLERHØJ, MARTIN
To: HALDOR TOPSØE A/S
Reel/Frame 052062/0830 →
Priority Claims (1)
DK PA 2017 00402 · Jul 6, 2017 · national
Continuity (1)
Related Publication 20200149735A1 · May 14, 2020