Titania-carbon nanotube-sulfur (TiO
A titania-carbon-sulfur composite including a titania-carbon composite prepared by mixing cylindrical carbon materials and titania (TiO 2-x ), in which some oxygen is reduced (i.e., x is less than 2), to have a structure in which cylindrical carbon materials are entangled and interconnected in three dimensions; and sulfur introduced into at least a part of the external surface and inside of the titania-carbon (TiO 2 —C) composite, and a method for preparing the same.
1. A titania-carbon-sulfur composite comprising:
a titania-carbon composite of TiO 2-x —C, which is prepared from cylindrical carbon materials and titania of formula TiO 2-x , wherein x is greater than 0 and less than 2, to obtain a structure in which the cylindrical carbon materials are entangled and interconnected in three dimensions; and
sulfur, which is introduced into at least a part of an external surface and an inside of the titania-carbon composite,
wherein a ratio of the cylindrical carbon material and the titania of TiO 2-x is 3:7 to 5:5 by weight.
2. A method for preparing a titania-carbon-sulfur composite comprising the steps of
a) preparing a dispersion of a mixture of a cylindrical carbon material and TiO 2 ;
b) spray-drying the dispersion to prepare a titania-carbon composite of TiO 2 —C;
c) subjecting the titania-carbon composite of b) to a thermal reduction treatment to prepare a titania-carbon composite of TiO 2-x —C, wherein x is greater than 0 and less than 2; and
d) impregnating the titania-carbon composite of TiO 2-x —C with sulfur to prepare the titania-carbon-sulfur composite,
wherein in step a), a mixing ratio of the cylindrical carbon material:TiO 2 is 3:7 to 5:5 by weight.
3. The method for preparing the titania-carbon-sulfur composite according to claim 2 , wherein in step b), the spray-drying is performed at a flow rate of 0.5 ml/min to 5 ml/min and a temperature of 50° C. to 180° C.
4. The method for preparing the titania-carbon-sulfur composite according to claim 2 , wherein in step c), the thermal reduction treatment is carried out by raising a temperature at 350° C. to 700° C. for 1 hour to 4 hours and then maintaining for 1 hour to 4 hours.
5. The method for preparing the titania-carbon-sulfur composite according to claim 4 , wherein in step c), the thermal reduction treatment is carried out in an atmosphere comprising one or more selected from the group consisting of helium, neon, argon, hydrogen, nitrogen, and SF 6 gas.
6. The method for preparing the titania-carbon-sulfur composite according to claim 2 , wherein the dispersion further comprises a dispersion medium comprising at least one selected from the group consisting of water, alcohol, benzene, toluene, pyridine, acetone, tetrahydrofuran (THF) and dimethylformaldehyde (DMF).
7. The method for preparing the titania-carbon-sulfur composite according to claim 2 , wherein in step d), the sulfur comprises at least one selected from the group consisting of elemental sulfur and sulfur compounds.
8. A titania-carbon-sulfur composite comprising:
a titania-carbon composite of TiO 2-x —C, wherein x is greater than 0 and less than 2, the carbon comprises a cylindrical carbon material, and the titania-carbon composite comprises a structure in which the cylindrical carbon material is entangled and interconnected in three dimensions; and
sulfur, which is present in at least a part of an external surface and an inside of the titania-carbon composite,
wherein a ratio of the cylindrical carbon material and the titania of TiO 2-x is 3:7 to 5:5 by weight.
9. The titania-carbon-sulfur composite according to claim 8 , wherein a ratio of the cylindrical carbon material and the titania of TiO 2-x is 3:7 by weight.
10. The titania-carbon-sulfur composite according to claim 8 , wherein a ratio of the cylindrical carbon material and the titania of TiO 2-x is 5:5 by weight.
11. The titania-carbon-sulfur composite according to claim 8 , wherein the titania-carbon composite has a porosity of 10% to 40% and a total BET specific surface area of 50 m 2 /g to 1000 m 2 /g.
12. The titania-carbon-sulfur composite according to claim 8 , wherein the titania-carbon-sulfur composite has a particle size of 2 μm to 5 μm.
13. The titania-carbon-sulfur composite according to claim 8 , wherein the cylindrical carbon material comprises at least one selected from the group consisting of carbon nanotube (CNT), graphite nanofiber (GNF), carbon nanofiber (CNF), and activated carbon fiber (ACF).
14. The titania-carbon-sulfur composite according to claim 8 , wherein the titania-carbon composite used to prepare the titania-carbon-sulfur composite has an average particle size of 1 μm to 500 μm.
15. The titania-carbon-sulfur composite according to claim 8 , wherein the titania-carbon composite has a porosity of 10% to 70% and a total BET specific surface area of 50 m 2 /g to 1000 m 2 /g.
16. The titania-carbon-sulfur composite according to claim 8 , wherein the sulfur comprises at least one selected from the group consisting of elemental sulfur and sulfur-based compounds.
17. A positive electrode comprising the titania-carbon-sulfur composite according to claim 8 .
18. The positive electrode according to claim 17 , wherein the positive electrode is for a lithium-sulfur battery.
19. A lithium secondary battery comprising the positive electrode of claim 17 ; a negative electrode; and an electrolyte.