IP Library Granted Patent US 11,542,380
Granted Patent B2
US 11,542,380 · App. 16/621,818 · Granted Jan 3, 2023

Foam molded product of thermoplastic polyester elastomer resin and method for producing the same

Inventors: Eri Morio (Shiga, JP); Takuya Akaishi (Shiga, JP)
Assignee: TOYOBO CO., LTD.
C08J9/34B29C44/42B29C45/56C08J9/0061C08J9/122C08L67/025B29K2067/00B29K2105/04C08J2203/06C08J2203/08C08J2367/02C08J2425/14C08L2203/14
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Quick Facts
Patent No.
US 11,542,380
App. No.
16/621,818
Granted
Jan 3, 2023
Kind
B2
Abstract

According to the present invention, there is provided a foam molded product of thermoplastic polyester elastomer resin which exhibits light weight and excellent rebound resilience. The foam molded product is characterized in that, the foam molded product has a foamed layer consisting of a resin phase and an isolated foamed cell.

Claims (24)

1. A foam molded product of thermoplastic polyester elastomer resin, comprising:

a foamed layer consisting of a resin phase and an isolated foamed cell,

wherein the resin phase contains a thermoplastic polyester elastomer (A),

wherein the thermoplastic polyester elastomer (A) is prepared by bonding a hard segment and at least one soft segment,

wherein the hard segment consists of polyester constituted from aromatic dicarboxylic acid and aliphatic and/or alicyclic diol as constituting ingredients,

wherein the at least one soft segment is selected from the group consisting of aliphatic polyether, aliphatic polyester and aliphatic polycarbonate,

wherein a content of the soft segment is 55 to 90% by mass,

wherein an average cell diameter of the foamed cell is 10 to 400 μm,

wherein the maximum cell diameter of the foamed cell is 10 to 500 μm,

wherein rebound resilience of the foam molded product is 60 to 90%, and

wherein density of the foam molded product is 0.1 to 0.35 g/cm 3 .

2. The foam molded product of thermoplastic polyester elastomer resin according to claim 1 , wherein the average cell diameter of the foamed cell is 200 to 400 μm.

3. The foam molded product of thermoplastic polyester elastomer resin according to claim 1 , wherein the density of the foam molded product is 0.1 to 0.25 g/cm 3 .

4. The foam molded product of thermoplastic polyester elastomer resin according to claim 1 , wherein the rebound resilience of the foam molded product is 70% to 90%.

5. The foam molded product of thermoplastic polyester elastomer resin according to claim 1 ,

wherein each surface of the foam molded product has a non-foamed skin layer having a thickness of 100 to 800 μm,

wherein an inner layer of the foam molded product includes the foamed layer, and

wherein the foam molded product has a sandwich structure of the non-foamed skin layers and the foamed layer in a thickness direction.

6. A method for producing the foam molded product of thermoplastic polyester elastomer resin according to claim 1 , comprising:

injecting a resin ingredient containing the polyester elastomer resin in a melted state together with a chemical foaming agent and/or an inert gas in a supercritical state into a cavity defined by clamped plural molds, thereby filling the cavity, and

when a non-foamed skin layer having a thickness of 100 to 800 μm is formed on each surface of the foam molded product, moving at least one of the plural molds in a mold-opening direction so as to expand a volume of the cavity,

wherein a core back transition time is 0.5 seconds to 5 seconds, and

wherein a molding temperature is a melting point of the resin plus 10 to 50° C.

7. The method for producing the foam molded product of thermoplastic polyester elastomer resin according to claim 6 , wherein the inert gas in a supercritical state is nitrogen.

Assignments (3)
CHANGE OF ADDRESS Recorded Aug 7, 2023
From: TOYOBO CO., LTD.
To: TOYOBO CO., LTD.
Reel/Frame 064505/0124 →
DE-MERGER Recorded Aug 7, 2023
From: TOYOBO CO., LTD.
To: TOYOBO MC CORPORATION
Reel/Frame 064505/0803 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 12, 2019
From: MORIO, ERI; AKAISHI, TAKUYA
To: TOYOBO CO., LTD.
Reel/Frame 051264/0742 →
Priority Claims (1)
JP JP2017-124910 · Jun 27, 2017 · national
Continuity (1)
Related Publication 20200123341A1 · Apr 23, 2020