Nano metal compound particles, coating material and film using the same, method for producing film, and method of producing nano metal compound particles
According to one embodiment, nano metal compound particles are provided. The nano metal compound particles have an average particle size of 50 nm or less. The nano metal compound particles have a peak ω t of 2.8 eV or less. The peak ω t corresponds to a resonant frequency of an oscillator according to a spectroscopic ellipsometry method fitted to a Lorentz model.
1. Nano metal compound particles having an average particle size of 50 nm or less, a maximum particle size of 100 nm or less, and a peak ω t of 2.8 eV or less, the peak cot corresponding to a resonant frequency of an oscillator according to a spectroscopic ellipsometry method for a batch of nano metal compound particles with a film thickness in a range of 50 nm to 200 nm fitted to a Lorentz model using a theoretical equation shown below:
ε(ω)=ε ∞ +fω t 2 /ω t 2 +ω 2 +iγ 0 ε
wherein ω denotes a frequency of incident light, ω t denotes the oscillator center of the oscillator, γ 0 denotes a damping factor, f denotes an oscillator strength, ε(ω) denotes a permittivity function, ε ∞ denotes a limit value of high-frequency permittivity function, and i is an imaginary number.
2. The nano metal compound particles according to claim 1 , wherein 0.5 eV≤ω t ≤2 eV.
3. The nano metal compound particles according to claim 1 , wherein the metal compound particles have an average particle size of 15 nm or less.
4. The nano metal compound particles according to claim 1 , comprising one or more materials selected from the group consisting of a metal oxide, a metal sulfide, a metal nitride, and a metal carbide.
5. The nano metal compound particles according to claim 1 , wherein the nano metal compound particles have lattice defects.
6. The nano metal compound particles according to claim 1 , wherein the nano metal compound particles comprise particles containing a metal oxide, and the metal oxide has an oxygen deficiency.
7. The nano metal compound particles according to claim 1 , wherein the nano metal compound particles comprise particles containing a metal oxide, and the metal oxide comprises one or more materials selected from the group consisting of an oxide represented by WO 3-x and satisfying 0<x<3, an oxide represented by MoO 3-x and satisfying 0<x<3, an oxide represented by IrO 2-x and satisfying 0<x<2, an oxide represented by NiO 1-x , and satisfying 0<x<1, and an oxide represented by TiO 2-x and satisfying 0<x<2.
8. A coating material comprising the nano metal compound particles according to claim 1 .
9. A film comprising the nano metal compound particles according to claim 1 .
10. The film according to claim 9 , for use in one selected from the group consisting of a semiconductor, a battery electrode, a photocatalyst, a sensor, and an electrochromic device.
11. The film according to claim 9 , having a film thickness of 1 μm or less.
12. The film according to claim 9 , having a peak ω t of 2.8 eV or less, the peak cot corresponding to a resonant frequency of an oscillator according to the spectroscopic ellipsometry method fitted to the Lorentz model.
13. The film according to claim 9 , comprising 50% by volume or more of the nano metal compound particles.
14. A method for producing a film, the method comprising:
forming a nano metal compound particle-containing paste film by applying a paste containing the nano metal compound particles according to claim 1 ; and
drying the nano metal compound particle-containing paste film.