Catalytically enhanced compositions for efficient removal of contaminants in flue gas streams
A sorbent composition that is useful for injection into a flue gas stream of a coal burning furnace to efficiently remove mercury from the flue gas stream. The sorbent composition may include a sorbent with an associated ancillary catalyst component that is a catalytic metal, a precursor to a catalytic metal, a catalytic metal compound or a precursor to a catalytic metal compound. Alternatively, a catalytic metal or metal compound, or their precursors, may be admixed with the coal feedstock prior to or during combustion in the furnace, or may be independently injected into a flue gas stream. A catalytic promoter may also be used to enhance the performance of the catalytic metal or metal compound.
1. A sorbent composition comprising:
a powdered activated carbon sorbent having a mean particle diameter (D50) of not greater than about 25 μm, a surface area of at least about 350 m 2 /g, and a total pore volume of at least about 0.20 cc/g; and
an ancillary catalyst component selected from the group consisting of:
(i) a catalytic metal selected from the group consisting of Fe, Cu, Mn, Pd, Au, Ag, Pt, Ir, V, Ni, Zn, Sn, Ti, Ce, and combinations thereof,
(ii) a precursor to the catalytic metal, wherein the precursor to the catalytic metal comprises the catalytic metal and is selected from the group consisting of a metal oxide, a metal halide, a metal hydroxide, a metal sulfate, a metal nitrate, a metal carbonate, and combinations thereof, and
(iii) combinations of the catalytic metal and the precursor to the catalytic metal,
wherein the ancillary catalyst component is coated on a surface of the powdered activated carbon sorbent, and
wherein the amount of the ancillary catalyst component is at least 0.001 wt. % and not greater than about 20 wt. % of the sorbent composition.
2. The sorbent composition of claim 1 , wherein the precursor to the catalytic metal is selected from the group consisting of copper (II) oxide (CuO), copper (II) chloride (CuCl 2 ), copper (II) nitrate (Cu(NO 3 ) 2 ), copper (II) hydroxide (Cu(OH) 2 ), copper (II) carbonate (CuCO 3 ), iron (III) oxide (Fe 2 O 3 ), iron (III) chloride (FeCl 3 ), iron (III) nitrate (Fe(NO 3 ) 3 ), iron (III) sulfate Fe 2 (SO 4 ) 3 , cerium (IV) oxide (CeO 2 ), manganese (IV) oxide (MnO 2 ), vanadium (V) oxide (V 2 O 5 ), zinc (II) oxide (ZnO), zinc sulfate (ZnSO 4 ), and combinations thereof.
3. The sorbent composition of claim 1 , further comprising a catalytic promoter dispersed on the powdered activated carbon sorbent, wherein the catalytic promoter comprises a promoter metal compound selected from the group consisting of alkali metal compounds, alkaline earth metal compounds, and combinations thereof.
4. The sorbent composition of claim 3 , wherein the catalytic promoter comprises a metal in elemental form or in the form of a metal oxide, a metal hydroxide, or a metal salt, the metal being selected from the group consisting of Li, Na, K, Be, Ca, Sr, Ba, Mg, and combinations thereof.
5. The sorbent composition of claim 1 , wherein the sorbent composition comprises not greater than about 1 wt. % of the ancillary catalyst component.
6. The sorbent composition of claim 1 , wherein the sorbent composition comprises not greater than about 5 wt. % of the ancillary catalyst component.
7. The sorbent composition of claim 1 , wherein the sorbent composition comprises not greater than about 10 wt. % of the ancillary catalyst component.
8. The sorbent composition of claim 1 , wherein the powdered activated carbon sorbent has a mean particle diameter (D50) of not greater than about 20 μm.
9. The sorbent composition of claim 1 , wherein the powdered activated carbon sorbent has a mean particle diameter (D50) of not greater than about 15 μm.
10. The sorbent composition of claim 1 , wherein the sorbent composition further comprises less than about 15 wt. % of a halogen.
11. The sorbent composition of claim 1 , wherein the sorbent composition further comprises less than about 6 wt. % of a halogen.
