Polyolefin composition with improved surface appearance
The present invention is directed to a heterophasic polypropylene composition (HECO1) and the use thereof to reduce the amount of flow marks of an injection moulded polyolefin composition. Further, the present invention is directed to a polyolefin composition (C) comprising a polyolefin (PO), said heterophasic polypropylene composition (HECO1) and optionally a filler as well as an article comprising said polyolefin composition (C).
1. A heterophasic polypropylene composition (HECO1), comprising:
i) a matrix (M) comprising a first propylene polymer (PP1) and a second propylene polymer (PP2), and
ii) an elastomeric propylene copolymer (EPR) being a copolymer of propylene and ethylene and/or a C 4 to C 8 α-olefin dispersed within the matrix (M),
wherein the ratio MFR(PP1)/MFR(PP2) is above 10,000, wherein MFR(PP1) is the melt flow rate MFR (230° C., 2.16 kg) in [g/10 min] determined according to ISO 1133 of the first propylene polymer (PP1) and MFR(PP2) is the melt flow rate MFR (230° C., 2.16 kg) in [g/10 min] determined according to ISO 1133 of the second propylene polymer (PP2).
2. The heterophasic polypropylene composition (HECO1) according to claim 1 , wherein the second propylene polymer (PP2) has a melt flow rate MFR (230° C., 2.16 kg) determined according to ISO 1133 equal or below 10.0 g/10 min.
3. A heterophasic polypropylene composition (HECO1), comprising:
i) a matrix (M) comprising a first propylene polymer (PP1) and a second propylene polymer (PP2), wherein the second propylene copolymer has a melt flow rate MFR (230° C., 2.16 kg) determined according to ISO 1133 of equal or below 0.05 g/10 min, and
ii) an elastomeric propylene copolymer (EPR) dispersed within the matrix (M),
wherein the ratio MFR(PP1)/MFR(PP2) is above 61, wherein MFR(PP1) is the melt flow rate MFR (230° C., 2.16 kg) in [g/10 min] determined according to ISO 1133 of the first propylene polymer (PP1) and MFR(PP2) is the melt flow rate MFR (230° C., 2.16 kg) in [g/10 min] determined according to ISO 1133 of the second propylene polymer (PP2).
4. The heterophasic polypropylene composition (HECO1) according to claim 1 , wherein the first propylene polymer (PP1) has a melt flow rate MFR (230° C., 2.16 kg) determined according to ISO 1133 equal or above 100 g/10 min.
5. The heterophasic polypropylene composition (HECO1) according to claim 1 , wherein the matrix (M) comprises the first propylene polymer (PP1) and the second propylene polymer (PP2) in a weight ratio of 99:1 to 80:20.
6. The heterophasic polypropylene composition (HECO1) according to claim 1 , having a xylene soluble fraction (XCS) in the range of 10.0 to 50.0 wt. %.
7. The heterophasic polypropylene composition (HECO1) according to claim 6 , wherein the comonomer content of the xylene soluble fraction (XCS) is in the range of 20.0 to 65.0 mol %.
8. The heterophasic polypropylene composition (HECO1) according to claim 1 , comprising the matrix (M) and the elastomeric propylene copolymer (EPR) in a weight ratio of 70:30 to 30:70.
9. The heterophasic polypropylene composition (HECO1) according to claim 1 , wherein the elastomeric propylene copolymer (EPR) comprises:
i) a first elastomeric propylene copolymer (EPR1), and
ii) a second elastomeric propylene copolymer (EPR2),
wherein the ratio C(EPR2)/C(EPR1) is in the range of 1.1 to 10.0, wherein C(EPR2) is the comonomer content in [mol %] of the second elastomeric propylene copolymer (EPR2) and (EPR1) is the comonomer content in [mol %] of the first elastomeric propylene copolymer (EPR1).
10. The heterophasic polypropylene composition (HECO1) according to claim 1 , having a melt flow rate MFR (230° C., 2.16 kg) determined according to ISO 1133 equal or below 10.0 g/10 min.
11. The heterophasic polypropylene composition (HECO1) according to claim 1 , wherein said heterophasic polypropylene composition (HECO1)
a) is free of phthalic acid esters as well as their respective decomposition products and
b) has 2,1 regio defects of less than 0.4% determined by 13 C-NMR spectroscopy.
12. A polyolefin composition (C), comprising:
i) a polyolefin (PO),
ii) the heterophasic polypropylene composition (HECO1) according to claim 1 , and
iii) optionally an inorganic filler (F).
13. The polyolefin composition (C) according to claim 12 , comprising 5.0 to 30.0 wt. % of the heterophasic polypropylene composition (HECO1), based on the overall weight of the polypropylene composition (C).
14. A polyolefin composition (C) according to claim 12 , wherein the polyolefin (PO) is a polypropylene being different than the heterophasic polypropylene composition (HECO1).
15. An injection moulded article, comprising the polyolefin composition (C) according to claim 14 .