Cobalt based alloy product
There is provided a cobalt-based alloy product comprising: in mass %, 0.08-0.25% C; 0.1% or less B; 10-30% Cr; 5% or less Fe and 30% or less Ni, the total amount of Fe and Ni being 30% or less; W and/or Mo, the total amount of W and Mo being 5-12%; 0.5% or less Si; 0.5% or less Mn; 0.003-0.04% N; 0.5 to 2 mass % of an M component being a transition metal other than W and Mo and having an atomic radius of more than 130 pm; and the balance being Co and impurities. The impurities include 0.5% or less Al and 0.04% or less O. The product is a polycrystalline body of matrix phase crystal grains. In the matrix phase crystal grains, segregation cells with an average size of 0.13-2 μm are formed, in which the M component is segregated in boundary regions of the segregation cells.
1. A product formed of a cobalt based alloy, the cobalt based alloy having a chemical composition comprising:
0.08 to 0.25 mass % of carbon;
0.1 mass % or less of boron;
10 to 30 mass % of chromium;
5 mass % or less of iron, 30 mass % or less of nickel, the total amount of the iron and the nickel being 30 mass % or less;
tungsten and/or molybdenum, the total amount of the tungsten and the molybdenum being 5 to 12 mass %;
0.5 mass % or less of silicon;
0.5 mass % or less of manganese;
0.003 to 0.04 mass % of nitrogen;
M components, each of the M components being a transition metal other than tungsten and molybdenum and having an atomic radius of more than 130 pm, the total amount of the M components being 0.69 to 2 mass %; and
the balance being cobalt and impurities, the impurities including 0.5 mass % or less of aluminum, and 0.04 mass % or less of oxygen,
wherein the product is a polycrystalline body of matrix phase crystal grains, and
wherein in the matrix phase crystal grains of the polycrystalline body, segregation cells with an average size of 0.13 to 2 pm are formed, in which the M components are segregated in boundary regions of the segregation cells.
2. The product according to claim 1 ,
wherein each of the M components is a component being capable of generating an MC type carbide phase of a simple cubic crystal system, and
wherein grains of the MC type carbide phase are precipitated on the boundary regions of the segregation cells.
3. The product according to claim 1 , wherein
the M components of the chemical composition include two or more of titanium, zirconium, hafnium, vanadium, niobium and tantalum.
4. The product according to claim 3 , wherein:
in the case that the chemical composition includes the titanium as one of the M components, content of the titanium is 0.01 to 1 mass %;
in the case that the chemical composition includes the zirconium as one of the M components, content of the zirconium is 0.05 to 1.5 mass %;
in the case that the chemical composition includes the hafnium as one of the M components, content of the hafnium is 0.01 to 0.5 mass %;
in the case that the chemical composition includes the vanadium as one of the M components, content of the vanadium is 0.01 to 0.5 mass %;
in the case that the chemical composition includes the niobium as one of the M components, content of the niobium is 0.02 to 1 mass %; and
in the case that the chemical composition includes the tantalum as one of the M components, content of the tantalum is 0.05 to 1.5 mass %.
5. The product according to claim 3 wherein
the zirconium is an essential component as one of the M components of the chemical composition.
6. The product according to claim 1 , wherein
the product exhibits a creep rupture time of 1,500 hours or more by a creep test under conditions of a temperature of 850° C. and a stress of 180 MPa.
7. The product according to claim 1 , wherein
the product is a high temperature member.
8. The product according to claim 7 , wherein the high temperature member is a turbine stator blade, a turbine rotor blade, a turbine combustor nozzle, or a heat exchanger.
9. The product according to claim 2 , wherein
the M components of the chemical composition are two or more of titanium, zirconium, hafnium, vanadium, niobium and tantalum.
10. The product according to claim 9 , wherein
in the case that the chemical composition includes the titanium as one of the M components, content of the titanium is 0.01 to 1 mass %;
in the case that the chemical composition includes the zirconium as one of the M components, content of the zirconium is 0.05 to 1.5 mass %;
in the case that the chemical composition includes the hafnium as one of the M components, content of the hafnium is 0.01 to 0.5 mass %;
in the case that the chemical composition includes the vanadium as one of the M components, content of the vanadium is 0.01 to 0.5 mass
in the case that the chemical composition includes the niobium as one of the M components, content of the niobium is 0.02 to 1 mass %; and
in the case that the chemical composition includes the tantalum as one of the M components, content of the tantalum is 0.05 to 1.5 mass %.
11. The product according to claim 4 , wherein
the zirconium is an essential component as one of the M components of the chemical composition.
12. The product according to claim 9 , wherein
the zirconium is an essential component as one of the M components of the chemical composition.
13. The product according to claim 10 , wherein
the zirconium is an essential component as one of the M components of the chemical composition.