12. The sorbent composition of claim 1 , wherein the sorbent composition further comprises less than about 3 wt. % of a halogen.
13. The sorbent composition of claim 1 , wherein the sorbent composition comprises substantially no halogens.
14. The sorbent composition of claim 1 , wherein the sorbent composition further comprises an aqueous solubilizing medium in an amount that is at least about 2 wt. % and not greater than about 12 wt. %.
15. A sorbent composition comprising:
a powdered activated carbon sorbent having a mean particle diameter (D50) of not greater than about 25 μm, a surface area of at least about 350 m 2 /g, and a total pore volume of at least about 0.20 cc/g; and
an ancillary catalyst component comprising one or more of:
(i) a catalytic metal selected from the group consisting of Fe, Cu, Mn, Pd, Au, Ag, Pt, Ir, V, Ni, Zn, Sn, Ti, Ce, and combinations thereof,
(ii) a precursor to the catalytic metal, wherein the precursor to the catalytic metal comprises the catalytic metal and is selected from the group consisting essentially of a metal oxide, a metal halide, a metal hydroxide, a metal sulfate, a metal nitrate, a metal carbonate, and combinations thereof, and
(iii) combinations of the catalytic metal and the precursor to the catalytic metal,
wherein the ancillary catalyst component is bound to a surface of the powdered activated carbon sorbent, and
wherein the amount of the ancillary catalyst component is at least 0.001 wt. % and not greater than about 20 wt. % of the sorbent composition.
16. The sorbent composition of claim 15 , wherein the precursor to the catalytic metal is selected from the group consisting of copper (II) oxide (CuO), copper (II) chloride (CuCl 2 ), copper (II) nitrate (Cu(NO 3 ) 2 ), copper (II) hydroxide (Cu(OH) 2 ), copper (II) carbonate (CuCO 3 ), iron (III) oxide (Fe 2 O 3 ), iron (III) chloride (FeCl 3 ), iron (III) nitrate (Fe(NO 3 ) 3 ), iron (III) sulfate Fe 2 (SO 4 ) 3 , cerium (IV) oxide (CeO 2 ), manganese (IV) oxide (MnO 2 ), vanadium (V) oxide (V 2 O 5 ), zinc (II) oxide (ZnO), zinc sulfate (ZnSO 4 ), and combinations thereof.
17. The sorbent composition of claim 15 , further comprising a catalytic promoter dispersed on the powdered activated carbon sorbent, wherein the catalytic promoter comprises a metal in elemental form or in the form of a metal oxide, a metal hydroxide, or a metal salt, the metal being selected from the group consisting of Al, Li, Na, K, Be, Ca, Sr, Ba, Sc, Y, Mg, and combinations thereof.
18. The sorbent composition of claim 15 , wherein the sorbent composition comprises not greater than about 1 wt. % of the ancillary catalyst component.
19. The sorbent composition of claim 15 , wherein the sorbent composition comprises not greater than about 5 wt. % of the ancillary catalyst component.
20. The sorbent composition of claim 15 , wherein the sorbent composition comprises not greater than about 10 wt. % of the ancillary catalyst component.
21. The sorbent composition of claim 15 , wherein the sorbent composition further comprises less than about 15 wt. % of a halogen.
22. The sorbent composition of claim 15 , wherein the sorbent composition comprises substantially no halogens.
23. The sorbent composition of claim 15 , wherein the sorbent composition further comprises an aqueous solubilizing medium in an amount that is at least about 2 wt. % and not greater than about 12 wt. %.
24. A sorbent composition comprising:
a powdered activated carbon sorbent having a mean particle diameter (D50) of not greater than about 25 μm, a surface area of at least about 350 m 2 /g, and a total pore volume of at least about 0.20 cc/g; and
an ancillary catalyst component selected from the group comprising one or more of:
(i) a catalytic metal selected from the group consisting of Fe, Cu, Mn, Pd, Au, Ag, Pt, Ir, V, Ni, Zn, Sn, Ti, and Ce, and
(ii) a precursor to the catalytic metal, wherein the precursor to the catalytic metal comprises the catalytic metal and is selected from the group comprising one or more of a metal oxide, a metal halide, a metal hydroxide, a metal sulfate, a metal nitrate, and a metal carbonate,
wherein the amount of the ancillary catalyst component is at least 0.001 wt. % and not greater than about 20 wt. % of the sorbent composition and wherein the sorbent composition comprises substantially no halogens.
