IP Library Granted Patent US 11,584,970
Granted Patent B2
US 11,584,970 · App. 16/649,739 · Granted Feb 21, 2023

High manganese steel for low temperature applications having excellent surface quality and a manufacturing method thereof

Inventors: Yu-Mi Ha (Gwangyang-si, KR); Young-Deok Jung (Gwangyang-si, KR); Sang-Deok Kang (Gwangyang-si, KR); Un-Hae Lee (Gwangyang-si, KR); Yong-Jin Kim (Gwangyang-si, KR); Sung-Kyu Kim (Gwangyang-si, KR); Young-Ju Kim (Pohang-si, KR)
Assignee: POSCO CO., LTD
C21D8/005C21D6/002C21D6/005C21D6/008C21D7/13C21D8/02C21D8/021C21D8/0205C21D8/0226C21D8/0263C21D9/00C21D9/0081C21D9/46C22C38/00C22C38/001C22C38/002C22C38/02C22C38/04C22C38/06C22C38/14C22C38/16C22C38/18C22C38/20C22C38/28C22C38/32C22C38/38C21D2211/001Y10T428/12951Y10T428/12972Y10T428/12979Y10T428/26
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Quick Facts
Patent No.
US 11,584,970
App. No.
16/649,739
Granted
Feb 21, 2023
Kind
B2
Abstract

The present invention relates to a high manganese steel for low temperature applications and a method for manufacturing the same. The high manganese steel contains 0.3 wt % to 0.8 wt % of C, 18 wt % to 26 wt % of Mn, 0.01 wt % to 1 wt % of Si, 0.01 wt % to 0.5 wt % of Al, 0.1 wt % or less of Ti (excluding 0%), 1 wt % to 4.5 wt % of Cr, 0.1 wt % to 0.9 wt % of Cu, 0.03 wt % or less of S (excluding 0%), 0.3 wt % or less of P (excluding 0%), 0.001 wt % to 0.03 wt % of N, 0.004 wt % or less of B (excluding 0%), and a remainder of Fe and other inevitable impurities, wherein a microstructure comprises an austenite single phase structure, and an average grain size of the austenite is 50 μm or less.

Claims (30)

1. A high manganese steel for low temperature applications, comprising:

0.3 wt % to 0.8 wt % of C, 18 wt % to 26 wt % of Mn, 0.01 wt % to 1 wt % of Si, 0.01 wt % to 0.5 wt % of Al, 0.1 wt % or less of Ti (excluding 0%), 1 wt % to 4.5 wt % of Cr, 0.1 wt % to 0.9 wt % of Cu, 0.03 wt % or less of S (excluding 0%), 0.3 wt % or less of P (excluding 0%), 0.001 wt % to 0.03 wt % of N, 0.004 wt % or less of B (excluding 0%), and a remainder of Fe and other inevitable impurities,

wherein a microstructure comprises an austenite single phase structure,

an average grain size of the austenite is 50 μm or less, and

a number of an austenite grain having a grain size of 50 μm or more is less than 1 per Cm 2 .

2. The high manganese steel of claim 1 , wherein an average grain size of the austenite structure is 20 μm to 30 μm.

3. The high manganese steel of claim 1 , wherein, in the austenite structure, a number of austenite grains having a grain size of 30 μm or more is less than 1 per cm 2 .

4. The high manganese steel of claim 1 , wherein the high manganese steel has rolling direction impact toughness of 100 J or higher at −196° C.

5. The high manganese steel of claim 1 , wherein the high manganese steel has an anisotropy index of 0.6 or higher, wherein the anisotropy index is a ratio of thickness direction impact toughness at −196° C. to rolling direction impact toughness at −196° C.

6. The high manganese steel of claim 1 , wherein the high manganese steel has yield strength of 400 MPa or higher.

7. The high manganese steel of claim 1 , wherein the high manganese steel is manufactured by a manufacturing method comprising preparing a slab having the composition of claim 1 , reheating the slab and hot rolling the reheated slab,

wherein a recrystallization structure having less than 1 grain having a grain size of 150 μm or more is formed per cm 2 on a surface layer portion (a region of the slab surface layer portion up to 2 mm from the surface in a slab thickness direction) of the slab before reheating.

