Catalyst composition for preparing elastic copolymer, and method for preparing elastic copolymer, which comprises ethylene and alpha-olefin or ethylene, alpha-olefin and unconjugated diene, by using same
The present invention relates to a method for preparing an ethylene-based elastic copolymer, and more particularly, to a method for preparing an ethylene-based elastic copolymer by using a catalyst composition for preparing an ethylene-based elastic copolymer, the catalyst composition comprising a binuclear constrained geometry transition metal compound, as a main catalyst, having a structural advantage to obtain a high-molecular-weight ethylene-based elastic copolymer due to a high polymerization activity and comonomer reactivity because the binuclear constrained geometry transition metal compound has a structure in which cyclopentadiene ligands of two constrained geometry catalysts are linked by 1,4-phenylene, and one or more cocatalyst compounds selected from the group consisting of an organoaluminum compound, an organoaluminoxane compound, and a boron compound.
1. A method for preparing an ethylene-based elastic copolymer in the presence of a catalyst composition comprising a binuclear constrained geometry transition metal compound represented by Formula 1 and one or more cocatalyst compounds selected from the group consisting of an organoaluminum compound, an organoaluminoxane compound, and a boron compound,
wherein the ethylene-based elastic copolymer is a copolymer of ethylene, propylene, and C4-C30 diene,
a polymerization temperature is in a range of 100 to 200° C.,
an ethylene conversion is 60 to 80%,
a propylene conversion is 40 to 50%, and
a content of the propylene in the ethylene-based elastic copolymer is 40 to 70 wt %
2. The method of claim 1 , wherein
the diene is one or more selected from the group consisting of 1,3-butadiene, 1,4-pentadiene, 1,4-hexadiene, 1,5-hexadiene, 1,5-heptadiene, 1,6-heptadiene, 1,6-octadiene, 1,7-octadiene, 1,7-nonadiene, 1,8-nonadiene, 1,8-decadiene, 1,9-decadiene, 1,12-tetradecadiene, 1,13-tetradecadiene, 2,3-dimethyl-1,3-butadiene, 3-methyl-1,4-hexadiene, 3-methyl-1,5-hexadiene, 3-ethyl-1,4-hexadiene, 3-ethyl-1,5 -hexadiene, 3,3-dimethyl-1,4-hexadiene, 3,3-dimethyl-1,5-hexadiene, 5-vinyl-2-norbornene, 2,5-norbornadiene, 7-methyl-2,5-norbornadiene, 7-ethyl-2,5-norbornadiene, 7-propyl-2,5-norbornadiene, 7-butyl-2,5-norbornadiene, 7-phenyl-2,5-norbornadiene, 7-hexyl-2,5-norbornadiene, 7,7-dimethyl-2,5-norbornadiene, 7-methyl-7-ethyl-2,5-norbornadiene, 7-chloro-2,5-norbornadiene, 7-bromo-2,5-norbornadiene, 7-fluoro-2,5-norbornadiene, 7,7-dichloro-2,5-norbornadiene, 1-methyl-2,5-norbornadiene, 1-ethyl-2,5-norbornadiene, 1-propyl-2,5-norbornadiene, 1-butyl-2,5-norbornadiene, 1-chloro-2,5-norbornadiene, 1-bromo-2,5-norbornadiene, 5-isopropenyl-2-norbornene, 5-ethylidene-2-norbornene (ENB), 5-vinylidene-2-norbornene (VNB), 5-methylene-2-norbornene (MNB), and dicyclopentadiene.
3. The method of claim 1 , wherein
a polymerization pressure is in a range of 10 to 200 bar.
4. The method of claim 1 , wherein
a weight average molecular weight of the ethylene-based elastic copolymer is in a range of 10,000 to 1,500,000 g/mol, and a molecular weight distribution of the ethylene-based elastic copolymer is in a range of 2.0 to 15.
5. The method of claim 1 , wherein
a content of the ethylene in the ethylene-based elastic copolymer is 20 to 85 wt %, and a content of the diene in the ethylene-based elastic copolymer is 0.1 to 15 wt %.