25. The sorbent composition of claim 24 , wherein the precursor to the catalytic metal is selected from the group consisting of copper (II) oxide (CuO), copper (II) chloride (CuCl 2 ), copper (II) nitrate (Cu(NO 3 ) 2 ), copper (II) hydroxide (Cu(OH) 2 ), copper (II) carbonate (CuCO 3 ), iron (III) oxide (Fe 2 O 3 ), iron (III) chloride (FeCl 3 ), iron (III) nitrate (Fe(NO 3 ) 3 ), iron (III) sulfate Fe 2 (SO 4 ) 3 , cerium (IV) oxide (CeO 2 ), manganese (IV) oxide (MnO 2 ), vanadium (V) oxide (V 2 O 5 ), zinc (II) oxide (ZnO), zinc sulfate (ZnSO 4 ), and combinations thereof.
26. The sorbent composition of claim 24 , further comprising a catalytic promoter dispersed on the powdered activated carbon sorbent, wherein the catalytic promoter comprises a metal in elemental form or in the form of a metal oxide, a metal hydroxide, or a metal salt, the metal being selected from the group consisting of Al, Li, Na, K, Be, Ca, Sr, Ba, Sc, Y, Mg, and combinations thereof.
27. The sorbent composition of claim 24 , wherein the sorbent composition comprises not greater than about 1 wt. % of the ancillary catalyst component.
28. The sorbent composition of claim 24 , wherein the sorbent composition comprises not greater than about 5 wt. % of the ancillary catalyst component.
29. The sorbent composition of claim 24 , wherein the sorbent composition comprises not greater than about 10 wt. % of the ancillary catalyst component.
30. The sorbent composition of claim 24 , wherein the sorbent composition further comprises an aqueous solubilizing medium in an amount that is at least about 2 wt. % and not greater than about 12 wt. %.
31. The sorbent composition of claim 15 , wherein the ancillary catalyst component is bound to a surface of the powdered activated carbon sorbent through covalent bonding, ionic bonding, or intramolecular forces.
32. A sorbent composition comprising:
a powdered activated carbon sorbent having a mean particle diameter (D50) of not greater than about 25 μm, a surface area of at least about 350 m 2 /g, and a total pore volume of at least about 0.20 cc/g; and
an ancillary catalyst component associated with a surface of the powdered activated carbon sorbent and comprising one or more of:
(i) a catalytic metal selected from the group consisting of Cu, Mn, Pd, Au, Ag, Pt, Ir, V, Ni, Zn, Sn, Ti, Ce, and combinations thereof,
(ii) a precursor to the catalytic metal, wherein the precursor to the catalytic metal comprises the catalytic metal and is selected from the group consisting essentially of a metal oxide, a metal halide, a metal hydroxide, a metal sulfate, a metal nitrate, a metal carbonate, and combinations thereof, and
(iii) combinations of the catalytic metal and the precursor to the catalytic metal,
wherein the ancillary catalyst component is bonded to a surface of the powdered activated carbon sorbent through covalent bonding, ionic bonding, or intramolecular bonding, and
wherein the amount of the ancillary catalyst component is at least 0.001 wt. % and not greater than about 20 wt. % of the sorbent composition.
33. The sorbent composition of claim 32 , wherein the precursor to the catalytic metal is selected from the group consisting of copper (II) oxide (CuO), copper (II) chloride (CuCl 2 ), copper (II) nitrate (Cu(NO 3 ) 2 ), copper (II) hydroxide (Cu(OH) 2 ), copper (II) carbonate (CuCO 3 ), cerium (IV) oxide (CeO 2 ), manganese (IV) oxide (MnO 2 ), vanadium (V) oxide (V 2 O 5 ), zinc (II) oxide (ZnO), zinc sulfate (ZnSO 4 ), and combinations thereof.