Synthesis of Janus nanomaterials
Synthesizing Janus nanoparticles including forming a lamellar phase having water layers, organic layers, and a surfactant, and reacting chemical precursors in the lamellar phase to form the Janus nanoparticles at interfaces of the water layers with the organic layers.
1. A method of synthesizing Janus nanoparticles, comprising:
forming a lamellar phase comprising water layers, organic layers, and a surfactant; and
reacting chemical precursors in the lamellar phase to form Janus nanoparticles at interfaces of the water layers with the organic layers, wherein reacting the chemical precursors gives a surface functional group on a surface of a Janus nanoparticle of the Janus nanoparticles; and
reacting a molecule functional group of a molecule with the surface functional group in presence of a reagent to attach the molecule to the surface of the Janus nanoparticle, wherein the reagent comprises 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride (EDC), succinimidyl ester (NHS), succinimidyliodoacetate (SIA), N-succinimidyl 3-(2-pyridyldithio) propionate (SPDP), succinic anhydride, or thionyl chloride (SOCl2), or any combinations thereof.
2. The method of claim 1 , wherein a molecule of the surfactant comprises a hydrophilic head contacting a water layer and a hydrophobic tail contacting an organic layer adjacent the water layer, and wherein the chemical precursors comprise organometallic compounds.
3. The method of claim 1 , wherein reacting chemical precursors comprises reacting at the interfaces a first chemical precursor incorporated in the water layers with a second chemical precursor incorporated in the organic layers.
4. The method of claim 3 , wherein the first chemical precursor comprises a water-soluble organometallic compound, wherein the second chemical precursor comprises an oil-soluble organometallic compound, and wherein the Janus nanoparticles comprise Janus metal-oxide nanoparticles.
5. The method of claim 1 , wherein the Janus nanoparticles comprise a hydrophobic surface and a hydrophilic surface, and wherein forming the lamellar phase and reacting the chemical precursors to form the Janus nanoparticles is a one-pot synthesis.
6. The method of claim 1 , wherein the surface functional group comprises an amine group or a thiol group.
7. The method of claim 1 , wherein the surface functional group comprises an alkyl —CnH2n+1CH3 group, an amine —NH2 group, a thiol —SH group, a carboxyl —COOH group, or an isothiolcyanate —NCS group.
8. The method of claim 1 , wherein the molecule functional group comprises an amine group, a thiol group, a hydroxyl group, a carboxyl group, or an isothiocyanate group, or any combinations thereof.