8. The high manganese steel of claim 7 , wherein an average grain size of the surface layer portion of the slab before reheating is 100 μm or less.

9. The high manganese steel of claim 7 , wherein the slab before reheating has a cross-section reduction rate of at least 60% at 1100° C.

10. The high manganese steel of claim 1 , wherein the high manganese steel has a thickness of 8.0 mm to 40 mm.

11. A method of manufacturing a high manganese steel for low temperature applications according to claim 1 , the method comprising:

preparing a slab comprising 0.3 wt % to 0.8 wt % of C, 18 wt % to 26 wt % of Mn, 0.01 wt % to 1 wt % of Si, 0.01 wt % to 0.5 wt % of Al, 0.1 wt % or less of Ti (excluding 0%), 1 wt % to 4.5 wt % of Cr, 0.1 wt % to 0.9 wt % of Cu, 0.03 wt % or less of S (excluding 0%), 0.3 wt % or less of P (excluding 0%), 0.001 wt % to 0.03 wt % of N, 0.004 wt % or less of B (excluding 0%), and a remainder of Fe and other inevitable impurities;

deformation application involving applying a deformation to the slab such that a recrystallization microstructure is formed on a surface layer portion of the slab;

air cooling involving air-cooling the slab on which the recrystallization microstructure is formed on the surface layer portion thereof to room temperature;

reheating involving heating the air-cooled slab to 1100° C. to 1250° C.;

hot rolling involving finish-rolling the reheated slab at 850° C. to 950° C. to obtain a hot-rolled steel; and

accelerated cooling involving accelerated-cooling the hot-rolled steel at a cooling speed of 10° C./sec or more to an accelerated cooling termination temperature of 600° C. or less.

12. The method of claim 11 , wherein the deformation application is performed by rough rolling under a high reduction condition at 1000° C. to 1200° C.

13. The method of claim 11 , wherein the deformation application is performed by high temperature forging at 1000° C. to 1200° C.

14. The method of claim 11 , wherein the deformation application is performed such that a number of grains having a grain size of at least 150 μm on the surface layer portion (a region of the slab surface layer portion up to 2 mm from the surface in a slab thickness direction) is less than 1 per cm 2 by rough rolling under a high reduction condition at 1000° C. to 1200° C.

15. The method of claim 11 , wherein an average grain size of the surface layer portion of the slab after the deformation application is 100 μm or less.

16. The method of claim 11 , wherein the deformation application is performed such that a thickness reduction rate is 15% to 50% for an initial slab.

17. The method of claim 11 , wherein, in the hot rolling, a final pass rolling temperature during hot finish rolling is 850° C. or above and less than 900° C. when a final thickness of the steel is 18 mm or above, and a final pass rolling temperature during hot finish rolling is 900° C. to 950° C. when a final thickness of the steel is less than 18 mm.

18. The method of claim 11 , wherein, in the hot rolling, a reduction ratio is 40% or more of a total reduction rate at a temperature below a non-recrystallization temperature (Tnr) when a final thickness of the steel is 18 mm or above.

19. The method of claim 11 , wherein the hot-rolled steel has a thickness of 8 mm to 40 mm.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061774/0129 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061561/0705 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2020
From: HA, YU-MI; JUNG, YOUNG-DEOK; KANG, SANG-DEOK; LEE, UN-HAE; KIM, YONG-JIN; KIM, SUNG-KYU; KIM, YOUNG-JU
To: POSCO
Reel/Frame 052198/0309 →
Priority Claims (2)
KR 10-2017-0135464 · Oct 18, 2017 · national
KR 10-2018-0115926 · Sep 28, 2018 · national
Continuity (1)
Related Publication 20200263268A1 · Aug 20, 2020