Nonaqueous electrolyte secondary battery
View Patent ↗This nonaqueous electrolyte secondary battery is provided with an electrode body that is obtained by alternately laminating a plurality of positive electrodes and a plurality of negative electrodes, with separators being interposed therebetween. Each separator is configured of a porous resin substrate and a porous heat-resistant layer that is formed on one surface of the resin substrate and has a larger surface roughness than the resin substrate. The electrode body comprises: bonding particles that bond a negative electrode and a heat-resistant layer with each other; and bonding particles that bond a positive electrode and a resin substrate with each other. The mass of the bonding particles per unit area in a first interface between the negative electrode and the heat-resistant layer is larger than the mass of the bonding particles per unit area in a second interface between the positive electrode and the resin substrate.
1. A non-aqueous electrolyte secondary battery, comprising an electrode assembly including a plurality of first electrodes and a plurality of second electrodes alternately laminated with a separator interposed therebetween, wherein
the separator includes a porous resin base material and a porous heat-resistant layer, the porous heat-resistant layer being formed on one side of the resin base material and having larger surface irregularities than surface irregularities of the resin base material,
the electrode assembly has:
first adhesive particles bonding the first electrodes to the heat resistant layer; and
second adhesive particles bonding the second electrodes to the resin base material,
a mass of the first adhesive particles per unit area at a first interface between the first electrodes and the heat resistant layer is larger than a mass of the second adhesive particles per unit area at a second interface between the second electrodes and the resin base material,
wherein (A) the number of the first adhesive particles per unit area at the first interface is larger than (B) the number of the second adhesive particles per unit area at the second interface,
wherein a ratio of the number of particles (AB) between the number of first adhesive particles (A) and the number of the second adhesive particles (B) is 1.01 to 2.5, and wherein an average particle diameter of the first adhesive particles is smaller than a concave part present on the surface of the heat resistant layer, and an average particle diameter of the second adhesive particles is larger than a concave part present on the surface of the resin base material.
2. The non-aqueous electrolyte secondary battery according to claim 1 , wherein
each of (S1) adhesion force between the first electrode and the heat resistant layer and (S2) adhesion force between the second electrode and the resin base material is 3 N/m or more and less than 10 N/m, and
an adhesion force ratio (S1/S2) between the adhesion force (Si) and the adhesion force (S2) is 0.5 to 1.5.
3. The non-aqueous electrolyte secondary battery according to claim 2 , wherein the ratio of the number of particles (A/B) and the adhesion force ratio (S1/S2) are within a pentagonal range having apexes at
[1] (A/B=1.01, S1/S2=0.70),
[2] (A/B=2.00, S1/S2=0.50),
[3] (A/B=2.50, S1/S2=0.60),
[4] (A/B=2.50, S1/S2=1.50), and
[5] (A/B=1.60, S1/S2=1.25).
4. The non-aqueous electrolyte secondary battery according to claim 1 , wherein adhesive particles of the same kind are used for the first adhesive particles and the second adhesive particles.
5. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the heat resistant layer includes inorganic compound particles having an average particle diameter larger than the average particle diameter of the first adhesive particles.