Process for the catalytic conversion of micro carbon residue content of heavy hydrocarbon feedstocks and a low surface area catalyst composition for use therein
An improved process for the hydroconversion of micro carbon residue content of heavy hydrocarbon feedstocks by the use of a catalyst composition that is especially useful in the conversion of micro carbon residue of such feedstocks. The catalyst composition is a low surface area composition that further has a specifically define pore structure the combination of which provides for its enhance micro carbon residue conversion property.
1. A process for converting at least a portion of an MCR content of a heavy hydrocarbon feedstock to yield a product having a reduced MCR content, wherein said process includes contacting said heavy hydrocarbon feedstock with a catalyst under MCR conversion process conditions and yielding said product, wherein the improvement comprises: enhancing the conversion of said MCR content of said heavy hydrocarbon feedstock by using as said catalyst in said process a calcined particulate of a co-mulled mixture, wherein said co-mulled mixture that is formed into a particulate, which is subsequently calcined to provide said calcined particulate, comprises a molybdenum component, a nickel component, an uncalcined pseudo-boehmite powder prepared by a two-step precipitation process and comprising at least 90 weight percent pseudo-boehmite, a mineral acid, and a catalyst fines portion having a particle size between 5 and 50 microns (μm) and a mean pore diameter between 40 Å and 150 Å, and wherein said calcined particulate is prepared under conditions so that it has specifically defined physical properties including:
(a) a total surface area of greater than 160 m 2 /g and less than 240 m 2 /g;
(b) a median pore diameter in the range of from 85 Å to 120 Å;
(c) from 8% to 22% of the total pore volume of said calcined particulate in the macropores having a pore diameter of 250 Å or greater; and
(d) greater than 40% and no more than 60% of the total pore volume of said calcined particulate within its pores having a diameter in the range of from 55 Å to 115 Å; and
(e) from about 10% to about 45% of the total pore volume of said calcined particulate is within the pores of a pore diameter in the range of from 50 Å to 100 Å.
2. The process as recited in claim 1 , wherein from 15% to 40% of said surface area is provided by pores having a pore diameter of less than or equal to 75 Å, as determined by N 2 desorption.
3. The process as recited in claim 1 , wherein from 20% to 60% of said surface area is provided by pores having a pore diameter in the range of 100 to 150 Å, as determined by mercury intrusion.
4. The process as recited in claim 1 , wherein said calcined particulate has a nitrogen median pore diameter that is in the range of from 87.5 Å to 115 Å.
5. The process as recited in claim 1 , further comprising a molybdenum component in an amount not less than 5 wt % but not more than 13 wt %, with the wt % being based on the total weight of said catalyst composition and assuming said molybdenum component is in the oxide form regardless of its actual form, and a nickel component present in an amount such that the weight ratio of the nickel component-to-molybdenum component is at least 0.25.
6. The process as recited in claim 1 , wherein from 20% to 60% of the total pore volume of said calcined particulate is present as pores having diameters in the range of from 100 Å to 150 Å, and wherein the portion of total pore volume of said calcined particulate in pores having diameters in the range of from 50 Å to 100 Å is less than the portion of its total pore volume in the pores having a pore diameter in the range of from 100 Å to 150 Å.
7. The process as recited in claim 1 , wherein the calcination of said particulate of said co-mulled mixture is conducted in air without added steam under calcination conditions that include a calcination temperature exceeding 1150° F. to provide said calcined particulate.
8. The process as recited in claim 1 , wherein said catalyst fines portion comprises molybdenum oxide, nickel oxide, phosphorus oxide, and γ-alumina, and wherein said catalyst fines portion is in an amount so as to provide a phosphorus content in said calcined particulate within a desired range.
9. The process as recited in claim 1 , wherein said calcined particulate has a total surface area in the range of from 190 m 2 /g to 235 m 2 /g.
10. The process as recited in claim 1 , wherein said calcined particulate has a total surface area in the range of from 195 m 2 /g to 230 m 2 /g.
11. The process as recited in claim 1 , wherein from 10% to 45% of the total pore volume of said calcined particulate is present as pores having diameters in the range of from 50 Å to 100 Å, and wherein from 25% to 55% of the total pore volume of said calcined particulate is present as pores having diameters in the range of from 100 Å to 150 Å.
12. The process as recited in claim 1 , wherein from 15% to 38% of the total pore volume of said calcined particulate is present as pores having diameters in the range of from 50 Å to 100 Å, and wherein no more than 55% of the total pore volume of said calcined particulate is present as pores having diameters in the range of from 55 Å to 115 Å.
13. The process as recited in claim 1 , wherein from 20% to 35% of the total pore volume of said calcined particulate is present as pores having diameters in the range of from 50 Å to 100 Å, and wherein no more than 55% of the total pore volume of said calcined particulate is present as pores having diameters in the range of from 55 Å to 115 Å.
14. The process as recited in claim 1 , wherein said mineral acid is an aqueous solution of nitric acid having a molar concentration and added to said co-mulled mixture in an amount so as to provide a desired microporosity of said calcined particulate.
15. The process as recited in claim 1 , wherein an amount of said catalyst fines portion in the co-mulled mixture is up to 50 wt % based on the total weight of said catalyst composition.