Curable organopolysiloxane composition containing dynamic covalent polysiloxane

1. A curable organopolysiloxane composition containing dynamic covalent organopolysiloxanes which yields, upon cure, a silicone having adaptive elastomeric and viscous characteristics, the curable organopolysiloxane composition comprising:

(a) alkenyl-containing organopolysiloxanes having an average of at least two alkenyl radicals per molecule;

(b) hydride-containing organopolysiloxanes having an average of at least two silicon-bonded hydrogen atoms per molecule;

(c) a dynamic covalent organopolysiloxane, wherein the dynamic covalent organopolysiloxane is an organopolysiloxane having dynamic covalent bonds; and

(d) a metal complex catalyst.

2. The curable organopolysiloxane composition of claim 1 , wherein the alkenyl-containing organopolysiloxanes and hydride-containing organopolysiloxanes independently comprise a total of 1-10,000 units of formulas I, II, and III below:

wherein,

R 1 , R 2 , and R 3 independently represent alkyl, cycloalkyl, or phenyl;

alkyl groups are branched or unbranched, saturated or unsaturated, and have 1-12 carbon atoms in their longest chain;

cycloalkyl groups are carbocyclic, unfused, non-aromatic ring systems having a total of 5-12 rings members;

each alkyl, cycloalkyl, or phenyl group may be unsubstituted or substituted with one or more substituent at any position;

alkyl substituents are halo, cycloalkyl, phenyl, hydroxyl, and ether;

cycloalkyl substituents are halo, alkyl, alkoxy, phenyl, and hydroxyl; and

phenyl substituents are alkyl and alkoxy.

3. The curable organopolysiloxane composition of claim 1 , wherein the alkenyl-containing organopolysiloxanes are alkenyl-terminated organopolysiloxanes, alkenyl-pendant organopolysiloxanes, or combinations thereof.

4. The curable organopolysiloxane composition of claim 1 , wherein the hydride-containing organopolysiloxanes are hydride-terminated organopolysiloxanes, hydride-pendant organopolysiloxanes, or combinations thereof.

5. The curable organopolysiloxane composition of claim 1 , wherein the dynamic covalent organopolysiloxanes comprise imines, acyl hydrazones, boronate esters, alkoxy amines, and combinations thereof.

6. The curable organopolysiloxane composition of claim 5 , wherein the dynamic covalent organopolysiloxanes are boronate esters.

7. The curable organopolysiloxane composition of claim 1 , wherein the metal complex catalyst is selected from the group consisting of platinum (Pt), ruthenium (Ru), rhodium (Rh), palladium (Pd), iridium (Jr), and combinations thereof.

8. The curable organopolysiloxane composition of claim 1 , wherein the metal complex catalyst is a Pt complex catalyst.

9. The curable organopolysiloxane composition of claim 8 , wherein the Pt complex catalyst is Karstedt's catalyst or Speier's catalyst.

10. The curable organopolysiloxane composition of claim 1 , wherein the composition further comprises fillers and treating agents.

11. The curable organopolysiloxane composition of claim 1 , wherein the composition further comprises blowing agents, surfactants, or combinations thereof.

12. The curable organopolysiloxane composition of claim 1 , wherein the alkenyl-containing organopolysiloxanes and hydride-containing organopolysiloxanes are not silanol-terminated.

13. A method of making a silicone rubber composition comprising the steps of:

combining (a) alkenyl-containing organopolysiloxanes having an average of at least two alkenyl radicals per molecule; (b) hydride-containing organopolysiloxanes having an average of at least two silicon-bonded hydrogen atoms per molecule; (c) a dynamic covalent organopolysiloxane, wherein the dynamic covalent organopolysiloxane is an organopolysiloxane having dynamic covalent bonds; and (d) a metal complex catalyst to form a mixture; and

curing the mixture under conditions sufficient to form a silicone rubber composition.

14. The method of claim 13 , wherein the preferred curing temperature is about 70° C. to about 150° C.

15. The method of claim 13 , wherein the dynamic covalent organopolysiloxanes comprise imines, acyl hydrazones, boronate esters, alkoxy amines, and combinations thereof.

16. The method of claim 13 , wherein the metal complex catalyst is selected from the group consisting of platinum (Pt), ruthenium (Ru), rhodium (Rh), palladium (Pd), iridium (Jr), and combinations thereof.

17. The method of claim 13 , wherein the metal complex catalyst is a Pt complex catalyst.

18. The method of claim 17 , wherein the Pt complex catalyst is Karstedt's catalyst or Speier's catalyst.

19. The method of claim 13 , wherein fillers and treating agents are added to the mixture during the combining step.

20. The method of claim 13 , wherein blowing agents, surfactants, or combinations thereof are added to the mixture during the combining step.

21. The method of claim 13 , further comprising, prior to the curing step, the step of placing the mixture into a mold.

22. A shaped article comprising a cured silicone rubber composition comprising the reaction product of:

(a) alkenyl-containing organopolysiloxanes having an average of at least two alkenyl radicals per molecule;

(b) hydride-containing organopolysiloxanes having an average of at least two silicon-bonded hydrogen atoms per molecule;

(c) a dynamic covalent organopolysiloxane, wherein the dynamic covalent organopolysiloxane is an organopolysiloxane having dynamic covalent bonds; and

(d) a metal complex catalyst;

wherein:

the alkenyl-containing organopolysiloxanes and hydride-containing organopolysiloxanes independently comprise a total of 1-10.000 units of formulas I, II, and III below:

wherein,

R 1 , R 2 , and R 3 independently represent alkyl, cycloalkyl, or phenyl;

alkyl groups are branched or unbranched, saturated or unsaturated, and have 1-12 carbon atoms in their longest chain;

cycloalkyl groups are carbocyclic, unfused, non-aromatic ring systems having a total of 5-12 rings members;

each alkyl, cycloalkyl, or phenyl group may be unsubstituted or substituted with one or more substituent at any position;

alkyl substituents are halo, cycloalkyl, phenyl, hydroxyl, and ether;

cycloalkyl substituents are halo, alkyl, alkoxy, phenyl, and hydroxyl; and

phenyl substituents are alkyl and alkoxy.