Wire rod and steel wire for springs having excellent corrosion fatigue resistance properties, and method for producing same
An embodiment of the present invention provides a wire rod and a steel wire which are for springs and have excellent corrosion fatigue resistance properties, and a method for producing same, the wire rod and steel wire containing, in wt %, 0.40-0.70% of C, 1.20-2.30% of Si, 0.20-0.80% of Mn, 0.20-0.80% of Cr, 0.015% or less of P, 0.015% or less of S, and 0.010% or less of N, with the remainder comprising Fe and other unavoidable impurities, along with at least one among 0.01-0.20% of V and 0.01-0.10% of Nb, wherein the V and Nb satisfy relational expression 1 below, the average grain size of prior austenite is no greater than 20 μm, and the surface decarburization depth is no greater than 0.1 mm. [Relational expression 1] [V]+[Nb]≥0.08 (where the V and Nb contents are in wt %).
1. A wire rod for a spring, the wire rod containing: by wt %, C: 0.40 to 0.70%, Si: 1.20 to 2.30%, Mn: 0.20 to 0.80%, Cr: 0.20 to 0.80%, P: 0.015% or less, S: 0.015% or less, N: 0.010% or less, one or two of V: 0.01 to 0.20% and Nb: 0.01 to 0.10%, and a balance of Fe and other unavoidable impurities,
wherein Relational Expression 1: [V]+[Nb]≥0.08 is satisfied, wherein, [V] and [Nb] represent the content of V and Nb in wt %,
wherein a microstructure of the wire rod is a composite structure of ferrite and pearlite, and a fraction of the ferrite is 5 to 35 area %,
a ratio of an amount of non-diffusible hydrogen to an amount of diffusible hydrogen is 2.67 or more,
an average grain size of prior austenite is 20 μm or less,
a depth of surface decarburization is 0.1 mm or less, and
the wire rod includes 3.17×10 4 /mm 2 or more of carbides containing 50 wt % or more of one or two of V and Nb.
2. A steel wire for a spring, the steel wire containing: by wt %, C: 0.40 to 0.70%, Si: 1.20 to 2.30%, Mn: 0.20 to 0.80%, Cr: 0.20 to 0.80%, P: 0.015% or less, S: 0.015% or less, N: 0.010% or less, one or two of V: 0.01 to 0.20% and Nb: 0.01 to 0.10%, and a balance of Fe and other unavoidable impurities,
wherein Relational Expression 1: [V]+[Nb]≥0.08 is satisfied, wherein [V] and [Nb] represent the content of V and Nb in wt %,
a ratio of an amount of non-diffusible hydrogen to an amount of diffusible hydrogen is 2.67 or more,
an average grain size of prior austenite is 20 μm or less,
a depth of surface decarburization is 0.1 mm or less,
the steel wire includes 3.17×10 4 /mm 2 or more of carbides containing 50 wt % or more of one or two of V and Nb, and
a microstructure of the steel wire is, in an area fraction, 10% or less of residual austenite and remaining tempered martensite.
3. The wire rod of claim 1 , further containing by wt %, one or two of Ti: 0.01 to 0.15% and Mo: 0.01 to 0.40%.
4. The wire rod of claim 1 , further containing by wt %, one or two of Cu: 0.01 to 0.40% and Ni: 0.10 to 0.60%.
5. The wire rod of claim 1 , wherein the wire rod contains, by wt %, Si: 1.20 to 1.49%.
6. The steel wire of claim 2 , further containing by wt %, one or two of Ti: 0.01 to 0.15% and Mo: 0.01 to 0.40%.
7. The steel wire of claim 2 , further containing by wt %, one or two of Cu: 0.01 to 0.40% and Ni: 0.10 to 0.60%.
8. A method for producing the wire rod of claim 1 , the method comprising:
heating, at 900 to 1050° C., a billet containing, by wt %, C: 0.40 to 0.70%, Si: 1.20 to 2.30%, Mn: 0.20 to 0.80%, Cr: 0.20 to 0.80%, P: 0.015% or less, S: 0.015% or less, N: 0.010% or less, and a balance of Fe and other unavoidable impurities, and further containing one or two of V: 0.01 to 0.20% and Nb: 0.01 to 0.10%, V and Nb satisfying the Relational Expression 1;
finishing rolling and winding the heated billet at 800 to 1000° C. to obtain a wound coil; and
performing primary cooling on the wound coil at a cooling rate of 2.0 to 10° C./s up to Ar1-40° C. and performing secondary cooling on the wound coil at a cooling rate of 0.3 to 1.8° C./s in a temperature range of (Ar1-40° C.) to (Ar1-140° C.).
9. The method of claim 8 , wherein the billet further contains, by wt %, one or two of Ti: 0.01 to 0.15% and Mo: 0.01 to 0.40%.
10. The method of claim 8 , wherein the billet further contains, by wt %, one or two of Cu: 0.01 to 0.40% and Ni: 0.10 to 0.60%.