Solvent-free photo-curable resin composition for polarizing plate protective layer, polarizing plate comprising cured product thereof, and image display device
A solvent free-type photocurable resin composition for a polarizing plate protective layer includes an acryl-based prepolymer comprising a (meth)acrylate-based monomer as a polymerization unit; and an isocyanate-based crosslinking agent, wherein the acryl-based prepolymer is in a partially polymerized state, and viscosity at 25° C. is greater than or equal to 50 cPs and less than or equal to 300 cPs. A polarizing plate including the solvent free-type photocurable resin composition, and an image display device including the polarizing plate is also provided.
1. A solvent-free photocurable resin composition for a polarizing plate protective layer comprising:
an acryl-based resin comprising (1) a first structure unit derived from a first acrylate-based monomer; (2) a second structure unit derived from a second acrylate-based monomer having hydroxyl crosslinking groups; and (3) unpolymerized monomers selected from a group consisting of the first acrylate-based monomer, the second acrylate-based monomer, and combinations thereof, thereby producing the acryl-based resin with a degree of partial polymerization, wherein the first structure unit and the second structure unit were partially co-polymerized, in the absence of a photoinitiator, the first structure unit being included in 98 parts by weight and the second structure unit being included in 2 parts by weight when the first structure unit and the second structure unit were partially co-polymerized; and
an acrylate-based isocyanate crosslinking agent, wherein the acrylate-based isocyanate crosslinking agent is included in 10 parts by weight to 20 parts by weight with respect to 100 parts by weight of the acryl-based resin;
wherein the degree of partial polymerization is selected such that the solvent-free photocurable resin composition has a viscosity at 25° C. of greater than or equal to 50 cPs and less than or equal to 300 cPs while having a solid content of 99.7% or higher;
wherein the first structure unit is iso-bornyl acrylate (IBOA), the second structure unit is 4-hydroxylbutyl acrylate (4-HBA) and the acrylate-based isocyanate crosslinking agent is 2-isocyanatoethyl acrylate (AOI).
2. The solvent-free photocurable resin composition of claim 1 , further comprising one or more additives selected from the group consisting of a dye, a pigment, an epoxy resin, an ultraviolet stabilizer, an antioxidant, a colorant, a reinforcing agent, a filler, a defoamer, a surfactant, a photoviscosity agent and a plasticizer.
3. The solvent-free photocurable resin composition of claim 1 , wherein the acryl-based resin has a weight average molecular weight of greater than or equal to 300,000 and less than or equal to 2,000,000.
4. The solvent-free photocurable resin composition of claim 1 , wherein the acryl-based resin has a degree of polymerization of greater than or equal to 5% and less than or equal to 20%.
5. The solvent-free photocurable resin composition of claim 1 , wherein the acryl-based resin consists of the first structure unit, the second structure unit, the acrylate-based isocyanate crosslinking agent, the unpolymerized monomers and a photoinitiator.
6. An image display device comprising the polarizing plate of claim 1 .
7. A polarizing plate comprising:
a polarizer; and
a protective layer provided on one surface or both surfaces of the polarizer,
wherein the protective layer is a cured material of the solvent-free photocurable resin composition of claim 1 .
8. The polarizing plate of claim 7 , wherein the protective layer has a thickness of greater than or equal to 4 μm and less than or equal to 11 μm.
9. The polarizing plate of claim 7 , wherein the protective layer is provided on each of both surf aces of the polarizer.